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Search results for: OXIDE GLASSES
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Hysteresis curves for some periodic and aperiodic perturbations in gases
PublicationEvolution of sound in a medium whose properties irreversibly vary in the course of wave propagation, is studied. For example, a gas that is a particular case of a Newtonian fluid is considered. Hysteresis curves, pictorial representations of irreversible attenuation of the sound energy, in the plane of thermodynamic states are plotted. The irreversible losses in internal energy are proportional to the total attenuation and depend...
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Features of Nonlinear Sound Propagation in Vibrationally Excited Gases
PublicationWeakly nonlinear sound propagation in a gas where molecular vibrational relaxation takes place is studied. New equations which govern the sound in media where the irreversible relaxation may take place are derived and discussed. Their form depends on the regime of excitation of oscillatory degrees of freedom, equilibrium (reversible) or non-equilibrium (irreversible), and on the comparative frequency of the sound in relation to...
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Ho2Pd1.3Ge2.7 – a ternary AlB2-type cluster glass system
PublicationWe report a successful synthesis of a ternary AlB2-type intermetallic compound. The phase purity was obtained by fine-tuning the Pd-Ge ratio out of the idealized 1-3. Attempts to synthesize an Er analogue were not successful. We discuss the instability of the Er analogue based on the atomic size ratio and also suggest that the increased stability of Ho2Pd1+xGe3−x in the Pd-rich range likely stems from a combination of atomic size...
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Nanocrystallization as a tool for controlling in vitro dissolution of borophosphate glass
PublicationThe controlled nanocrystallization of sodium-calcium-borophosphate glass (Na16.6Ca5.1B10.5Al0.8P10.5 O56.5 in at %) was conducted to investigate its influence on in vitro dissolution. Three temperatures (570 ◦C, 590 ◦C, and 610 ◦C) were selected based on thermal analysis and investigation of the morphology, structure, and in vitro dissolution of glass and glass-ceramics was conducted. The results of X-ray diffraction confirmed...
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Electron diffision coefficients in triatomic gases measurements and model
PublicationPraca zawiera porównanie współczynników dyfuzji elektronów w gazach trójatomowych (N2O, C2O) zmierzonych w doświadczeniu ze współczynnikami wyznaczonymi numerycznie z wykorzystaniem równania Boltzmanna oraz z zastosowaniem metody Monte Carlo. Przedstawiona procedura pozwala zweryfikować przekroje czynne na zderzenia elektronów z drobinami gazów.
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Conductivity and superconductivity of (Bi,Pb)4Sr3Ca3Cu4Ox glass-ceramics.
PublicationW układzie(Bi,Pb)-Sr-Ca-Cu-O poprzez krystalizację w fazie stałej można wytworzyć materiały o bardzo różnych właściwościach elektrycznych i nadprzewodzących. W zależności od warunków krystalizacji, można wytworzyć nadprzewodnik o temperaturze krytycznej między 8 a 105 st.K lub materiał nie przechodzący do stanu nadprzewodzącego. W pracy pokazano i przedyskutowano wpływ składu fazowego, struktury i mikrostruktury na przewodnictwo...
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INFLUENCE OF THE MARINE 4-STROKE DIESEL ENGINE MALFUNCTIONS ON THE NITRIC OXIDES EMISSION
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Evaluation of Ln2CuO4 (Ln: La, Pr, Nd) oxides as cathode materials for IT-SOFCs
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Effective one-band Hamiltonian for the copper-oxygen plane in the superconducting copper oxides
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Structure and transport properties of triple-conducting BaxSr1−xTi1−yFeyO3−δ oxides
PublicationIn this work, BaxSr1−xTi1−yFeyO3−δ perovskite-based mixed conducting ceramics (for x = 0, 0.2, 0.5 and y = 0.1, 0.8) were synthesized and studied. The structural analysis based on the X-ray diffraction results showed significant changes in the unit cell volume and Fe(Ti)–O distance as a function of Ba content. The morphology of the synthesized samples studied by means of scanning electron microscopy has shown different microstructures...
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Tunable emission and energy transfer of B2O3–Bi2O3–AlF3 glass system doped with Eu3+/Dy3+
PublicationThe structure and luminescent properties of the B2O3–Bi2O–AlF3 glass system doped with Eu3+/Dy3+ ions in different molar ratios were studied. A series of glasses were synthesized by the conventional melt quenching technique. Glass transition and crystallization temperatures were examined by Differential Thermal Analysis (DTA) measurements. The amorphous character of the prepared samples was confirmed by the X-ray diffraction (XRD)...
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Influence of Phase Composition on Dielectric Properties of Bismuth-Based Ceramics with Scheelite-Type Structure
PublicationGoal of the present research was to study dielectric properties of BiNbO4 ceramics fabricated by solid state reaction route followed with pressureless sintering. The samples were fabricated from the mixture of oxides, viz. Nb2O5 and Bi2O3. Apart from stoichiometric amount an excess of 3%, 5% and 10% by mole of Bi2O3 was used. It was found that an excess amount of Bi2O3 oxide caused formation of Bi5Nb3O15 minor phase in amount of...
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Submicron inorganic particles as an additional filler in hybrid epoxy matrix composites reinforced with glass fibres
PublicationIn this study, the effect of selected submicron metal oxide (zinc oxide, titanium oxide) or non-metal oxide (silicon dioxide) particles on mechanical and thermo-mechanical properties of epoxy/glass composites was investigated. The applied epoxy resin was a diglycidyl ether of bisphenol-A cured with triethylenetetramine. As a reinforcement twill weave E-glass fabric was used. Hybrid composites (contained particulate and fibrous...
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Performance of a single layer fuel cell based on a mixed proton-electron conducting composite
PublicationMany of the challenges in solid oxide fuel cell technology stem from chemical and mechanical incompatibilities between the anode, cathode and electrolyte materials. Numerous attempts have been made to identify compatible materials. Here, these challenges are circumvented by the introduction of a working single layer fuel cell, fabricated from a composite of proton conducting BaCe0.6Zr0.2Y0.2O3-δ and a mixture of semiconducting...
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Identification of the Inertia of Masses Flowing Water through the Pipes in Water Power Plants
PublicationW artykule przedstawiono sposób identyfikacji stałej czasowej reprezentującej bezwładność mas przepływającej wody w systemie rurociągów, w elektrowni wodnej. Przedstawiono strukturę modelu układu regulacji prędkości kątowej wykorzystywanego w procesie identyfikacji oraz przeprowadzono badania skuteczności działania metody w środowisku Matlab-Simulink. Opisano najistotniejsze wnioski wynikające z przeprowadzonych badań symulacyjnych.
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The influence of a sweat rate on heat losses of the selected segments of a sweating thermal manikin
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Transmission Losses Spatial Analysis of the Supply System of Electrified Urban Transport Network
PublicationThe paper presents mathematical model TOPSIS which was applied for MCDA benchmark of trolleybus supply system. Moreover, paper presents the novel method of transmission losses analysis in electrified urban transport system. Research work was based on measurements realized in Gdynia trolleybus network.
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Study of the Flow Dynamics of Surface Water Masses in the Area of the Coastal Gulf of Gdansk
PublicationThe paper describes two methods of predicting the movement of small objects with surface water masses. One of the methods uses graph theory to describe the motion of water masses in port docks. The results of this study were compared to a simulation using the hydrodynamic numerical model M3D. The results obtained in a virtual environment were related to the experiments in the real world. In the coastal area of the Gulf of Gdansk,...
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Viability and intracellular nitric oxide generation in the umbilical cord blood CD34+CD133– and CD34+CD133+ cell populations exposed to local anaesthetics
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An enhanced electrochemical nanohybrid sensing platform consisting of reduced graphene oxide and sulfanyl metalloporphyrazines for sensitive determination of hydrogen peroxide and l -cysteine
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Luminescent properties of undoped and Ce3+ doped crystals in Y2O3 Lu2O3 Al2O3 triple oxide system grown by micro-pulling-down method
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Application of biocompatible and ultrastable superparamagnetic iron(iii) oxide nanoparticles doped with magnesium for efficient magnetic fluid hyperthermia in lung cancer cells
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Modeling nitrous oxide production by a denitrifying-enhancedbiologically phosphorus removing (EBPR) activated sludge in thepresence of different carbon sources and electron acceptors
PublicationIn this study, the IWA Activated Sludge Model No. 2d (ASM2d) was expanded to identify the most important mechanisms leading to the anoxic nitrous oxide (N2O) production in the combined nitrogen (N) and phosphorus (P) removal activated sludge systems. The new model adopted a three-stage denitrification concept and was evaluated against the measured data from one/two-phase batch experiments carried out with activated sludge withdrawn...
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Electrophoretic co-deposition of Fe2O3 and Mn1,5Co1,5O4: Processing and oxidation performance of Fe-doped Mn-Co coatings for solid oxide cell interconnects
PublicationThe “in-situ” Fe-doping of the manganese cobalt spinel was achieved by electrophoretic co-deposition of Mn1,5Co1,5O4 and Fe2O3 powders followed by a two-step reactive sintering treatment. The effects on the coating properties of two different Fe-doping levels (5 and 10 wt.% respectively) and two different temperatures of the reducing treatment (900 and 1000 °C) are discussed. Samples with Fe-doped coatings demonstrated a lower...
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Strategies for mitigating nitrous oxide production and decreasing the carbon footprint of a full-scale combined nitrogen and phosphorus removal activated sludge system
PublicationNitrous oxide (N2O) emitted from biological nutrient removal activated sludge systems contributes significantly to the total carbon footprint of modern wastewater treatment plants. In the present study, N2O production and emissions were experimentally determined in a large-scale plant (220,000 PE) employing combined nitrogen (N) and phosphorus (P) removal. As a modelling tool, the Activated Sludge Model 2d (ASM2d) was extended...
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Stone cutting industry waste-supported zinc oxide nanostructures for ultrasonic assisted decomposition of an anti-inflammatory non-steroidal pharmaceutical compound
PublicationPowdered stone waste (PSW) obtained from a stone cutting industrial unit was applied as support for the immobilization of nano-sized ZnO to be utilized as an effective catalyst for the catalytic conversion of acetaminophen (ACE) under ultrasonication. The incorporation of ZnO nanostructures into PSW structure enhanced the specific surface area and pore volume of the as-prepared nanocompound. The change in the value of zero point...
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Ni/cerium Molybdenum Oxide Hydrate Microflakes Composite Coatings Electrodeposited from Choline Chloride: Ethylene Glycol Deep Eutectic Solvent
PublicationCerium molybdenum oxide hydrate microflakes are codeposited with nickel from a deep eutectic solvent-based bath. During seven days of exposure in 0.05 M NaCl solution, the corrosion resistance of composite coating (Ni/CeMoOxide) is slightly reduced, due to the existence of some microcracks caused by large microflakes. Multielemental analysis of the solution, in which coatings are exposed and the qualitative changes in the surface...
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Iron doped manganese cobaltite spinel coatings produced by electrophoretic co-deposition on interconnects for solid oxide cells: Microstructural and electrical characterization
PublicationWe report a systematic microstructural and electrical characterization of iron doped Mn–Co spinel coatings processed by electrophoretic co-deposition of Mn1.5Co1.5O4 and Fe2O3 powders on Crofer 22 APU and AISI 441 steel substrates. Iron addition to Mn–Co spinel coating leads to a reduction of the area specific resistance on both substrates, after 3200 h at 750 °C. The Fe doped Mn–Co coating both leads to a thinner oxide scale and...
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Effects of Micro-Arc Oxidation Process Parameters on Characteristics of Calcium-Phosphate Containing Oxide Layers on the Selective Laser Melted Ti13Zr13Nb Alloy
PublicationTitania-based films on selective laser melted Ti13Zr13Nb have been formed by micro-arc oxidation (MAO) at different process parameters (voltage, current, processing time) in order to evaluate the impact of MAO process parameters in calcium and phosphate (Ca + P) containing electrolyte on surface characteristic, early-stage bioactivity, nanomechanical properties, and adhesion between the oxide coatings and substrate. The surface...
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Corncob-supported calcium oxide nanoparticles from hen eggshells for cadmium (Cd-II) removal from aqueous solutions; Synthesis and characterization
PublicationThis study investigated the efficient removal of cadmium ions from aqueous solutions using calcium oxide nanoparticles (CaO NPs) synthesized from waste hen eggshells using a Sol-gel method and supported on corncob bio-adsorbent. The synthesized CaO NPs were characterized using FT-IR, XRD, specific surface area, and TGA. Batch adsorption experiments were conducted to examine the influence of process parameters such as adsorbent...
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The Impact of Lightning Flashes and Sprites on the Earth’s Global Electric Circuit: An Overview of Recent Modeling Results
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<title>Search for optical flashes accompanying gamma ray bursts Pi of the Sky collaboration</title>
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A novel approach for processing CaAlSiON glass-ceramics by spark plasma sintering: Mechanical and electrical properties
PublicationLithium containing glassy materials can be used as solid electrolytes or electrode materials for lithium-ion batteries due to their high energy density. Conventional melt-quenched Ca11Al14Si16O49N10 glass powder containing 24 e/o N, doped with Li-ions (1, 3, and 6 wt. %) and sintered by spark plasma sintering technique (SPS) was studied. The benefits of using SPS to produce glass-ceramics are rapid heating rates compared to conventional...
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Tensile strength test of PE foils modified with zinc oxide and zinc salts
Open Research DataThis dataset contains the results of PE foils mechanical tests, in which the material was evaluated for strength and extensibility at the moment of breaking and based on the same tests preceded by material fatigue in 50 stretching cycles. The principle of the method is to stretch the test sample placed in the clamps of the stretching apparatus at a...
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FTIR spectra and IGC chromatograms for chemically reduced graphene oxide aerogels (rGOA)
Open Research DataThe effect of selected synthesis parameters on reduced graphene oxide aerogels properties was investigated using Fourier-transform infrared spectroscopy and dynamic adsorption method (Inverse Gas Chromatography, IGC). Samples were synthesized by sol-gel method by reduction induced self-assembly of graphene oxide. As a reductant l-ascorbic acid was used....
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XRD patterns of vanadium oxide nanostructures on silicon substrate obtained by V2O5 recrystallization
Open Research DataThe DataSet contains the XRD patterns of vanadium oxide nanostructures on silicon substrates obtained by recrystallization of V2O5 thin films between 800-1200°C under synthetic air. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials.
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SEM micrographs of vanadium oxide nanostructures obtained by V2O5 recrystallization at 1000°C
Open Research DataThe DataSet contains the scanning electron microscopy (SEM) micrographs of vanadium oxide nanostructures on quartz glass and silicon substrates obtained by recrystallization of V2O5 thin films at 1000°C under synthetic air. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials.
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SEM micrographs of vanadium oxide nanostructures obtained by V2O5 recrystallization at 800°C
Open Research DataThe DataSet contains the scanning electron microscopy (SEM) micrographs of vanadium oxide nanostructures on quartz glass and silicon substrates obtained by recrystallization of V2O5 thin films at 800°C under synthetic air. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials.
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Ultra-thin film of aluminum oxide influence on the plasmon resonance in gold nanostructures
Open Research DataUltra-thin film of aluminum oxide influence on the plasmon resonance in gold nanostructures was measured by UV-VIS spectroscopy. Ultra thin film of Al2O3 was deposited on a gold nanostructures. Thickness of film was 2nm - 8nm. Shift of plasmon resonance was observed, as a result of various dielectric constant of layer.
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SEM micrographs of vanadium oxide nanostructures obtained by V2O5 recrystallization at 1200°C
Open Research DataThe DataSet contains the scanning electron microscopy (SEM) micrographs of vanadium oxide nanostructures on quartz glass and silicon substrates obtained by recrystallization of V2O5 thin films at 1200°C under synthetic air. The thin films were obtained by the sol-gel method. The information about sol synthesis is described in the Journal of Nanomaterials.
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XPS measurements of the Fe-Bi based glass
Open Research DataFe-Si-O and Fe-Si-Pb-O glass was measured by XPS method. The influence of Pb dopand on the glass structure, including the valence of iron, was investigated. The influence of the annealing temperature on the behavior of iron in glass was also investigated. Studies have confirmed the mixed valence of iron in glasses and a high proportion of metallic Fe.
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Application of TOF-SIMS Method in the Study of Wetting the Iron (111) Surface with Promoter Oxides
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Structural Disorder in High-Spin {CoII9WV6} (Core)-[Pyridine N-Oxides] (Shell) Architectures
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Aerobic Cytotoxicity of Aromatic N-Oxides: The Role of NAD(P)H:Quinone Oxidoreductase (NQO1)
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Natural Environments for Nanoparticles Synthesis of Metal, Metal Oxides, Core–Shell and Bimetallic Systems
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MnxCo3-xO4 spinel oxides as efficient oxygen evolution reaction catalysts in alkaline media
PublicationThe design of efficient electrocatalysts for oxygen evolution reaction (OER) is an essential task in developing sustainable water splitting technology for the production of hydrogen. In this work, manganese cobalt spinel oxides with a general formula of MnxCo3-xO4 (x=0, 0.5, 1, 1.5, 2) were synthesised via a soft chemistry method. Non-equilibrium mixed powder compositions were produced, resulting in high electrocatalytic activity....
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Kinetic analysis of the reduction of a ternary system of Bi, Sb and Te oxides by hydrogen for BiSbTe3 synthesis
PublicationReduction in a hydrogen atmosphere of Bi2O3, Sb2O3 and TeO2 mixes oxides for the synthesis of BiSbTe3 was analysed. The reduction reactions of Sb2O3 and Sb2O4 oxides, as well as Bi2O3+Sb2O3 and Sb2O3+3TeO2 mix- tures, were also evaluated. The reduction of Sb2O4 is investigated for the first time. The reactions of the mixed oxides systems also were not the subject of research so far despite being used for synthesis of the (Bi,Sb)2Te3...
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The (Bi,Pb)4Sr3Ca3Cu4Ox glass-ceramics: disordered metal and superconductor
PublicationAmorficzny materiał (Bi,Pb)4Sr3Ca3Cu4Ox wygrzewany w odpowiednich warunkach staje się granulastym metalem i nadprzewodnikiem. Może być uważany za silnie nieuporządkowany metal. Ma duży opór i zazwyczaj ujemny współczynnik temperaturowej zależności oporu. Nieuporządkowanie i granulasty charakter materiału ujawnia się również w jego właściwościach nadprzewodzących.
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Cluster-glass behavior of a highly oxygen deficient perovskite, BaBi0.28Co0.72O2.2
PublicationZostała przeprowadzona synteza zwiąku typu perowskitowego BaBi0.28Co0.72O2.2. Stuktura krystalograficzna została określona poprzez dyfrakcję neutronową i promieniowania rentgenowskiego. Pomiary podatności magnetycznej AC i DC wskazują na zachowanie typu szkła klastrowego, które wynika z oddziaływań klastrów ferromagnetycznych.
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<title>Technology of soft-glass optical fiber capillaries</title>
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