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Search results for: PVA/TIO2
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Preparation, characterization and photocatalytic activity of TiO2 microspheres decorated by bimetallic nanoparticles
PublicationComposite photocatalysts that consist of TiO2and noble metal nanostructures have been considered tobe the promising and pivotal material for accessible enhancement of the efficiency in the photocatalyticprocess carried out in the aqueous and gas phases. In this work we fabricated porous TiO2microspheresthrough a hydrothermal process followed by photochemical reduction of noble metal nanoparticles atthe TiO2surface. The morphology...
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Transparent TiO2 nanotubes supporting silver sulfide for photoelectrochemical water splitting
PublicationDifferences between photoelectrochemical and electrochemical activity were thoroughly investigated for the oxygen evolution reaction mediated by Ag2S deposited on two types of ordered titania substrates. Titanium dioxide nanotubes were fabricated by anodization of magnetron sputtered Ti films on ITO-coated glass substrates or directly from Ti foil. Further, Ag2S deposition on the nanotubes was carried out using successive ionic...
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Resistance noise in tio2-based thin film gas sensors underultraviolet irradiation
PublicationBadano możliwości wykorzystania fluktuacji rezystancji w cienkich warstwach TiO2 do wykrywania gazów. Pomiary przeprowadzono, gdy próbka była oświetlona promieniowaniem ultrafioletowym o długości 370nm, w obecności gazu H2S. Stwierdzono, że fluktuacje rezystancji są indukowane promieniowaniem ultrafioletowym i pozwalają na wykrycie obecności H2S w stężeniu do 1.5 ppm.
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Modifiers for Medical Grade Polymeric Systems used in FDM 3D Printing - Short Review
PublicationFDM 3D printing could find an application in the wide range of biomedical applications. Unfortunately, the quantity of polymeric biomaterials suitable to processing into filaments is limited. The most frequently used biomaterials for medical constructs such as bone grafts, soft tissue scaffolds or another DDS include PCL, PLA, PVA, HPC, EVA copolymer, EC and TPUs. Various modifiers such as TCP, HA, TEC, MMC could be applicated...
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Preparation and characterization of biodegradable and compostable PLA/TPS/ESO compositions
PublicationIn this study, biodegradable and compostable compositions, derived from totally natural feedstock/raw materials, namely polylactide (PLA), potato thermoplastic starch (TPS) and plant glycerin have been made by melt extrusion with epoxydized soybean oil (ESO) as reactive modifier in order to improve PLAs ductility and reduce the products cost without compromising biodegradation. The obtained PLA/mTPS(0,5ESO)[75/25] and PLA/ mTPS(2ESO)[75/25]...
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POM/EVA Blends with Future Utility in Fused Deposition Modeling
PublicationPolyoxymethylene (POM) is one of the most popular thermoplastic polymers used in the industry. Therefore, the interest in its potential applications in rapid prototyping is understandable. Nevertheless, its low dimensional stability causes the warping of 3D prints, limiting its applications. This research aimed to evaluate the effects of POM modification with ethylene-vinyl acetate (EVA) (2.5, 5.0, and 7.5 wt.%) on its processing...
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Leakage detection and localisation in drinking water distributionnetworks by MultiRegional PCA
PublicationMonitoring is one of the most important steps in advanced control of complex dynamic systems. Precise information about systems behaviour, including faults indicating, enables for efficient control. The paper describes an approach to detection and localisation of pipe leakage in Drinking Water Distribution Systems (DWDS) representing complex and distributed dynamic system of large scale. Proposed MultiRegional Principal Component...
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Preparation of double-sided self-adhesive tape Si-PSA
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Analysis of thoracic regional impedance changes using PCA approach
PublicationA multichannel impedance and one lead electrocardiographic recording system has been developed. The impedance measurement unit is built using a four-electrode technique. It consists of a sinusoidal, 40 kHz, current source and five measurement channels. Circumferential current electrodes have been located at a neck and an abdomen. Voltagemeasurement disk electrodes formed five two-electrode measurement ports. The impedance change...
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Prediction of the properties of PVD/CVD coatings with the use of FEM analysis
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The wear of PVD coated elements in oscillation motion at high temperature
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Performance of the PVT solar collector operated with water-Al2O3 nanofluid
PublicationAn experimental investigation of the hybrid module photovoltaic panel -solar collector (PVT) cooled by water-Al2O3 nanofluids has been conducted. The weight fractions of the nanoparticles were 1% and 3%. Thermal efficiency, power efficiency and overall efficiency have been determined for artificial source of light and sunlight. No noticeable effect of the nanoparticle concentration on the overall efficiency of the PVT module has...
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PERFORMANCE OF THE PVT SOLAR COLLECTOR OPERATED WITH WATER –AL2O3 NANOFLUID
PublicationAn experimental investigation of the hybrid module photovoltaic panel -solar collector (PVT) cooled by water-Al2O3 nanofluids has been conducted. The weight fractions of the nanoparticles were 1% and 3%. Thermal efficiency, power efficiency and overall efficiency have been determined for artificial source of light and sunlight. No noticeable effect of the nanoparticle concentration on the overall efficiency of the PVT module has...
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Improving flexibility and performance of PVM applications by distributed partial evaluation
PublicationA new framework for developing both flexible and efficient PVM applications is described. We propose Architecture Templates Interface (ATI) that allows to control application granularity and parallelism. To ensure high application efficiency we extend partial evaluation strategy into domain of distributed applications obtaining Distributed Partial Evaluation (DPE). Both ATI and DPE were implemented using a new distributed programming...
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Diagnostyka i identyfikacja procesu przy użyciu AdMS-PCA
PublicationArtykuł dotyczy diagnostyki i identyfikacji procesu przy użyciu adaptacyjnego, wieloskalowego rozszerzenia PCA - Adaptive Multiscale Principal Component Analysis (AdMS-PCA). Przeprowadzona została analiza własności AdMS-PCA istotnych dla diagnostyki i identyfikacji. Zauważono wadę części adaptacyjnej metody, która ogranicza jej praktyczne zastosowanie. Zaproponowano modyfikację poprzez wprowadzenie algorytmu nadzorującego adaptację....
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Novel decahedral TiO2 photocatalysts modified with Ru or Rh NPs: Insight into the mechanism
PublicationNovel decahedral TiO2 modified with Ru or Rh NPs were successfully synthesized by hydrothermal method. The effect of metal type as well as amount of noble metal precursor (0.05, 0.1, 0.2, 0.3 and 0.5 wt.%) on the photocatalytic activity were investigated. Decahedral TiO2 decorated by Ru and Rh nanoparticles was prepared by photodeposition method, whereas Rh doped TiO2 was obtained by onestep hydrothermal method with introduction...
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Highly Active TiO2 Microspheres Formation in the Presence of Ethylammonium Nitrate Ionic Liquid
PublicationSpherical microparticles of TiO2 were synthesized by the ionic liquid-assisted solvothermal method at different reaction times (3, 6, 12, and 24 h). The properties of the prepared photocatalysts were investigated by means of UV-VIS diffuse-reflectance spectroscopy (DRS), Brunauer–Emmett–Teller (BET) surface area measurements, scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), and X-ray photoelectron spectroscopy...
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Synergistic effect of TiO2 photocatalytic advanced oxidation processes in the treatment of refinery effluents
PublicationDifferent types of photolytic and photocatalytic advanced oxidation processes (AOPs) were used for treatment of refinery effluents from bitumen production. The treatment efficiency was evaluated by analyzing chemical oxygen demand (COD), biological oxygen demand (BOD5), volatile organic compounds (VOCs) and sulfide ions concentration. The studies revealed a synergistic effect of application of external oxidants (O3, H2O2, O3/H2O2)...
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Electrophoretic Deposition and Characteristics of Chitosan–Nanosilver Composite Coatings on a Nanotubular TiO2 Layer
PublicationThe surface treatment of titanium implants has been applied mainly to increase surface bioactivity and, more recently, to introduce antibacterial properties. To this end, composite coatings have been investigated, particularly those based on hydroxyapatite. The present research was aimed at the development of another coating type, chitosan–nanosilver, deposited on a Ti13Zr13Nb alloy. The research comprised characterization of the...
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PREPARATION AND CHARACTERIZATION OF CoFe2O4/TiO2-PANI HYBRID NANOCOMPOSITE WITH MAGNETIC AND PHOYOCATALYTIC ACTIVITY
PublicationHybrid nanocomposites consisting of inorganic component and organic conducting polymer are promising materials, which can be applied in heterogeneous photocatalysis. Titanium(IV) oxide is widely used photocatalysts due to its non-toxicity, low cost and chemical stability. The main disadvantage of TiO2 is low photocatalytic activity under visible light. Conducting polymers, also known as conjugated polymers are polymer materials...
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Formation of the hollow nanopillar arrays through the laser-induced transformation of TiO2 nanotubes
PublicationIn the following article, we present a simple, two-step method of creating spaced, hollow nanopillars, from the titania nanotube arrays via pulsed laser-treatment. Due to the high ordering of the structure, the prepared material exhibits photonic properties, which has been shown to increase the overall photoefficiency. The optical and morphological changes in the titania nanotubes after pulsed laser-treatment with 532, 355, and...
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Scalable Route toward Superior Photoresponse of UV-Laser-Treated TiO2 Nanotubes
PublicationTitanium dioxide nanotubes gain considerable attention as a photoactive material due to chemical stability, photocorrosion resistance, or lowcost manufacturing method. This work presents scalable pulsed laser modification of TiO2 nanotubes resulting in enhanced photoactivity in a system equipped with a motorized table, which allows for modifications of both precisely selected and any-large sample area. Images obtained from scanning...
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Preparation and Characterization of Defective TiO2. The Effect of the Reaction Environment on Titanium Vacancies Formation
PublicationAmong various methods of improving visible light activity of titanium(IV) oxide, the formation of defects and vacancies (both oxygen and titanium) in the crystal structure of TiO2 is an easy and relatively cheap alternative to improve the photocatalytic activity. In the presented work, visible light active defective TiO2 was obtained by the hydrothermal reaction in the presence of three different oxidizing agents: HIO3, H2O2, and...
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TiO2 photoactivity in vis and UV light: The influence of calcination temperature and surface properties
PublicationPrzygotowano serię fotokatalizatorów w postaci tlenku tytanu (IV) kalcynowanych w różnych temperaturach od 350 do 750˚C. Charakterystyka fotokatalizatorów za pomocą metod XRD, UV-Vis/DRS, FTIR, XPS, BET oraz BJH wykazała, że próbka TiO2 aktywna w świetle widzialnym posiadała strukturę anatazu, powierzchnię właściwą ok. 200 m2/g, absorbowała światło o długości fali λ>400 nm oraz zawierała 10,1 % at. węgla (wiązanie C-C). Aktywność...
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Detoxification of parabens using UV-A enhanced by noble metals—TiO2 supported catalysts
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A tight-binding model of a carbon nanotube interacting with TiO2 rutile (110) surface
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Influence of geometry and annealing temperature in argon atmosphere of TiO2 nanotubes on their electrochemical properties
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Influence of Thermal Modification and Morphology of TiO2 Nanotubes on Their Electrochemical Properties for Biosensors Applications
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Electrochemical stability of TiO2 nanotubes deposited with silver and gold nanoparticles in aqueous environment
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Photocatalytic water disinfection under the artificial solar light by fructose-modified TiO2
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A preliminary study on antifungal effect of TiO2-based paints in natural indoor light
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Influence of TiO2 hydrophilicity on the photocatalytic decomposition of gaseous acetaldehyde in a circulated flow reactor
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Application of carbon-coated TiO2 for decomposition of methylene blue in a photocatalytic membrane reactor
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Interfacial Charge Transfer Complexes in TiO2-Enediol Hybrids Synthesized by Sol–Gel
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Enhanced Degradation of Ethylene in Thermo-Photocatalytic Process Using TiO2/Nickel Foam
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Effect of UV radiation and chitosan coating on the adsorption-photocatalytic activity of TiO2 particles
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Photocatalytic Degradation of 4,4′-Isopropylidenebis(2,6-dibromophenol) on Sulfur-Doped Nano TiO2
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Preparation and photocatalytic activity of boron-modified TiO2 under UV and visible light
PublicationOtrzymano TiO2 domieszkowany borem i wyznaczono jego aktywność fotokatalityczną w zakresie światła UV i Vis. Katalizatory otrzymano metodą zol-żel lub poprzez ucieranie dwutlenku tytanu z prekursorami B. Jako źródło boru zastosowano kwas borowy lub ester trietylowy kwasu borowego. Fotoaktywność próbek badano w reakcji degradacji fenolu (Co = 0,21 mmol/dm3 ) w zakresie światła Vis lub UV. Obecność węgla i boru we wszystkich przygotowanych...
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Silver-doped TiO2 prepared by microemulsion method: surface properties, bio- and photoactivity
PublicationOtrzymane fotokatalizatory typu Ag-TiO2 wykazywały wyższą aktywność w reakcjach fotodegradacji fenolu w obecności promieniowania z zakresu UV oraz światła widzialnego w porównaniu z komercyjnym katalizatorem Degussa P25 oraz czystym niedomieszkowanym TiO2, otrzymanym w mikroemulsji woda-AOT-cykloheksan. Powierzchnia właściwa (BET) otrzymanych katalizatorów wynosiła od 100 do 160 m2/g. Na podstawie analizy rentgenowskiej (XRD) stwierdzono,...
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Characterization of TiO2 Modified with Bimetallic Ag/Au Nanoparticles Obtained in Microemulsion System
PublicationFotokatalizatory TiO2 modyfikowane nanocząstkami bimetalicznymi Ag/Au przygotowano metodą mikroemulsyjną w układzie woda/surfaktant/cykloheksan. Aktywność fotokatalityczna próbek Ag/Au-TiO2 oszacowano przez wyznaczenie stopnia degradacji fenolu pod wpływem światła VIS. Fenol został użyty jako model zanieczyszczeń, ponieważ jest substancją niebezpieczną dla środowiska. Najwyższą aktywność w zakresie światła widzialnego wykazała...
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Photosensitization of TiO2 and SnO2 by Artificial Self-Assembling Mimics of the Natural Chlorosomal Bacteriochlorophylls
PublicationOf all known photosynthetic organisms, the green sulfur bacteria are able to survive under the lowest illumination conditions due to highly efficient photon management and exciton transport enabled by their special organelles, the chlorosomes, which consist mainly of self-assembled bacteriochlorophyll c, d, or e molecules. A challenging task is to mimic the principle of self-assembling chromophores in artificial light-harvesting...
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Porowate nanostruktury anatazu wytwarzane z Ti oraz TiO2 metodą PLD
PublicationNiniejsza praca dotyczy wytwarzania cienkich warstw dwutlenku tytanu metodą PLD. Za pomocą technik spektroskopowych zbadany został wpływ wartości ciśnienia gazu osłonowego na otrzymywane struktury krystaliczne w warstwach. Obserwowano także zależność uzyskanych faz krystalicznych od rodzaju odparowywanego materiału.
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The effect of nanoparticles size on photocatalytic and antimicrobial properties of Ag-Pt/TiO2 photocatalysts
PublicationAg-Pt-modified TiO2 nanocomposites were synthesized using the sol–gel method. Bimetallic modified TiO2 nanoparticles exhibited improved photocatalytic activity under visible-light irradiation, better than monometallic Ag/TiO2 and Pt/TiO2 nanoparticles (NPs). All modified powders showed localized surface plasmon resonance (LSPR) in visible region. The photocatalysts’ characteristics by X-ray diffractometry (XRD), scanning transmission...
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Preparation and characterization of Pt–N/TiO2 photocatalysts and their efficiency in degradation of recalcitrant chemicals
PublicationSeries of Pt–N/TiO2 photocatalysts were synthesized using the sol–gel method. The photocatalysts’ characteristics by X-ray diffractometry (XRD), scanning transmission electron microscopy (STEM), diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) showed that sample with the molar ratio Ti:N equal 1:4 and platinum nanoparticles size of about 3 nm had anatase structure, about 94 m2/g specific surface area...
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Gallic Acid-Functionalized, TiO2-Based Nanomaterial—Preparation, Physicochemical and Biological Properties
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Modeling of TiO2-Based Electron-Selective Contacts for Crystalline Silicon Solar Cells
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Bifunctional catalyst based on molecular structure: Spherical mesoporous TiO2 and gCN for photocatalysis
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Effect of sol composition on the properties of TiO2 powders obtained by the sol-gel method
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Boosting of Antibacterial Performance of Cellulose Based Paper Sheet via TiO2 Nanoparticles
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Effect of brookite on the photocatalytic properties of mixed-phase TiO2 obtained at a higher temperature
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