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Search results for: NAFION
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Impact of the Alkyl Side Chains of Cations and Anions on the Activity and Renaturation of Lysozyme: A Systematic Study Performed Using Six Amino‐Acid‐Based Ionic Liquids
PublicationThe impact of the structure of ionic liquid on the activity and renaturation of lysozyme from the hen egg white (HEWL) was investigated. A set of six ionic liquids based on morpholinium cation and N-acylated amino acids as anions were exploited. The matrix used was based on two homologous series: one with N-acetyl-L-valinate [Val] as a common anion and morpholinium cation with a different number of carbon atoms in the n-alkyl chain...
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Jacek Tomków dr hab. inż.
PeopleEducation:1. 2018 - Ph.D. of Technical Sciencesin field of Materials Engineeringthesis: Influence of underwater welding conditions on cold cracking of high strength low alloy steel 2. 2012 - Master of Science Engineer, Gdansk University of Technologyin the field of: Mechanical Engineeringwith specialization in: Manufacturing Engineering and Computer Aided Manufacturing Processesthesis: Non-destructive testing of welding joints...
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Valorisation of bioplastics synthesised by liquefaction of celluloseusing hetero- and homogeneous catalysts
Open Research DataThe purpose of the present study was to test the effectiveness of a heterogeneous catalyst such as Nafion ion-exchange resin on the cellulose liquefaction process. The results obtained were compared with the bio-polyols obtained in a conventional way, using a homogeneous catalyst (sulfuric acid (VI)). Depending on the catalyst used and the temperature...
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Potential energy curves and spectroscopic parameters of the diatomic silver anion and neutral silver dimer
Open Research DataThe process of a two-channel decay of the diatomic silver anion (Ag2-), namely the spontaneous electron ejection giving Ag2 + e- and the dissociation leading to Ag- + Ag is theoretically studied. The ground state potential energy curves (PECs) of the neutral silver dimer and anionic silver diatomic molecule are calculated using the single reference...
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Gdańsk palimpsest. On obscuring and retrieving traces of memory
PublicationThe article deals with the problems of collective identity resulting from over one thousand year history of the city on the Motława river and the role of historical policy of the local authorities regarding the material cultural heritage of many nations and cultures. In our opinion, the palimpsestic (palimpsestueuse) character of the city plays a significant role in the discourse about the past of Gdańsk. We use that notion after...
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Surface active fatty acid ILs: Influence of the hydrophobic tail and/or theimidazolium hydroxyl functionalization on aggregates formation
PublicationNine structurally-related fatty acid ionic liquids have been prepared and their thermal behavior as well as their ability to self-assemble in water has been investigated. The thermal properties were studied by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC), while the aggregation behavior was analyzed by tensiometry, isothermal titration calorimetry (ITC), conductometry, dynamic light scattering (DLS),...
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Anion-π Architectures of HAT(CN)6 and 5d Polycyanidometalates: [W(CN)8]3–, [Re(CN)7]3–, and [Pt(CN)6]2–
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Density, sound velocity, viscosity, and refractive index of new morpholinium ionic liquids with amino acid-based anions: Effect of temperature, alkyl chain length, and anion
PublicationIn this work, room temperature synthesis of twenty new ionic liquids (ILs) based on the N-alkyl-N-methylmorpholinium ([Mor1,R], R = 2, 3, 4, 6, 8) cation and N-acetyl-L-amino acid anions (L-alaninate, L-valinate, L-leucinate, L-isoleucinate) was described. The synthesized ILs were characterized by various spectroscopic techniques and high-resolution mass spectrometry. Furthermore, density (ρ), sound velocity (v), viscosity (η)...
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Theoretical calculation of the physico-chemical properties of 1-butyl-4-methylpyridinium based ionic liquids
PublicationACCEPTED MAIonic liquids (ILs) have attracted much attention for their unique physicochemical properties, which can be designed as needed by altering the ion combinations. Besides experimental work, numerous computational studies have been concerned with prediction of physical properties of ILs. The results of molecular dynamics simulations of ILs depend strongly on the proper force field parameterization. Classical force fields...
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Impact of the Alkyl Side Chains of Cations and Anions on the Activity and Renaturation of Lysozyme: A Systematic Study Performed Using Six Amino‐Acid‐Based Ionic Liquids
PublicationThe impact of the structure of ionic liquid on the activity and renaturation of lysozyme from the hen egg white (HEWL) was investigated. A set of six ionic liquids based on morpholinium cation and N-acylated amino acids as anions were exploited. The matrix used was based on two homologous series: one with N-acetyl-L-valinate [Val] as a common anion and morpholinium cation with a different number of...
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Application of the tetraphenylphosphonium tetraphenylborate (TPTB) assumption to the thermodynamic properties of solvated ions in dimethylsulfoxide
PublicationW niniejszej pracy za pomocą spektroskopii ATR FTIR sprawdzano możliwość zastosowania tetrafenyloboranu tetrafenylofosfoniowego w metodzie elektrolitu wzorcowego, służącej do podziału wielkości termodynamicznych elektrolitów w dimetylosulfotlenku na udziały jonowe. Jednoznacznie stwierdzono, że poza termodynamiczne założenie o identycznych oddziaływaniach jonów w elektrolicie wzorcowym z cząsteczkami DMSO jest nieprawdziwe. Uzyskane...
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Deformation degree estimators for several basic structural units in numerically simulated materials
PublicationW pracy wprowadzono i zdefiniowano kilka estymatorów stopnia deformacji dla serii bazowych jednostek strukturalnych typu CA_n (C-kation, A-anion) występujących w strukturach symulowanych numerycznie. Do wyznaczenia rozkładu wartości estymatoróww funkcji stopnia deformacji kształtu zadanego wielościanu zastosowano symulacje Monte Carlo. Otrzymane rozkłady są danymi referencyjnymi, które są bardzo użyteczne przy jakościowej analizie...
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Hybrid battery based on arylated carbon nanotubes and laccase
PublicationSingle-walled carbon nanotubes (SWCNT) were covalently modified with anthracene and anthraquinone and used for the construction of cathodes for biocatalytic reduction of dioxygen. The nanotubes with aromatic groups casted onto the electrode increased the working surface of the electrode and enabled efficient direct electron transfer (DET) between the enzyme and the electrode. The aryl groups enter the hydrophobic pocket of the...
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Understanding ion–ion and ion–solvent interactions in aqueous solutions of morpholinium ionic liquids with N-acetyl-L-alaninate anion through partial molar properties and molecular dynamics simulations
PublicationAmino acid ionic liquids (AAILs) provide a low toxicity, biodegradable alternative to conventional ionic liquids, while also maintaining solubility in water. Densities and sound velocities of aqueous solutions of four amino acid ionic liquids (AAILs), based on the N-alkyl-N-methylmorpholinium ([Mor1,R], R = 2, 3, 6, 8) cation and N-acetyl-L-alaninate ([N-Ac-L-Ala]) anion were measured at T = (293.15–313.15) K and at atmospheric...
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Monitoring system of the road embankment
PublicationThe paper presents the monitoring system of the embankment supported on concrete columns and overlaid by a load transfer platform (LTP) with the embedded steel grid. This field investigation was to study the complex inter-action between the columns, the LTP layer, and steel reinforcement via full-scale in situ measurements during erection of the embankment. The study was focused on the behaviour of steel reinforcement and the behaviour...
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Non-adiabatic coupling elements between the diatomic silver anion and neutral silver dimer plus continuum electron
Open Research DataThe process of a two-channel decay of the diatomic silver anion (Ag2-), namely the spontaneous electron ejection giving Ag2 + e- and the dissociation leading to Ag- + Ag is theoretically studied. The ground state potential energy curves (PECs) of the neutral silver dimer and anionic silver diatomic molecule are calculated using the single reference...
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Micellar aggregation of Triton X-100 surfactant in imidazolium ionic liquids
PublicationIn this work we investigated aggregation behavior of a nonionic surfactant Triton X-100 in eighteen imidazolium ionic liquids (ILs) with two to eight carbon atoms in cations alkyl chain, namely 1-ethyl-3-methylimidazolium, [EMIM], 1-butyl-3-methylimidazolium, [PrMIM], 3-methyl-1-propylimidazolium, [BMIM], 1-hexyl-3-methylimidazolium, [PMIM], 3-methyl-1-pentyl-imidazolium, [HMIM], and 1-octyl-3-methylimidazolium, [OMIM], and with...
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The luminescence study of Ga2–x(Al0.68In0.32)xO3:Cr3+ coumpounds.
Open Research DataNear-infrared (NIR) phosphor-converted light-emitting diodes (pc-LEDs) are a highly efficient perspective NIR light source, with application hindered by a narrow emission band. In this work, we broaden the emission of a new series of NIR phosphors by controlling crystal structure disorder through cation cosubstitution. By substituting Ga3+ with (Al0.68In0.32)3+,...
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Investigation of solid polymer electrolyte gas sensor with different electrochemical techniques
PublicationIn this work solid polymer electrolyte (SPE) amperometric sulphur dioxide sensor is investigated. Nafion was used as a membrane electrode and 1M sulphuric acid as an internal electrolyte. Sensor response to sulphur dioxide was measured. Besides traditional constant voltage amperometry also different electrochemical techniques were used. Results obtained by these methods are compared.
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Influence of the internal electrolyte composition on amperometric sulphur dioxide sensor properties
PublicationIn this work amperometric sulphur dioxide sensor with a liquid electrolyte, a mercury sulphate reference electrode and solid polymer electrolyte (Nafion) covered with gold as a working electrode will be presented. The main goal of this research is to determine the influence of internal electrolyte composition on the sensor properties. Sensor filled with 1M and 5M sulphuric acid has been investigated.
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Influence of the internal electrolyte composition on amperometric sulphur dioxide sensor properties
PublicationIn this work investigation of an amperometric sulphur dioxide sensor with a liquid electrolyte, a mercury sulphate reference electrode and solid polymer electrolyte (Nafion) covered with gold as a working electrode properties is presented. The main goal of this research is to determine the influence of internal electrolyte composition on the sensor properties. Sensor filled with 1M and 5M sulphuric acid has been studied.
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Information based integration for complex systems. W: Knowledge and infor-mation technology management in the 21st century organizations. Ed. A. Gu- nasekaran, O. Khalil, M.R. Syed. London: Idea**2002 s. 89-104 Informacyjna integracja systemów złożonych.
PublicationW rozdziale zaproponowano strukturę inteligentnego systemu wspomagania pro-cesu integracji dla złożonych systemów wytwarzania. System wspomagania opar-to na bazie wiedzy, w której wiedza modelowana jest regulami produkcji. Zbu-dowano również iteracyjny algorytm integracji. Samą ideę integracji opartona przepływach informacyjnych.
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Lower Rim Substituted p-tert-Butyl Calix[4]arenes(V). Synthesis of New 5,11,17,22-tetrakis-p-tert-Butyl-25-27-bis(dialkoxyphosphorylmethoxy)calix[4] arenes and Cation Complexation Studies in Ion Selective Membrane Electrodes.
PublicationZaprezentowano syntezę i właściwości trzech nowych związków (2-4), bis podstawionych na dolnym obrzeżu grupami z resztą fosforylową. Związki te były badane jako jonofory w membranowych elektrodach jonoselektywnych (ISE) wykazując selektywność na kationy Rb+,K+ oraz duży i płaski kation guanidyniowyG+). Badano korelację pomiędzy stereo-strukturą związków a ich selektywnością w ISE. Stałe trwałości kompleksów z kationami metali...
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Quality of bottled waters
PublicationBottled water is a product that is purchased by annually increasing numbers of people of all age groups. The quality control of mineral waters tends to concentrate on the determination of anion and cation levels, since it is these that govern the taste, smell and possible medicinal properties of the water. The constantly rising sales of mineral waters bring with them the ever increasing exploitation of their sources. The consequences...
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Ionic liquids in the microextraction techniques: the influence of ILs structure and properties
PublicationIonic liquids (ILs) are composed entirely of ions thus they possess unique properties, including negligible volatility, a liquid state in a broad range of temperatures and ability to change them depending on the chosen type of anion and cation, which make ILs unique and useful for many applications in sample preparation techniques. A deeper understanding of the nature of ILs and the impact of their structure on their parameters...
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THE INFLUENCE OF GESTALT THEORY ON ERNST CASSIRER’S PHENOMENOLOGY OF SYMBOLIC FORMS
PublicationIn the opinion of many scholars the notion of symbolic pregnancy is one of the key concepts in Ernst Cassirer’s philosophy of symbolic forms. Without a proper under-standing of its conceptual frame Cassirer’s philosophy lacks a consistent foundation. The notion symbolic pregnancy offers the mechanism of distinction of symbolic forms. The newest investigations (also in unpublished or less known, neglected writings of the philosopher)...
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The first compound with an unusual type of anion, [Li(SR)2]-:bis(µ2-aqua-d2)tetrakis(aqua-d2)]dilithium(I)bis[bis(tri-tert-butoxysilanethiolato-k2O,S)lithate(I)]dihydrate-d2
PublicationTytułowy związek [Li2(D2O)6][Li(C9H27SSiO3)2]2*2D2O, jest pierwszym związkiem z wiązaniem S-M (M-metal alkaliczny), zawierającym niespotykany typ anionu litanowego: [Li(SR)2]-,gdzie R=Si{OC{CH3)3}3. Centrum symetrii związku znajduję się pośrodku pierścienia Li2O2 wchodzącego w skład kationu. Wszystkie atomy litu budujące rdzenie kationów - LiO4 i anionów - LiO2S2, są czterokoordynacyjne. Jednoujemne aniony [Li(SR)2]- są dobrze...
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Thermodynamic study of binary mixtures of 2-propanol with ionic liquids, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexylammonium bis(trifluoromethylsulfonyl)imide
PublicationIn this work, densities, speeds of sound, refractive indices and viscosities of three binary mixtures containing the ionic liquids 1-hexyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexyl-ammonium bis(trifluoromethylsulfonyl)imide, mixed with 2-propanol at wide temperature and composition ranges at atmospheric pressure have been measured. From these...
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Synthesis, structural and spectroscopic properties of asymmetric schiff bases derived from 2,3-diaminopyridine
PublicationTwo Schiff base derivatives, 4-(2-amino-3-pyridyliminomethyl)phenol (I) and 3-(2-amino-3- pyridyliminomethyl)nitrobenzene (II ), were synthesised and characterised by spectroscopy. The structure of I was determined by single crystal X-ray diffraction studies. The asymmetric Schiff base derived from 2,3-diaminopyridine selectively recognise transition and heavy metal cations, and some anion. Ligands I and II form stable complexes...
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Synteza, właściwości i zastosowanie cieczy jonowych, pochodnych naturalnych związków organicznych
PublicationW ramach pracy doktorskiej zaprojektowano, zsyntezowano oraz określono właściwości cieczy jonowych zawierających w swojej strukturze cząsteczki pochodzenia naturalnego – głównie aminokwasów w postaci N-acetylowanej. Wybrane ciecze jonowe zostały wykorzystane jako katalizatory przeniesienia fazowego w reakcjach N- oraz C¬-substytucji. Wydajności reakcji zostały porównane ze standardowymi katalizatorami. Innym rodzajem otrzymanych...
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Budowa i podstawowy skład surowców oraz produktów żywnościowych
PublicationRozdział zawiera zagadnienia związane ze składem chemicznym mięsa, mleka, surowców skrobiowych, nasion roślin strączkowych, tłuszczów jadalnych oraz owoców i warzyw.
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Adapting a General Tool to Monitoring Multi-Agent Systems Through Virtual Host Layer Extenstion
PublicationNagios is a free software for IT infrastructure monitoring. Out-of-the-box it is not suited for monitoring multi-agent systems, because agents may dynamically join and leave the system or change roles. But Nagios' flexible configuration makes extensions possible. This paper presents and verifies Nagios configuration and extensions for monitoring multi-agent systems.
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Barbara Kusznierewicz dr hab. inż.
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Tailoring a low-energy ball milled MnCo2O4 spinel catalyst to boost oxygen evolution reaction performance
PublicationThe development of cost-efficient oxygen evolution reaction (OER) catalysts is one of the most important tasks facing modern techniques for hydrogen production. In this work, for the first time, a low-energy ball milling process of MnCo2O4 (MCO) spinel powders, with a mechanical modification time exceeding 1 day was used. After 6 days of ball-milling, the obtained overpotential of the electrocatalyst reached the value of 375 mV...
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The role of proteins in food. Chapter 6
PublicationStruktura i konformacja wpływają na biologiczne oraz funkcjonalne właściwości białek i na ich rolę w tworzeniu pożądanych cech produktów żywnościowych. Właściwości funkcjonalne to rozpuszczalność w środowisku wodnym o różnej sile jonowej, wodochłonność oraz zdolność żelowania, tworzenia błon, emulgowania lipidów i pienienia się. Białka mięsa, ryb, mleka, jaj, nasion roślin strączkowych, nasion zbóż oraz drobnoustrojów różnią się...
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What Skills for Multi-Partner Open Innovation Projects? Open Innovation Competence Profile in a Cluster Ecosystem Context
PublicationIndustry 4.0 and the turbulent environment have rendered increasing interest in open inno- vation that extends from the bilateral transmission of expertise to multilateral platform collaborations. Open innovation ventures are seen as intricate collaborations that require the commitment of numer- ous partners during the lifetime of the project. In order to examine the specific competence of open innovation teams, we set the research...
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Temperature-dependent structure-property modeling of viscosity for ionic liquids
PublicationIn this paper we present the methodology for assessing the ionic liquids' viscosity at six temperature points (25, 35, 45, 50, 60 and 70 [C]), which utilizes only the in silico approach. The main idea of such assessment is based on the "correction equation" describing the correlation between experimentally measured viscosity and theoretically derived density (calculated with use of molecular mechanics), given at 6 different temperature...
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Use of pyridinium and pyrrolidinium ionic liquids for removal of toluene from gas streams
PublicationSeparation of toluene from a toluene/N2 gas mixture using supported liquid membranes based on a series of pyridinium (1-butylpyridinium- bis(trifluoromethylsulfonyl)imide - [C4Py][Tf2N], 1-hexylpyridinium trifluoromethanesulfone [C6Py][Tf2N]) and pyrrolidinium (1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C4Pyrr][Tf2N], 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C6Pyrr][Tf2N], 1-butyl-1-methylpyrrolidinium...
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Hybrid biobateryy based on arylated carbon nanotubes and laccase
PublicationSingle-walled carbon nanotubes (SWCNT) were covalently modified with antracene and antraquinone and used for the construction of cathodes for biocatalytic reduction od dioxygen. The nanotubes with aromatic groups casted onto the electrode increased the working surface of the electrode and enabled efficient direct electron tarnsfer (DET) between the enzyme and the electrode. the aryl groups enter the hydrophobic pocket of the T1...
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A Note on Shannon Capacity for Invariant and Evolving Channels
PublicationIn the paper we discuss the notion of Shannon capacity for invariant and evolving channels. We show how this notion is involved in information theory, graph theory and Ramsey theory.
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Adapting a general tool to monitoring multi-agent systems through virtual host layer extenstion = Rozszerzenie typowego narzędzia o warstwę hosta wirtualnego w celu monitorowania systemów agentowych
PublicationNagios to bezpłatne oprogramowanie do monitorowania infrastruktury IT. Nie jest ono dostosowane do monitorowania systemów agentowych, gdyż agenty mogą swobodnie podejmować lub zarzucać realizację działań, czy zmieniać pełnioną rolę. Bogate możliwości konfigurowania Nagios pozwalają poszerzyć jego możliwości. Artykuł przedstawia i weryfikuje konfigurację oraz rozszerzenie Nagios, umożliwiające monitorowanie systemów agentowych.
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Jacek Krenz dr hab. inż. arch.
PeopleJacek Krenz, born in 1948 in Poznań, Poland, is an academic architect and painter. He is a professor at Gdańsk University of Technology, Faculty of Architecture, taught also at University of Fine Arts in Poznań – both in Poland – and at Universidade da Beira Interior in Covilhã, Portugal. Charter member of The Polish Watercolour Society. He is a co-founder of the Wdzydze Artists’ Village in Kaszuby, Poland, where he works in his...
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Simple synthesis route for fabrication of protective photo‐crosslinked poly(zwitterionic) membranes for application in non‐enzymatic glucose sensing
PublicationThis work focuses on the fabrication of non-enzymatic glucose sensing materials based on laser-formed Au nanoparticles embedded in Ti-textured substrates. Those materials possess good catalytic activity toward glucose oxidation in 0.1 × phosphate buffered saline as well as resistance to some interferants, such as ascorbic acid, urea, and glycine. The electrodes are further coated with three different polymers, that is, Nafion,...
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Jerzy Łabanowski prof. dr hab. inż.
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Construction and investigation of SO2 amperometric sensor with a solid polymer electrolyte membrane
Publicationn this paper a sensor for detection of the sulphur dioxide based on three electrode cell configuration with a liquid electrolyte, a mercury sulphate reference electrode and a solid polymer electrolyte working electrode is presented. Working elec- trode was obtained by using Takenaka-Torikai chemical deposi- tion method by precipitation of Au particles into the pores of the Nafion membrane. Sensors characteristics measurements were...
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Chemical investigations of the MoO3 doped by K films deposited FTO
Open Research DataMoO3 thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The influence of photointercalation of alkali metal cation (K+) into the MoO3 structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated. The chemical characterisation...
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Theoretical and Experimental Studies on the Visible Light Activity of TiO2 Modified with Halide-Based Ionic Liquids
PublicationFormation of a surface complex between organic molecules and TiO2 is one of the possible strategies for the development of visible light-induced TiO2 photoactivity. Herein, three ionic liquids (ILs) with the same cation and dierent anions (1-butylpirydynium chloride/bromide/iodide) have been applied for the surface modification of TiO2 and to understand the role of anions in visible light-induced activity of ILs-TiO2 systems. Photocatalytic...
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Charakterystyka białek głównych surowców żywnościowych. Rozdział 6
PublicationBiałka mięśniowe mają w większości bardzo korzystny skład aminokwasowy i pożądane właściwości funkcjonalne. Są to białka cieczy międzykomórkowej i sarkoplazmy, białka włókien mięśniowych - przede wszystkim miozyna i aktyna, a także kolageny i elastyna. Wśród białek mleka największy udział mają kazeiny, uczestniczące w tworzeniu skrzepu w serowarstwie, zaś w serwatce są głównie β-laktoglobulina, α-laktoalbumina, immunoglobuliny,...
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Trzmiele- ważne owady zapylające. Wykorzystanie jako organizmów wskaźnikowych- wyzwanie dla analityków.
PublicationWiększość roślin do wydania owoców i nasion wymaga zapylenia przez owady, które w poszukiwaniu pokarmu- nektaru i pyłku- przenoszą go z jednego kwiatu na drugi. Tak jest w przypadku drzew i krzewów owocowych, a także wielu warzyw. Rośliny , pomimo obfitego kwitnienia wiosną, bez pomocy owadów nie wydadzą plonu latem. W krajobrazie rolniczym zapylenie roślin uprawnych jest tak samo ważnym czynnikiem plonotwórczym, jak nawożenie...
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Cross sections for ionization and ionic fragmentation of pyrimidine molecules by electron collisions
PublicationThe electron impact mass spectroscopy and the total ion collection measurements were used to investigate the ionization and ionic fragmentation of the pyrimidine, C4H4N2, molecules in the gasphase. The cation mass spectra were measured in the 10−85 amu range and the observed mass peaks assigned to corresponding ionic fragments. The most abundant cation in the mass spectra is the parent cation, C4H4N+2, at 80 amu. The appearance...