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Search results for: CURE KINETICS
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The shape of an ROC curve in the evaluation of credit scoring models
PublicationThe AUC, i.e. the area under the receiver operating characteristic (ROC) curve, or its scaled version, the Gini coefficient, are the standard measures of the discriminatory power of credit scoring. Using binormal ROC curve models, we show how the shape of the curves affects the economic benefits of using scoring models with the same AUC. Based on the results, we propose that the shape parameter of the fitted ROC curve is reported...
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Demagnetization of the core and reduction of power transformer inrush current
PublicationW artykule przedstawiono metodę ograniczenia prądów włączania transformatora energetycznego za pomocą demagnetyzacji rdzenia magnetycznego. Jako źródło energii do demagnetyzacji w proponowanej metodzie zastosowano kondensator. Do wytworzenia pola rozmagnesowującego wykorzystano uzwojenia robocze transformatora. Przeprowadzono obliczenia magnetyzmu szczątkowego rdzenia po demagnetyzacji dla różnych wartości pojemności, napięcia...
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Kinetics of photoinducet birefringence in the guest-host system of poly(methyl methacrylate)doped with azobenzene-containing crown ethers
PublicationWykazano występowanie fotoindukowanej dwójłomności dla klasy fotoaktywnych eterów koronowych składających się z reszty azobenzenu i giętkiego fragmentu oligo(oksyetylenowego) o różnej długości. Kinetyka fotoindukowanej dwójłomności była badana dla serii tych eterów koronowych rozpuszczonych w matrycy z polimetakrylanu metylu. Oczekiwano, że kształt cząsteczek koron zapewni względną swobodę reorientacji podczas izomeracji, niezależnie...
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Kinetics of molecular decomposition under irradiation of gold nanoparticles with nanosecond laser pulses—A 5-Bromouracil case study
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TiO2 Modified with Organic Acids for the Decomposition of Chlorfenvinphos under the Influence of Visible Light: Activity, Performance, Adsorption, and Kinetics
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Evaluation of Eucalyptus leaves as an adsorbent for decolorization of Methyl Violet (2B) dye in contaminated waters: Thermodynamic and Kinetics model
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The Effect of Polymer Microstructure on Encapsulation Efficiency and Release Kinetics of Citropin 1.1 from the Poly(ε-caprolactone) Microparticles
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Release kinetics and antimicrobial properties of the potassium sorbate-loaded edible films made from pullulan, gelatin and their blends
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Fully bio-based poly(propylene succinate) synthesis and investigation of thermal degradation kinetics with released gases analysis
PublicationOne of the most important information about polyesters is their thermal stability and phase transition tem- peratures. These characteristics give information about the promising behavior of the polyester during proces- sing. In this work, linear bio-based polyester polyols were prepared with the use of succinic acid and 1.3- propanediol (both with natural origin). As a polycondensation catalyst was used tetraisopropyl orthotitanate...
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Thermal utilization of meat and bone meals. Performance analysis in terms of drying process, pyrolysis and kinetics of volatiles combustion
PublicationA development of technology of thermal utilization requires a thorough knowledge of the physicochemical properties, as well as kinetics of combustion of volatiles and char. Due to waste management regulations the meat and bone meal (MBM) is regarded as biofuel constituting one of the alternatives to fossil fuels in the energy market. MBM is a heterogeneous material that may consist of several different fractions. The extensive...
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Isothermal Vulcanization and Non-Isothermal Degradation Kinetics of XNBR/Epoxy/XNBR-g-Halloysite Nanotubes (HNT) Nanocomposites
PublicationThe effect of several concentrations of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the vulcanization and degradation kinetics of XNBR/epoxy compounds were evaluated using experimental and theoretical methods. The isothermal vulcanization kinetics were studied at various temperatures by rheometry and differential scanning calorimetry (DSC). The results obtained indicated that the...
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Exploring multi-step glucose oxidation kinetics at GOx-functionalized nanotextured gold surfaces with differential impedimetric technique
PublicationFor a few past years, we can observe the enormous growth of investigations related to ultrasensitive electrochemical sensors capable of reliable determination of important body parameters and analytes. Utilized procedures rely on standard electrochemical methods, demanding electrode polarization, and information about the initial characteristics of the working electrode. More and more complex electrode materials are characterized...
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Kinetics of molecular decomposition under irradiation of gold nanoparticles with nanosecond laser pulses—A 5-Bromouracil case study
PublicationABSTRACT Laser illuminated gold nanoparticles (AuNPs) efficiently absorb light and heat up the surrounding medium, leading to versatile applications ranging from plasmonic catalysis to cancer photothermal therapy. Therefore, an in-depth understanding of the thermal, optical, and electron induced reaction pathways is required. Here, the electrophilic DNA nucleobase analog 5-Bromouracil (BrU) has been used as a model compound to...
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Photodegradation of single and mixture of parabens – Kinetic, by-products identification and cost-efficiency analysis
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Kinetic and equilibrium studies of the reaction of 2,4-dinitrophenyl-2,4,6-trinitrophenylmethane with cryptands in acetonitrile
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Modelling of the Baumann turbine stage operation Part II. Free and kinetic vibrations
PublicationIn this paper has been presented a methodology of validation a novel mathematical model dedicated to evaluation and prediction of material degradation and demage of steam turbine elements such as blades, valves and pipes due to three mechanisms: stress-corosion, high-temperature creep and low-cyclic fatigue. The validation concept is based on an experimental setup manufactured in the Laboratory of Faculty of Mechanical and Power...
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Effective sonophotocatalytic degradation of tetracycline in water: Optimization, kinetic modeling, and degradation pathways
PublicationHybrid advanced oxidation processes (AOPs) are gaining interest in degradation of variety of recalcitrant compounds for water and wastewater treatment, due to possible synergistic effects. The present study systematically evaluated the degradation of tetracycline (TC) with a sonophotocatalytic process combining acoustic cavitation (sonocavitation) and photocatalysis based on N-doped TiO2 catalyst. The TC degradation rate constant...
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Tendencies in abrasive machining with lapping kinematics - experimental studies
PublicationW pracy przedstawiono tendencje rozwoju obróbki ściernej z wykorzystaniem kinematyki docierania. Zaprezentowano wyniki badań szlifowania specjalnymi narzędziami w układzie docierarki jedno- i dwutarczowej.
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Technological aspects of microgrinding with single-disc lapping kinematics
PublicationPrzedstawiono wyniki badań mikroszlifowania powierzchni płaskich na docierarce jednotarczowej. Badano stan powierzchni narzędzia wykonanego na bazie mikroziaren diamentowych D65/50 naniesionych galwanicznie na podłoże stalowe. Analizowano wydajność obróbki oraz chropowatość powierzchni elementów ze stali 18G2A.
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VARIABLE KINEMATICS OF HONING PROCESS – INFLUENCE ON MACHINED WORKPIECE
PublicationSurface quality of holes plays an important role in machine manufacturing industry especially in the production of car engines and hydraulic cylinders. Investigations of honing process were carried out by 6 years on horizontal CNC Sunnen’s honing machine HTH 4000S, on vertical conventional honing machine WMW’s SZS 200 and on CNC milling machine of Haas VF 3SS with equipment of Honingtec for honing. Measurements of cylindricity...
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Genetics algorithms in multi-objective optimization of detection observer
PublicationW rozdziale przedstawia się możliwości zastosowania podejścia genetycznegodo zagadnień wielokryterialnej optymalizacji w przestrzeniach wielowymiaro-wych z wykorzystaniem koncepcji optymalności w sensie Pareto. Jako przykładilustrujący rozważane podejście daje się zadanie syntezy obserwatorów stanusłużących wykrywaniu błądów występujących w układzie sterowania bezzałogowe-go statku latającego oraz w układzie napędowym jednostki...
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Heteroleptic cadmium(II) complex, potential precursor for semiconducting CdS layers. Thermal stability and non-isothermal decomposition kinetics
PublicationW ramach pracy zweryfikowano stabilność termiczną [Cd{SSi(OBut)3}(S2CNEt2)]2 - potencjalnego prekursora do otrzymywania warstw półprzewodnikowych CdS. Równocześnie przeprowadzono analizę kinetyki rozkładu za pomocą różnych metod izokonwersyjnych zaproponowanych przez Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose i Friedmanna w wyniku czego wyznaczono całkowity tryplet kinetyczny dla omawianego kompleksu.
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Adsorption Kinetics of Acid Dye Acid Red 88 onto Magnetic Multi‐Walled Carbon Nanotubes‐Fe3C Nanocomposite
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The kinetics of phenol decomposition under UV irradiation with and without H2O2 on TiO2, Fe–TiO2 and Fe–C–TiO2 photocatalysts
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In-situ FTIR study of reaction mechanism and chemical kinetics of a Xundian lignite during non-isothermal low temperature pyrolysis
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Bifunctional sulfur-silicon podands as new nucleophilic ionophores in acyl transfer reactions. Influence of monovalent cations on the reaction kinetics
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The reaction of substituted N-phenacyl-pyridinium bromides in the pyridine ring with DABCO and DBU in water and DMSO. Kinetics and DFT studies
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Sonocatalytic degradation of Bisphenol A from aquatic matrices over Pd/CeO2 nanoparticles: Kinetics study, transformation products, and toxicity
PublicationIn this work, different ratios of palladium – cerium oxide (Pd/CeO2) catalyst were synthesized and characterized, while their sonocatalytic activity was evaluated for the degradation of the xenobiotic Bisphenol A (BPA) from aqueous solutions. Sonocatalytic activity expressed as BPA decomposition exhibited a volcano-type behavior in relation to the Pd loading, and the 0.25Pd/CeO2 catalyst characterized by the maximum Pd dispersion...
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Chemical investigation on the mechanism and kinetics of the atmospheric degradation reaction of Trichlorofluoroethene by OH⋅ and Its subsequent fate in the presence of O2/NOx
PublicationThe M06-2X/6-311++G(d,p) level of theory was used to examine the degradation of Trichlorofluoroethene (TCFE) initiated by OH⋅ radicals. Additionally, the coupled-cluster single-double with triple perturbative [CCSD(T)] method was employed to refine the single-point energies using the complete basis set extrapolation approach. The results indicated that OH-addition is the dominant pathway. OH⋅ adds to both the C1 and C2 carbons,...
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Enhanced electrochemical kinetics of highly-oriented (111)-textured boron-doped diamond electrodes induced by deuterium plasma chemistry
PublicationNovel highly-oriented (111)-textured boron-doped diamond electrodes (BDDD) featuring high electrochemical activity and electrode stability toward electrochemical analytics were fabricated by deuterium-rich microwave plasma CVD. The high flux deuterium plasma-induced preferential formation of (111)-faceted diamond as revealed by XRD. The highly-oriented diamond surface exhibited improved boron dopant incorporation and activation,...
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Development, characterization and evaluation of composite adsorbent for the adsorption of crystal violet from aqueous solution: Isotherm, kinetics, and thermodynamic studies
PublicationThe purpose of this work focuses on the production and investigations of a new composite material as alternative low-cost adsorbent for the removal of crystal violet (CV) dye from waste solution. The production method was performed by in-situ thermal activation technology via extrusion process of polymer wastes containing tire rubber (50 wt%) and polyurethane foam (50 wt%) using single-screw extruder under processing temperature...
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Kinetic flux vector splitting scheme for solving non-reactive multi-component flows
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Kinetic characterization of hydrogen sulfide inhibition of suspended anammox biomass from a membrane bioreactor
PublicationThe inhibition effects of hydrogen sulfide (H2S) on anammox-enriched biomass from a laboratory membrane reactor were analyzed in a series of batch respirometric experiments. The determined half maximal inhibitory concentration (IC50) was 4.67 mg H2S-S L−1 at the constant pH = 7.0 and the total sulfide concentration varying between 1 and 15 mg TS-S L−1. In another test, the IC50 was found to be 4.25 mg H2S-S L−1 under a constant...
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Numerical Investigation of Nuclear Reactor Kinetic and Heat Transfer Fractional Model with Temperature Feedback
PublicationAbstract—In the paper, the numerical results concerning the kinetics and proposed heat exchange models in nuclear reactor based on fractional calculus are presented for typical inputs. Two fractional models are proposed and compared with the model based on ordinary derivative. The first fractional model is based on one of the generalized Cattaneo equations. The second one is based on replacing the ordinary to fractional order of...
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Mechanism of phenol photodegradation in the presence of pure and modified-TiO2: A review
PublicationW publikacji został przedstawiony przegląd i podsumowanie literaturowe na temat fotokatalitycznego utleniania fenolu w obecności TiO2. Opisano mechanizm rozkładu fenolu i tworzenia się rodników OH.
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Core-Shell Nanoparticles with Hyperbranched Poly(arylene-oxindole) Interiors
PublicationCore-shell type star polymers composed of poly(tert-butyl acrylate) (poly(t-BuA)) arms and 100% hyperbranched poly(arylene-oxindole) interiors were synthesized via the "core-first" method. Atom transfer radical polymerization of t-BuA initiated by 2-bromopropionyl terminal groups of the hyperbranched core was applied for the synthesis of the stars. The resultant star structures were characterized by gel permeation chromatography...
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Diagnostic pure transgastric NOTES in an intensive therapy unit patient
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Core outcomes measures in dental computer vision studies (DentalCOMS)
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Soft-core processors as SoC prototyping solution for cryptographic application
PublicationArtykuł przedstawia metodę wykorzystania procesora soft-core w zastosowaniach kryptografii. Przedstawione są problemy oraz zagadnienia, które udowadniają potrzebę wprowadzania silnych zabezpieczeń na niskim poziomie systemu sprzętowo-programowego. Istniejące zagrożenia stanowią wyzwanie dla projektantów bezpiecznych systemów, a sprzętowa realizacja obsługi algorytmu kryptograficznego AES jest dobrym przykładem rozwiązania tych...
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Beyond clinical care: the pharmacoeconomic and research roles of pharmacists in Poland
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Nationwide survey on volunteers' training in hospice and palliative care in Poland
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Thermodynamic and electromagnetic properties of hard-core charged bosons on a lattice
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The Usefulness of Cyclic Diamidines with Different Core-substituents as Antitumor Agents
PublicationA series of related polycationic compds. has been screened for potential antitumor activity by the NCI's in vitro testing (one dose primary anticancer assay and the NCI-60 full panel screening). The GI50 values of triazines 3 and 4 are on av. 1.9 μM and 2.4 μM, resp. Furan 8 deserves mention too (1.9 μM). The biol. test results showed that carbazole 10 possessed cytotoxic activity in the nanomolar range, much better than...
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Symmetrical and unsymmetrical azomethines with thiophene core: structure–properties investigations
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Spectroscopic and Physicochemical Investigations of Azomethines with Triphenylamine Core towards Optoelectronics
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Cinnamon as a Useful Preventive Substance for the Care of Human and Plant Health
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Biopsychosocial complexity measured by health care needs in controlled acromegaly
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Needs of Older People Attending Day Care Centres in Poland
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Core spliceosomal Sm proteins as constituents of cytoplasmic mRNPs in plants
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Core spliceosomal Sm proteins as constituents of cytoplasmic mRNPs in plants
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