mgr inż. Sylwia Godlewska
Contact
- sylgodle@student.pg.edu.pl
Publication showcase
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Mononuclear sodium(I) and copper(I) silanethiolates
Stericallyencumberedligand(ArO) 3 SiS − , where Ar = 2,6-diisopropylphenyl, was employed for the synthesisof a dicoordinate copper(I) complex. The ligand creates a very hydrophobic environment around the metal center as indicated by the crystal structures and FT-IR spectroscopy.
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Propeller-Like Chirality of Methyl-Tris (2,6-diisopropylphenoxy)Silylsulfide
Two new methylsilylsulfides are synthesized. Propeller-like chirality is described for triaryloxysilanethiol and its methyl derivative. S-methylation of the silanethiol lowers the overall symmetry of the unit cell.
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Bromidotetrakis(1H-2-ethyl-5-methylimidazole-κN3)copper(II) bromide
Atom Cu(II) w tytułowym kompleksie jest skoordynowany przez cztery atomy N obojętnych cząsteczek imidazolu oraz jon bromkowy. Jon kompleksowy ma geometrię piramidy kwadratowej. Kationy kompleksowe w krysztale tworzą układ dipoli ułożonych ''głowa do ogona'' równolegle do osi c.
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