Widening of the electroactivity potential range by composite formation – capacitive properties of TiO2/BiVO4/PEDOT:PSS electrodes in contact with an aqueous electrolyte - Publikacja - MOST Wiedzy

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Widening of the electroactivity potential range by composite formation – capacitive properties of TiO2/BiVO4/PEDOT:PSS electrodes in contact with an aqueous electrolyte

Abstrakt

Composites based on the titania nanotubes were tested in aqueous electrolyte as a potential electrode material for energy storage devices. The nanotubular morphology of TiO2 was obtained by Ti anodization. TiO2 nanotubes were covered by a thin layer of bismuth vanadate using pulsed laser deposition. The formation of the TiO2/BiVO4 junction leads to enhancement of pseudocapacitance in the cathodic potential range. The third component, the conjugated polymer PEDOT:PSS, was electrodeposited from an electrolyte containing the monomer EDOT and NaPSS as a source of counter ions. Each stage of modification and deposition affected the overall capacitance and allowed for an expansion of the potential range of electroactivity. Multiple charge/discharge cycles were performed to characterize the electrochemical stability of the inorganic–organic hybrid electrode. Capacitance values higher than 10 mF·cm−2 were maintained even after 10000 galvanostatic cycles (ic = ia = 0.5 mA·cm−2).

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Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
Beilstein Journal of Nanotechnology nr 10, strony 483 - 493,
ISSN: 2190-4286
Język:
angielski
Rok wydania:
2019
Opis bibliograficzny:
Trzciński K., Szkoda M., Nowak A., Łapiński M. S., Lisowska-Oleksiak A.: Widening of the electroactivity potential range by composite formation – capacitive properties of TiO2/BiVO4/PEDOT:PSS electrodes in contact with an aqueous electrolyte// Beilstein Journal of Nanotechnology. -Vol. 10, (2019), s.483-493
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3762/bjnano.10.49
Weryfikacja:
Politechnika Gdańska

wyświetlono 185 razy

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