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Search results for: AOR reactions
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Mai’a K. Davis Cross, Ireneusz Paweł Karolewski (red.), European-Russian Power Relations in Turbulent Times, University of Michigan Press, Ann Arbor 2021, ss. 311.
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Does China use its trade potential in the Belt and Road Initiative properly? The relations between Chinese value added and trade potential in the European countries: bottom-up analysis
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Reaktory elektrochemiczne w przemyśle - konstrukcja i zastosowania
PublicationZ biegiem lat reakcje elektrochemiczne przestały być postrzegane jedynie jako eksperymenty laboratoryjne lub proste baterie. Chociaż mechanizm reakcji i budowa prostych reaktorów znana jest ludzkości już od ponad 100 lat w ostatnich latach można zauważyć największy wzrost zainteresowania tą dziedziną. Nowy stale opracowywane są lepsze projekty budowy reaktorów. Modyfikacje to nie tylko rodzaje i formy materiałów, z których wykonane...
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Beliefs about psychological help among firemen
PublicationThe aim of this study was to identify beliefs and perceived barriers in psychological help. Findings: 1. Occupational stress and participation in traumatic rescue actions was related with negative beliefs. 2. Firemen were afraid of a commader's reaction. 3. Avoidance coping accounts for fear about stigmatization.
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Phosphinophosphoranes: Mixed-Valent Phosphorus Compounds with Ambiphilic Properties
PublicationHerein, we present a simple synthesis of mixed-valent phosphinophosphoranes bearing three- and five-coordinate phosphorus centers. Compounds with phosphorus–phosphorus bonds were synthesized via a reaction of lithium phosphides RR′PLi with cat2PCl (cat = catecholate), whereas derivatives with methylene-linked phosphorus centers were obtained via a reaction of phosphanylmethanides RR′CH2Li with cat2PCl. The presence of accessible...
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Simultaneous Removal of Hexane and Ethanol from Air in a Biotrickling Filter—Process Performance and Monitoring Using Electronic Nose
PublicationBiofiltration is a well-accepted method for the removal of malodorous compounds from air streams. Interestingly, the mechanisms underlying this process are not fully understood. The aim of this paper was to investigate the simultaneous removal of hydrophobic hexane with hydrophilic ethanol, resulting in the enhanced removal of hexane in the presence of ethanol. Investigations were performed in a peat-perlite packed biotrickling...
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The role of air masses on iron concentrations in wet atmospheric deposition over the urbanized coastal zone of the Gulf of Gdańsk
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Influence of Binders and Lightweight Aggregates on the Properties of Cementitious Mortars: From Traditional Requirements to Indoor Air Quality Improvement
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Mobile monitoring system for air quality control along traffic routes = Monitoring zanieczyszczeń wzdłuż ciągów komunikacyjnych
PublicationW referacie przedstawiono budowę i zasadę działania mobilnej stacji monitoringu do badania i analizy zanieczyszczeń powietrza atmosferycznego wzdłuż ciagów komunikacyjnych. Przedstawiono również wyniki badań imisji substancji emitowanych z pojazdów poruszających się wzdłuż układu komunikacyjnego Trójmiasta stosując urzadzenie ETL 2000 Bus, zamontowane na dachu samochodu osobowego. Wcześniej, uzyskane wyniki porównano z wynikami...
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Modeling and experimental investigation of the hydraulic jump in liquid film formed by an impinging two-phase air-water jet
PublicationPrzedstawiono model analityczny układu hydraulicznego powstałego na skutek uderzenia strugi dwufazowej wody i powietrza. Obliczenia porównano z badaniami eksperymentalnymi przeprowadzonymi na własnym stanowisku badawczym. Uzyskano zadowalającą zgodność.
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Analysis of the Resistance Change of Chemosensitive Layers to the Presence of Ammonia Vapors under Variable Conditions of Air Temperature and Humidity
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LABORATORY STUDY ON INFLUENCE OF AIR DUCT THROTTLING ON EXHAUST GAS COMPOSITION IN MARINE FOUR-STROKE DIESEL ENGINE
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Co-free triple perovskite La1.5Ba1.5Cu3O7±δ as a promising air electrode material for solid oxide fuel cells
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Authors’ response (March 5, 2019) to the letter to the Editor concerning the paper “Impact of air pollution on depression and suicide”
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Transcriptomics‐Based and AOP‐Informed Structure–Activity Relationships to Predict Pulmonary Pathology Induced by Multiwalled Carbon Nanotubes
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Long-term exposure to urban air pollution and the relationship with life expectancy in cohort of 3.5 million people in Silesia
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Modelling and experimental investigation of the phenomenon of brekdown of the liquid layer formed by an impinging two-phase air-water jet
PublicationW pracy przedstawiono analizę teoretyczną i badania eksperymentalne badania zjawiska rozrywania warstwy cieczy powstałej z uderzającej strugi
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Modelling of high temperature air/steam gasification of biomassand solid wastes in view of hydrogen-rich gas production
PublicationPrzedstawiono zaawansowane technologie produkcji gazu bogatego w wodór z biomasy i odpadów komunalnych. Przeprowadzono badania eksperymentalne na stanowisku pomiarowym wykonanym w skali półprzemysłowej. Otrzymano obiecujące rezultaty podczas zgazowania palet drewnianych gazem o różnej zawartości pary wodnej.
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Application of a catalytic combustion sensor (Pellistor) for the monitoring of the explosiveness of a hydrogen-air mixture in the upper explosive limit range
PublicationA new technique is presented for continuous measurements of hydrogen contamination by air in the upper explosive limit range. It is based on the application of a catalytic combustion sensor placed in a cell through which the tested sample passes. The air content is the function of the quantity of formed heat during catalytic combustion of hydrogen inside the sensor. There is the possibility of using the method in industrial installations...
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Challenges of Green Chemistry in monitoring and air protection. Wyzwania Zielonej Chemii w monitoringu i ochronie powietrza.
PublicationW pracy przedstawiono podstawowe założenia Zielonej Chemii do syntezy i przerobu związków chemicznych. W szczególnośi opisano nowe podejście w opracowywaniu metod analitycznych pozwalających na ocenę stanu zanieczyszczenia środowiska - w tym i powietrza. Podkreślono rolę analityki procesowej jako narzędzia kontroli procesu chemicznego, pozwalającego na szybkie wykrycie zagrożenia zanieczyszczenia powietrza.
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Universal mobile monitoring system for gaseous air pollution = Uniwersalny system mobilnego monitoringu gazowych zanieczyszczeń powietrza
PublicationW pracy przedstawiono koncepcję systemu do mobilnego monitoringu substancji chemicznych w powietrzu. Proponowany system może być zastosowany do pomiaru zanieczyszczeń powietrza emitowanych przez komunikację. Stacja monitoringowa jest stosunkowo małych rozmiarów i może być zamontowana na pojazdach prywatnych lub publicznych. Zmierzone stężenia są zbierane i przenoszone poprzez sieć GSM do centralnej bazy danych. Przedstawiono także...
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The influence of meteorological conditions and anthropogenic activities on the seasonal fluctuations of BTEX in the urban air of the Hanseatic city of Gdansk, Poland
PublicationThe results of studies conducted in Gdansk in the period from January to December 2013 and focused on the determination of BTEX in the atmospheric air are presented. At the stage of the isolation and/or enrichment of analytes from the gaseous medium, a passive sampling technique—Radiello® diffusive passive samplers, was applied. The time-weighted average annual concentration of benzene, toluene, ethylbenzene, and total xylenes...
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Air temperature and location of isobaric surfaces in relation to atmospheric circulation, based on radiosonde data from Legionowo, Poland
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Air-drying temperature changes the content of the phenolic acids and flavonols in white mulberry (Morus alba L.) leaves
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Interactive information and decision support system for urban and industrial air quality management based on multi-agent system
PublicationThis article presents conception of interactive information and decision support system for urban and industrial air quality management. The emphasis of the project is on real-time analysis and multi-media information, and the support of distributed and mobile clients through the Internet. The approach integrates meteorological data and forecasts, air quality and emission monitoring, dynamic 3D simulation modelling and forecasting,...
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Diagnostics of UV Nanosecond Laser Generated Plasma Plume Dynamics in Ambient Air Using Time-Resolved Imaging
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Removal of cyclohexane vapors from air in biotrickling filters: Effects of gas mixture composition and circular economy approach
PublicationThis work presents results of investigations on biotrickling filtration of air polluted with cyclohexane co-treated in binary, ternary and quaternary volatile organic compounds (VOCs) mixtures, including vapors of hexane, toluene and ethanol. The removal of cyclohexane from a gas mixture depends on the physicochemical properties of the co-treated VOCs and the lower the hydrophobicity of the VOC, the higher the removal efficiency...
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Techno-economic evaluation of combined cycle gas turbine and a diabatic compressed air energy storage integration concept
PublicationMore and more operational flexibility is required from conventional power plants due to the increasing share of weather-dependent renewable energy sources (RES) generation in the power system. One way to increase power plant’s flexibility is integrating it with energy storage. The energy storage facility can be used to minimize ramping or shutdowns and therefore should lower overall generating costs and CO2 emissions. In this article,...
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Spatial aspects of urban air quality management: Estimating the impact of micro-scale urban form on pollution dispersion
PublicationUrban planning and design solutions affect urban ventilation conditions, thus mitigating the effects of atmospheric pollution. However, these findings are not being implemented in the planning practice to a sufficient extent, partly due to the lack of specific guidelines. Moreover, many urban air quality monitoring (AQM) sites have low represnentativeness and thus do not provide comprehensive data for effective urban air pollution control...
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An MOR Algorithm Based on the Immittance Zero and Pole Eigenvectors for Fast FEM Simulations of Two-Port Microwave Structures
PublicationThe aim of this article is to present a novel model-order reduction (MOR) algorithm for fast finite-element frequency-domain simulations of microwave two-port structures. The projection basis used to construct the reduced-order model (ROM) comprises two sets: singular vectors and regular vectors. The first set is composed of the eigenvectors associated with the poles of the finite-element method (FEM) state-space system, while...
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Reducing Air Pollutant Emissions from the Residential Sector by Switching to Alternative Energy Sources in Single-Family Homes
PublicationThe paper discusses a scenario for adapting residential buildings to the requirements of the EU climate and energy package. It analyzes the option of reducing pollutant emissions to ambient air by switching to alternative energy sources in a typical single-family residential building. The most common sources of energy in central heating and ventilation systems and water heating systems were compared, and the analyzed energy carriers...
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Effect of different ventilation systems on air quality, heat consumption and psycho-physical comfort in modern residential buildings
PublicationArtykuł omawia wpływ różnych systemów wentylacji na jakość powietrza, zużycie ciepła i komfort psychiczno-fizyczny w nowoczesnych domach mieszkalnych na terenie Niemiec. Badania wykonano na kompleksie domków jednorodzinnych. Zbadano wpływ 4 systemów wentylacji.
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On the EM algorithm for the estimation of speech AR parameters in noise
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Organizacijos etyika ir kultura: buti ar atrodyti
PublicationW artykule podjęta próba wyjaśnienia wpływu instytucjonalizacji etyki na in-tegrację kultury organizacyjnej oraz jakośc wykonawstwa.
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Syntheses and structures of the first terminal phosphanylphosphido complexes of molybdenum(IV)
PublicationThe reactions of R2P-P(SiMe3)Li (R = tBu, iPr2N) with [Cp2MoCl2] yield terminal phosphanylphosphido complexes formally via the insertion of the phosphinidene P-atom into the C - H bond of a cyclopentadienyl ring and the migration of the hydrogen atom or SiMe3 moiety to the molybdenum centre. Solid state structures of [Cp(C5H4P-PtBu2)MoH], [Cp(C5H4P-PtBu2)Mo(SiMe3)] and [Cp{C5H4P-P(NiPr2)2}Mo(SiMe3)] were established by single crystal...
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Selected design and construction aspects of supercritical steam generators for high temperature reactors = Wybrane aspekty konstrukcyjne i projektowe generatorów pary nadkrytycznej ogrzewanych z reaktorów wysokotemperaturowych
PublicationW artykule zaprezentowano uwarunkowania projektowe i konstrukcyjne nadkrytycznego generatora pary (jednoprzepływowego) wykorzystującego do ogrzewania hel z reaktorów HTR i VHTR. Wymiennik helikoidalny jest preferowany dla zwiększenia wymiany ciepła i zwartości. Badano własności czynników wymieniających ciepło z parą w obszarach przy- i nadkrytycznych. Analizowano korelacje, aby wybrać najbardziej wiarygodne. Przedyskutowano najbardziej...
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Screening stability, thermochemistry, and chemical kinetics of 3-hydroxybutanoic acid as a bifunctional biodiesel additive
PublicationThe thermo-kinetic aspects of 3-hydroxybutyric acid (3-HBA) pyrolysis in the gas phase were investigated using density functional theory (DFT), specifically the M06-2X theoretical level in conjunction with the cc-pVTZ basis set. The obtained data were compared with benchmark CBS-QB3 results. The degradation mechanism was divided into 16 pathways, comprising 6 complex fissions and 10 barrierless reactions. Energy profiles were calculated...
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Reactivity of Phosphanylphosphinidene Complex of Tungsten(VI) toward Phosphines: A New Method of Synthesis of catena-Polyphosphorus Ligands
PublicationThe reactivity of an anionic phosphanylphosphinidene complex of tungsten(VI), [(2,6-i-Pr2C6H3N)2(Cl)- W(η2-t-Bu2P=P)]Li·3DME toward PMe3, halogenophosphines, and iodine was investigated. Reaction of the starting complex with Me3P led to formation of a new neutral phosphanylphosphinidene complex, [( 2,6-i-Pr2C6H3N)2(Me3P)W(η2-t-Bu2P=P)]. Reactions with halogenophosphines yielded new catena-phosphorus complexes. From reaction with...
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Reactivity of Diimido Complexes of Molybdenum and Tungsten towards Lithium Derivatives of Diphosphanes and Triphosphanes
PublicationThe reaction of R2P–P(SiMe3)Li (R = tBu, iPr) with the diimido molybdenum complex [(ArN)2MoCl2·dme] (Ar = 2,6-iPr2C6H3; dme = 1,2-dimethoxyethane) yielded the side-oncoordinated phosphanylphosphinidene anionic complexes [(2,6-iPr2C6H3N)2Mo(Cl)(η2-P=PR2)]– (7Mo, 8Mo). The thermal decomposition of [(2,6-iPr2C6H3N)2M(Cl)(η2-P=PR2)]–[M = Mo (7Mo), W (8W)] to [(2,6-iPr2C6H3N)2M(Cl)(1,2-η-tBu2P=P–PtBu2)] [M = Mo (3Mo), W (3W)] was investigated...
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In-Out Surface Modification of Halloysite Nanotubes (HNTs) for Excellent Cure of Epoxy: Chemistry and Kinetics Modeling
PublicationIn-out surface modification of halloysite nanotubes (HNTs) has been successfully performed by taking advantage of 8-hydroxyquinolines in the lumen of HNTs and precisely synthesized aniline oligomers (AO) of different lengths (tri- and pentamer) anchored on the external surface of the HNTs. Several analyses, including FTIR, H-NMR, TGA, UV-visible spectroscopy, and SEM, were used to establish the nature of the HNTs’ surface engineering....
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Development of Strategies for AOB and NOB Competition Supported by Mathematical Modeling in Terms of Successful Deammonification Implementation for Energy-Efficient WWTPs
PublicationNovel technologies such as partial nitritation (PN) and partial denitritation (PDN) could be combined with the anammox-based process in order to alleviate energy input. The former combination, also noted as deammonification, has been intensively studied in a frame of lab and full-scale wastewater treatment in order to optimize operational costs and process efficiency. For the deammonification process, key functional microbes include...
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Influence of Thermal Decomposition of Wood and Wood-Based Materials on the State of the Atmospheric Air. Emissions of Toxic Compounds and Greenhouse Gases
PublicationThis paper presents the energy characteristics of wood and wood-based materials in the form of commercially available pellets, furniture board (MDF) and OSB. Toxicometric indices were determined for gaseous destructs arising from thermal decomposition and combustion of the materials studied. The paper proves that combustion conditions are crucial in terms of toxic destructive emissions. It has been shown that the combustion of...
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The impact of air humidity on the operation of proton exchange membrane fuel cells determined using dynamic electrochemical impedance spectroscopy
PublicationThis paper describes the changes in the fuel cell impedance across a range of current loads and humidity changes. The changes of each equivalent circuit parameters representing specific processes occurring in fuel cells, as a function of humidity and current changes, were determined. Within the combined scope of current and humidity, the optimal working conditions of the cells were determined, corresponding to the lowest impedance...
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A framework for Air Quality Management Zones - Useful GIS-based tool for urban planning: Case studies in Antwerp and Gdańsk
PublicationThere is a growing recognition of the importance of proper urban design in the improvement of air flow and pollution dispersion and in reducing human exposure to air pollution. However, a limited number of studies have been published so far focusing on the development of standard procedures which could be applied by urban planners to effectively evaluate urban conditions with respect to air quality. To fill this gap, a new approach...
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Determination of polybrominated diphenyl ethers (PBDEs) in dust samples collected in air conditioning filters of different usage – method development
PublicationThis study presents the results of studies aimed at the development of an analytical procedure for separation, identification, and determination of PBDEs compounds in dust samples collected from automotive cabin air filters and samples collected from filters installed as part of the air purification system in academic facilities. Ultrasound-assisted dispersive solid phase extraction (UA-dSPE) was found to perform better in terms...
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Experimental and comparative study on the two-phase pressure drop of air-water mixture in U-bend and straight pipe annuli
PublicationIn this paper, the experimental and theoretical analysis of pressure drop in singlephase and two phase-flow were presented for straight and U-bend smooth tube annulus and tube annulus with wire coil insert. Experiments for various boundary conditions were performed. In case of U-tube and straight tube with and without turbulator, tests were made for the water-water and air-water systems. The study covered a wide measuring range,...
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Occurrence of fungi and cytotoxicity of the species: Aspergillus ochraceus, Aspergillus niger and Aspergillus flavus isolated from the air of hospital wards
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Using AOP-Wiki to support the ecotoxicological risk assessment of nanomaterials: first steps in the development of novel adverse outcome pathways
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Preliminary study of possible relationships between exposure to PCDD/Fs and dl-PCBs in ambient air and the length of life of people
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A new approach in the calibration of passive samplersA new approach on the calibration of passive dosimeters for studies of indoor air (....--------ROZBIEŻNOŚĆ TYTUŁÓW-------------------------------------
PublicationPrzedstawiono problematykę kalibracji próbników pasywnych wykorzystywanych w Katedrze Chemii Analitycznej Wydz. Chemicznego PG do monitoringu jakości powietrza wewnętrznego. Proponowane podejście pozwala na oszacowanie wartości stałych kalibracyjnych, a tym samym oznaczenia stężeń związków od heksanu do dodekanu. Tak więc permeacyjne dozymetry pasywne mogą być wykorzystane w analogicznym zakresie jak próbniki aktywne.