Novel fast analytical method for indirect determination of MCPD fatty acid esters in edible oils and fats based on simultaneous extraction and derivatization - Publikacja - MOST Wiedzy

Wyszukiwarka

Novel fast analytical method for indirect determination of MCPD fatty acid esters in edible oils and fats based on simultaneous extraction and derivatization

Abstrakt

A novel method for indirect determination of MCPD esters levels in lipid samples has been developed. The method is based on combination of extraction and derivatisation in the same sample preparation step. It is achieved by the application of diethyl ether as extraction solvent for isolation of released from esterified forms analytes from water phase and dilution solvent for solid PBA – derivatisation agent. It is a noteworthy improvement of recommended indirect approaches available in the literature, because such steps as sample clean-up, multiple liquid-liquid extractions and preconcentration are excluded in the proposed solution. In this way, developed procedure is shortened and simplified. Such approach also minimizes the utilization of organic solvents, therefore it is in accordance with the principles of “green analytical chemistry”. In spite of the fact that the step of sample clean-up is omitted, no deterioration in GC-MS system performance was observed. Equivalence testing of the developed procedure and AOCS cd 29b-13 official method (SGS) has been conducted. It was concluded that results obtained by both methods do not differ statistically significantly. The procedure has been applied to determination of MCPD esters concentrations in lipid fractions isolated by accelerated solvent extraction technique from such foodstuffs as bakery products, salty deep-fried snacks and instant products. In all investigated samples the level of bound MCPD was elevated. Additionally, for both procedures the environmental impact (with the use of analytical Eco-scale) and uncertainty budget have been assessed and compared.

Cytowania

  • 1 5

    CrossRef

  • 0

    Web of Science

  • 1 6

    Scopus

Cytuj jako

Pełna treść

pobierz publikację
pobrano 129 razy
Wersja publikacji
Accepted albo Published Version
Licencja
Creative Commons: CC-BY otwiera się w nowej karcie

Słowa kluczowe

Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
ANALYTICAL AND BIOANALYTICAL CHEMISTRY nr 409, wydanie 17, strony 4267 - 4278,
ISSN: 1618-2642
Język:
angielski
Rok wydania:
2017
Opis bibliograficzny:
Jędrkiewicz R., Głowacz-Różyńska A., Gromadzka J., Konieczka P., Namieśnik J.: Novel fast analytical method for indirect determination of MCPD fatty acid esters in edible oils and fats based on simultaneous extraction and derivatization// ANALYTICAL AND BIOANALYTICAL CHEMISTRY. -Vol. 409, iss. 17 (2017), s.4267-4278
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1007/s00216-017-0381-z
Bibliografia: test
  1. Velíšek J, Davidek J, Hajšlová J, Kubelka V, Janíček G, Mánková B. Chlorohydrins in protein hydrolysates. Z Lebensm Unters Forsch. 1978;163:241-4. otwiera się w nowej karcie
  2. Brown-Woodman PDC, White IG, Ridley DD. The antifertility activity and toxicity of α-chlorohydrin derivatives in male rats. Contraception. 1979;19:517-29. otwiera się w nowej karcie
  3. Kwack SJ, Kim SS, Choi YW, Rhee GS, Lee RD, Seok JH, et al. Mechanism of antifertility in male rats treated with 3-monochloro- 1, 2-propanediol (3-MCPD). J Toxicol Environ Health. 2004;67: 2001-11. otwiera się w nowej karcie
  4. Cho WS, Han BS, Nam KT, Park K, Choi M, Kim SH, et al. Carcinogenicity study of 3-monochloropropane-1,2-diol in Sprague-Dawley rats. Food Chem Toxicol. 2008;46:3172-7. otwiera się w nowej karcie
  5. Svejkovská B, Novotny O, Divinova V, Reblova Z, Doležal M, Velíšek J. Esters of 3-chloropropane-1, 2-diol in foodstuffs. Czech J Food Sci. 2004;22:190-6. otwiera się w nowej karcie
  6. Zelinková Z, Svejkovská B, Velíšek J, Doležal M. Fatty acid esters of 3-chloropropane-1, 2-diol in edible oils. Food Addit Contam. 2006;23:1290-8. otwiera się w nowej karcie
  7. Craft BD, Chiodini A, Garst J, Granvogl M. Fatty acid esters of monochloropropanediol (MCPD) and glycidol in refined edible oils. Food Addit Contam. 2013;30:46-51. otwiera się w nowej karcie
  8. Fiebig HJ. Determination of ester-bound 3-chloro-1, 2-propanediol, and glycidol in fats and oils-a collaborative study. Eur J Lipid Sci Technol. 2011;113:393-9. otwiera się w nowej karcie
  9. Razak RAA, Kuntom A, Siew WL, Ibrahim NA, Ramli MR, H u s s e i n R , e t a l . D e t e c t i o n a n d m o n i t o r i n g o f 3 - monochloropropane-1, 2-diol (3-MCPD) esters in cooking oils. Food Control. 2012;25:355-60.
  10. Jędrkiewicz R, Głowacz A, Gromadzka J, Namieśnik J. Determination of 3-MCPD and 2-MCPD esters in edible oils, fish oils, and lipid fractions of margarines available in Polish market. Food Control. 2016;59:487-92. otwiera się w nowej karcie
  11. Jędrkiewicz R, Głowacz-Różyńska A, Gromadzka J, Kloskowski A, Namieśnik J. Indirect determination of MCPD fatty acid esters in lipid fractions of commercially available infant formulas for the assessment of infants' health risk. Food Anal Methods. 2016;9: 3460-9. otwiera się w nowej karcie
  12. Svejkovská B, Doležal M, Velíšek J. Formation and decomposition of 3-chloropropane-1, 2-diol esters in models simulating processed foods. Czech J Food Sci. 2006;24:172-9. otwiera się w nowej karcie
  13. Hrnčiřík K, van Duijn G. An initial study on the formation of 3- MCPD esters during oil refining. Eur J Lipid Sci Technol. 2011;113:374-9.
  14. Ermacora A, Hrnčiřík K. Influence of oil composition on the for- mation of fatty acid esters of 2-chloropropane-1, 3-diol (2-MCPD) and 3-chloropropane-1, 2-diol (3-MCPD) under conditions simu- lating oil refining. Food Chem. 2014;161:383-9. otwiera się w nowej karcie
  15. Buhrke T, Weisshaar R, Lampen A. Absorption and metabolism of the food contaminant 3-chloro-1, 2-propanediol (3-MCPD), and its fatty acid esters by human intestinal Caco-2 cells. Arch Toxicol. 2011;85:1201-8. otwiera się w nowej karcie
  16. Bakhiya N, Abraham K, Gürtler R, Appel KE, Lampen A. Toxicological assessment of 3-chloropropane-1, 2-diol, and glycidol fatty acid esters in food. Mol Nutr Food Res. 2011;55: 509-21. otwiera się w nowej karcie
  17. Appel KE, Abraham K, Berger-Preiss E, Hansen T, Apel E, Schuchardt S, et al. Relative oral bioavailability of glycidol from glycidyl fatty acid esters in rats. Arch Toxicol. 2013;87:1649-59. otwiera się w nowej karcie
  18. Commission recommendation on the monitoring of the presence of 2-and 3-monochloropropane-1,2-diol (2 and 3-MCPD), 2-and 3- MCPD fatty acid esters, and glycidyl fatty acid esters in food. Official J Eur Union (2014/661/EU) otwiera się w nowej karcie
  19. Habermeyer M, Guth S, Eisenbrand G. Identification of gaps in knowledge concerning toxicology of 3-MCPD and glycidol esters. Eur J Lipid Sci Technol. 2011;113:314-8. otwiera się w nowej karcie
  20. Infant formula and follow-up formula may contain harmful 3- MCPD fatty acid esters. BfR Opinion No. 047/2007 otwiera się w nowej karcie
  21. Collaborative Study for the determination of 3-MCPD-and 2- MCPD fatty acid esters in fat containing foods. BfR. 2013 otwiera się w nowej karcie
  22. EFSA Scientific Opinion on 3-MCPD and GE. Risks for human health related to the presence of 3-and 2-monochloropropanediol (MCPD), and their fatty acid esters, and glycidyl fatty acid esters in food. EFSA J. 2016;14:4426. otwiera się w nowej karcie
  23. Crews C, Chiodini A, Granvogl M, Hamlet C, Hrncirik K, Kuhlmann J, et al. Analytical approaches for MCPD esters and glycidyl esters in food and biological samples: a review and future perspectives. Food Addit Contam. 2012;30:11-45. otwiera się w nowej karcie
  24. Haines TD, Adlaf KJ, Pierceall RM, Lee I, Venkitasubramanian P, Collison MW. Direct determination of MCPD fatty acid esters and glycidyl fatty acid esters in vegetable oils by LC-TOFMS. J Am Oil Chem Soc. 2011;88:1-14. otwiera się w nowej karcie
  25. MacMahon S, Ridge CD, Begley TH. Liquid chromatography-tan- dem mass spectrometry (LC-MS/MS) method for the direct detec- tion of 2-monochloropropanediol (2-MCPD) esters in edible oils. J Agric Food Chem. 2014;62:11647-56. otwiera się w nowej karcie
  26. Dubois M, Tarres A, Goldmann T, Empl AM, Donaubauer A, Seefelder W. Comparison of indirect and direct quantification of esters of monochloropropanediol in vegetable oil. J Chromatogr A. 2012;1236:189-201. otwiera się w nowej karcie
  27. Kuhlmann J. Determination of bound 2, 3-epoxy-1-propanol (glycidol) and bound monochloropropanediol (MCPD) in refined oils. Eur J Lipid Sci Technol. 2011;113:335-44. otwiera się w nowej karcie
  28. Ermacora A, Hrnčiřík K. A novel method for simultaneous moni- toring of 2-MCPD, 3-MCPD and glycidyl esters in oils and fats. J Am Oil Chem Soc. 2013;90:1-8. otwiera się w nowej karcie
  29. Hrnčiřík K, Zelinková Z, Ermacora A. Critical factors of indirect determination of 3-chloropropane-1, 2-diol esters. Eur J Lipid Sci Technol. 2011;113:361-7.
  30. AOCS official method Cd 29b-13 reapproved (2017) 2-and 3- MCPD fatty acid esters and glycidol fatty acid esters in edible oils and fats by alkaline transesterification and GC/MS 31. AOCS official method Cd 29a-13 reapproved (2017) 2-and 3- MCPD fatty acid esters and glycidol fatty acid esters in edible oils and fats by acid transesterification and GC/MS otwiera się w nowej karcie
  31. Gałuszka A, Konieczka P, Migaszewski ZM, Namieśnik J. Analytical Eco-Scale for assessing the greenness of analytical pro- cedures. Trends Anal Chem. 2012;37:61-72. otwiera się w nowej karcie
Weryfikacja:
Politechnika Gdańska

wyświetlono 177 razy

Publikacje, które mogą cię zainteresować

Meta Tagi