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Search results for: AOR reactions
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Spinel of Nickel-Cobalt Oxide with Rod-Like Architecture as Electrocatalyst for Oxygen Evolution Reaction
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Electroactive heterojunctions of iron-based compounds in oxygen evolution reaction—Insight into synergy and mechanism
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Impedance of cation-coupled electron transfer reaction: teoretical description of one pathway process
PublicationPrzyjęto możliwość występowanie dwóch wzajemnie sprzężonych reakcji. Opisana została impedancja sprzężonej reakcji przeniesienia elektronu z kationem. Wyznaczony został również model elektrycznego schematu zastępczego. Całkowita impedancja Faradayowska jest sumą impedancji przeniesienia elektronu i impedancji przeniesienia kationu. Przykłady pomiaru impedancyjnego w warunkach potencjostatycznych i potencjodynamicznych zostały omówione....
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The Influence of External Additional Loading on the Muscle Activity and Ground Reaction Forces during Gait
PublicationAsymmetrical external loading acting on the usculoskeletal system is generally considered unhealthy. Despite this knowledge, carrying loads in an asymmetrical manner like carrying on one shoulder, with one hand, or on the strap across the torso is a common practice. This study is aimed at presenting the effects of the mentioned load carrying methods on muscle activity assessed by using thermal field and ground reaction forces....
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Human awareness versus Autonomous Vehicles view: comparison of reaction times during emergencies
PublicationHuman safety is one of the most critical factors when a new technology is introduced to the everyday use. It was no different in the case of Autonomous Vehicles (AV), designed to replace generally available Conventional Vehicles (CV) in the future. AV rules, from the start, focus on guaranteeing safety for passengers and other road users, and these assumptions usually work during normal traffic conditions. However, there is still...
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Application of Cohen´s class time-frequency distributions in the Belousov-Zhabotinsky reaction analysis
PublicationPrzedstawiono rezultaty spektralnej analizy rejestrów Biełousowa-Żabotyńskiego za pomocą czasowo-częstotliwościowych metod analizy sygnałów należących do klasy Cohen´a. Przykładowy rejestr zmian potencjału elektrody bromo-selektywnej został poddany analizie z wykorzystaniem rozkładu Wignera-Ville´a oraz rozkładu stożkowego. Zastosowanie powyższych algorytmów pozwoliło na uzyskanie spektrogramów przedstawiających zależność pomiędzy...
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Air Pollution: Monitoring
PublicationThe entry presents an overview of the issues in the field of air pollution monitoring. At the beginning, the general objectives of air monitoring, ambient air quality standards for so-called criteria pollutants, and their sources are discussed. In the next part, both analytical methods and instruments for monitoring of ambient air and stack gases are briefly presented. Additionally, other approaches used in air pollution monitoring,...
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Photocatalytic Air Purification
PublicationW publikacji zostały omówione mechanizmy i wpływ różnych czynników na fotokatalityczne usuwanie zanieczyszczeń powietrza, takich jak lotne związki organiczne (VOC), NOx i SO2. Został dokonany przegląd artykułów i patentów dotyczących przygotowywania fotokatalizatorów i technik ich osadzania na nośnikach. Zaprezentowane zostały przykłady fotoreaktorów przystosowanych do pracy w fazie gazowej. Część opisanych reaktorów może być użyta...
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Study of oxygen electrode reactions on symmetrical porous SrTi0.30Fe0.70O3-δ electrodes on Ce0.8Gd0.2O1.9 electrolyte at 800 °C–500 °C
PublicationIron doped strontium titanates (SrTi1-xFexO3-δ) are an interesting mixed ionic-electronic conductor model used to study basic oxygen reduction/oxidation reactions. In this work, we performed an impedance spectroscopy study on symmetrical porous SrTi0.30Fe0.70O3-δ (STF70) electrodes on a ceriabased electrolyte. The sample was measured in varying oxygen concentration: from 0.3% to 100% in 800 °C - 500 °C temperature range. Low polarisation...
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Multisine impedimetric probing of biocatalytic reactions for label-free detection of DEFB1 gene: How to verify that your dog is not human?
PublicationAlbert is a dog (Canis familiaris), but he does not realize this. Albert loves human food (and beer), watching movies on the internet, sleeping in bed, and more. But he should not do all these things. To convince him that, we have desinged a test procedure. The DEFB1 gene is unique to human species. Detecting its presence from saliva and in short periods may offer an advantage in the field of forensic medicine, and influence Albert’s...
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Thermodynamics and Intermolecular Interactions of Nicotinamide in Neat and Binary Solutions: Experimental Measurements and COSMO-RS Concentration Dependent Reactions Investigations
PublicationIn this study, the temperature-dependent solubility of nicotinamide (niacin) was measured in six neat solvents and five aqueous-organic binary mixtures (methanol, 1,4-dioxane, acetonitrile, DMSO and DMF). It was discovered that the selected set of organic solvents offer all sorts of solvent effects, including co-solvent, synergistic, and anti-solvent features, enabling flexible tuning of niacin solubility. In addition, differential...
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Gender belief systems through the lens of culture—Differences in precarious manhood beliefs and reactions to masculinity threat in Poland and Norway.
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FTIR, NMR and kinetic studies of proton transfer reactions from nitro-substituted diarylmethanes to N-bases with guanidine character
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Advanced oxidation processes (AOPs) based wastewater treatment - unexpected nitration side reactions - a serious environmental issue: A review
PublicationChemical compounds containing nitro group (nitro-products) are a one of toxic by-products, that can be formed during wastewater treatment processes. In case of presence of nitrite or nitrate ions, the formation of nitro-products during advanced oxidation processes (AOPs) is very common. It is caused by the reactive nitrogen species (RNs) such as nitrate radical (NO3•), nitrite radical (NO2•), nitrogen oxide radical (NO•) and peroxynirite...
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Hybrid Modulation for Modular Voltage Source Inverters with Coupled Reactors
PublicationThis paper proposes and discusses a concept of a hybrid modulation for the control of modular voltage source inverters with coupled reactors. The use of coupled reactors as the integrating elements leads to significant reduction in the size and weight of the circuit. The proposed modulation combines novel coarsely quantized pulse amplitude modulation (CQ-PAM) and innovative space-vector pulse width modulation (SVPWM). The former...
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Absolute Photoabsorption Cross-Sections of Methanol for Terrestrial and Astrophysical Relevance
PublicationWe investigate the methanol absorption spectrum in the range 5.5–10.8 eV to provide accurate and absolute cross-sections values. The main goal of this study is to provide a comprehensive analysis of methanol electronic-state spectroscopy by employing high-resolution vacuum ultraviolet (VUV) photoabsorption measurements together with state-of-the-art quantum chemical calculation methods. The VUV spectrum reveals several new features...
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36-pulse rectifier with a system of coupled three-phase reactors
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Electron-impact dissociation of molecular hydrogen: benchmark cross sections
PublicationWe present a joint experimental and theoretical investigation of a fundamental process in atomic and molecular physics: electron impact excitation of molecular hydrogen’s (H2) most dominant transition (X1Σg+ → b3Σu+). Excitation of this state is by far the main channel that causes the dissociation of H2 into H + H atoms at low energies. The Convergent Close-Coupling (CCC) calculations predicted significant, more than factor of...
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Modular multipulse voltage source inverters with integrating coupled reactors
PublicationA novel approach to the voltage source inverters (VSI) construction is presented in the paper. The invented inverter structures allow to operate several DC/AC converters in parallel resulting in lower voltage distortions at extremely low switching frequency. The research presented in the paper describes such a parallel operation of the VSI’s which is possible thanks to the use of coupled inductors. The eighteen-pulse and twenty-four-pulse...
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Low harmonic multipulse voltage converters using coupled reactors
PublicationThis paper presents a novel approach to the multi pulse voltage converters (VC), especially voltage source inverters (VSI) and matrix converters (MC) based on several typical identical modules connected in parallel using coupled reactors. Such arrangements resulting in lower voltage distortions at extremely low switching frequency. The proposed arrangement was validated by simulation. Laboratory models of 18- and 24pulse 3-level...
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Cross sections for electron collision with five-membered ring heterocycles
PublicationCałkowity absolutny przekrój czynny (TCS) na rozpraszanie elektronów na cząsteczce izoksazolu (CH)3NO, został zmierzony przy wykorzystaniu liniowej techniki transmisyjnej dla energii zderzenia od 1 do 400 eV. Zależność energetyczna funkcji TCS jest typowa dla cząsteczek silnie polarnych; w całym zakresie badanych energii wartość TCS maleje wraz ze wzrostem energii zderzenia. Zaobserwowano wąskie struktury rezonansowe w okolicy...
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Total cross sections for electron scattering with some C3 hydrocarbons
PublicationPrzedstawiono absolutne całkowite przekroje czynne na rozpraszanie elektronów dla dwóch izomerów C3H4 oraz C3H8 w zakresie energii 0.5-37- eV. Przedyskutowano efekt izomeryczny oraz wpływ krotności wiązania C-C.
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Advanced vanadium modified steels for high pressure hydrogen reactors
PublicationPrzedstawiono nową generację stali chromowo-molibdenowych zmodyfikowanych wanadem, przeznaczonych do budowy wodorowych reaktorów i porównano ze stalami konwencjonalnymi. Opisano mikrostrukturę, właściwości i zastosowanie stali. Podkreślono wpływ mikrostruktury nowych stali na przebieg degradacji środowiskowej.
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Semiempirical analysis of electron scattering cross sections in N2O and CO2.
PublicationPorównano współczynniki transportu wyznaczone doświadczalnie w eksperymentach rojowych z wyznaczonymi teoretycznie z rozwiązania równania Boltzmana dla N2O i CO2. Badano wpływ przekrojów czynnych na wzbudzenia wibracyjne w tych gazach, w zakresie niskich energii na zgodność tych współczynników transportu.
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Dissociative electron attachment and anion-induced dimerization in pyruvic acid
PublicationWe report partial cross sections for the dissociative electron attachment to pyruvic acid. A rich fragmentation dynamics is observed. Electronic structure calculations facilitate the identification of complex rearrangement reactions that occur during the dissociation. Furthermore, a number of fragment anions produced at electron energies close to 0 eV are observed, that cannot originate from single electron-molecule collisions....
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Generalization of Kramers-Krönig relations for evaluation of causality in power-law media
PublicationClassical Kramers-Krönig (K–K) relations connect real and imaginary parts of the frequency-domain response of a system. The K–K relations also hold between the logarithm of modulus and the argument of the response, e.g. between the attenuation and the phase shift of a solution to a wave-propagation problem. For square-integrable functions of frequency, the satisfaction of classical K–K relations implies causality in the time domain....
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THE INFLUENCE OF WATER-LAND RELATIONS ON THE LANDSCAPE AND ARCHITECTURE OF THE VISTULA DELTA (POLAND)
PublicationThe Vistula Delta is unique region of water domination. In this part of Europe, historic rural assumptions have been developing since the 12th century. Practically, it can be said that most of the systems were related to the coexistence of the human and the water element. Relations of water and land, developed specific types of villages such as a water-based village. Water landscape; polders, canals, dikes and rivers, hydro-technical...
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Improving the Accuracy in Sentiment Classification in the Light of Modelling the Latent Semantic Relations
PublicationThe research presents the methodology of improving the accuracy in sentiment classification in the light of modelling the latent semantic relations (LSR). The objective of this methodology is to find ways of eliminating the limitations of the discriminant and probabilistic methods for LSR revealing and customizing the sentiment classification process (SCP) to the more accurate recognition of text tonality. This objective was achieved...
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Determination of bisphenol A in size fractions of indoor dust from several microenvironments
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Społeczna odpowiedzialność firm - narzędzie public relations czy coś więcej?
PublicationArtykuł stawia pytanie o miejsce działań Corporate Social Resposibility [ CSR} w strategii przedsiębiorstw i zależności między public relations a CSR w realizacji celów przedsiębiorstwa - między innymi kreowania wizerunku, budowania reputacji.
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Influence of nitrogen and organic matter fractions on wastewater treatment in treatment wetland
PublicationMunicipal wastewater contains both biodegradable and non-degradable pollutants. Moreover, they are present in dissolved, colloidal and particulate forms. These fractions are characterised by various decomposition rates, hence their bioavailability during microbial respiration. It was confirm that biological degradation rate in terms of COD reduction is influenced by particle size speciation. Therefore, the objective of the study...
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The impact of technological and structural changes in the national economy on the labour-capital relations
PublicationThe aim of the research presented in this paper is to present the relations between labour and capital in the national economy, resulting from technological and structural changes taking place in the years 1991 to 2008. The structure of the paper is as follows. It first presents the functional determinants for the Polish economy in 1991-2008 affecting the phenomenon subject to study. Then it presents the preliminary analysis of...
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Fem analysis of cosserat plates and shells based on some constitutive relations
PublicationPrzeprowadzono studium doboru mikropolarnych współczynników konstytutywnych w pewnym modelu płyty Cosseratów. Wyznaczono ograniczenia na ich wartości i przeprowadzono parametryczną analizę wpływu tych współczynników na geometrycznie nieliniowe deformacje powłok z ortogonalnymi przecięciami płatów.
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Extended non-linear relations of elastic shells undergoing phase transitions
PublicationThe non-linear theory of elastic shells undergoing phase transitions was proposed by two first authors in J. Elast. 79, 67-86 (2004). In the present paper the theory is extended by taking into account also the elastic strain energy density of the curvilinear phase interface as well as the resultant forces and couples acting along the interface surface curve itself. All shell relations are found from the variational principle of...
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Fully Isohexide-Based Polyesters: Synthesis, Characterization, and Structure-Properties Relations
PublicationHere we present a novel series of biobasedpolyesters solely based on renewable isohexide building blocks,synthesized via melt polymerization. The recently developedisoidide dicarboxylic acid (IIDCA) was polymerized with rigidrenewable diols such as isosorbide (IS), isomannide (IM),isoidide (II), and the novel 2,5-methylene-extended isoididedimethanol (IIDML). Both IIDCA and IIDML weredeveloped to increase the reactivity of the...
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Consequences of russia’s military invasion of Ukraine for Polish-Ukrainian trade relations
PublicationAn accurate forecast of interstate trade volume allows for short-term and long-term planning, particularly deciding on state budget revenues, foreign exchange earnings, border arrangement, other infrastructure, migration and social policies. Hostilities are destructive so the russian military aggression against Ukraine in 2022 needs to be assessed in terms of its effects on key economic aspects of Polish-Ukrainian relations, as...
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Organic matter removal efficiency in treatment wetlands simulation by COD fractions
PublicationThe objective of this paper was to investigate the organic fraction (colloidal, particulate, and dissolved) in sewage treatment in treatment wetland. Performance of TWs was simulated well with a simple first order model k – C* based on monitoring data. In this investigation background or residual concentration (C*) was assumed to be equal concentration of input influent organic matter in particulate (CODp). Calculated reaction...
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Metabolic transformation of antitumor agent C1311 with various fractions of rat liver.
PublicationWykazano, że enzymatyczna aktywacja jest konieczna dla aktywności bilogicznej pochodnej C-1311. Zbadano przemiany związku w obecności różnych frakcji enzymatycznych mikrosomalnych komórek wątroby szczura.Badania te wykazały, że związek C-1311 jest bardziej podatny na transformację pod wpływem frakcji aktywowanych enzymów mikrosomalnych (CYP1A, CYP2B, CYP3A i CYP4A) niż frakcji S9, cytozolowej czy mikrosomów nieaktywowanych. Związek...
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Phytochemical parasite-host relations and interactions: A Cistanche armena case study
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Fabrication of ILs-Assisted AgTaO3 Nanoparticles for the Water Splitting Reaction: The Effect of ILs on Morphology and Photoactivity
PublicationThe design of an active, stable and ecient photocatalyst that is able to be used for hydrogen production is of great interest nowadays. Therefore, four methods of AgTaO3 perovskite synthesis, such as hydrothermal, solvothermal, sol-gel and solid state reactions, were proposed in this study to identify the one with the highest hydrogen generation eciency by the water splitting reaction. The comprehensive results clearly show that...
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Spectacular Oxygen Evolution Reaction Enhancement through Laser Processing of the Nickel‐Decorated Titania Nanotubes
PublicationThe selective, laser‐induced modification of the nickel‐decorated titania nanotubes provides remarkable enhancement toward oxygen evolution reaction. Particularly, the irradiation of the laterally spaced crystalline TiO2 nanotubes, results in the formation of the tight closure over irradiated end, preserving their hollow interior. The shape of the absorbance spectra is modulated along with applied energy, and the new absorption...
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The kinetics of substitution reaction of oxydiacetate and thiodiacetate copper(II) complexes with 1,10-phenanthroline and 2,2’-bipyridine
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Synergistic interactions and reaction mechanisms of biochar surface functionalities in antibiotics removal from industrial wastewater
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Reaction to Disease and Coping Strategies in Stressful Situations among Psoriasis Patients: Cross-Sectional Study
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The reaction heats and PM5 semiempirical studies of complexes formed between silicon podand and monovalent cations
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The reaction heats and PM5 semiempirical studies of complexes formed between silicon podand and Li+ cations
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The effects of confinement in pores built of folded graphene sheets on the equilibrium of nitrogen monoxide dimerisation reaction
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Two-Dimensional Molybdenum Diselenide Tuned by Bimetal Co/Ni Nanoparticles for Oxygen Evolution Reaction
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A simple modification to improve the accuracy of methylation-sensitive restriction enzyme quantitative polymerase chain reaction
PublicationDNA digestion with endonucleases sensitive to CpG methylation such as HpaII followed by polymerase chain reaction (PCR) quantitation is commonly used in molecular studies as a simple and inexpensive solution for assessment of region-specific DNA methylation. We observed that the results of such analyses were highly overestimated if mock-digested samples were applied as the reference.We determined DNA methylation levels in several...
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Metrological characteristics of the flat voltammetric electrode in time domain with a reversible electrochemical reaction running on the surface
PublicationW artykule przedstawiono właściwości metrologiczne płaskich elektrod woltamperometrycznych. Omówiono wpływ napięcia polaryzującego na wartości parametrów charakteryzujących te elektrody.