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A method for the analysis of methylmercury and total Hg in fungal matrices

Abstrakt

The aim of the study was to develop an efficient method for the determination of monomethyl-mercury (MeHg) and total mercury (THg) content in materials such as fungal sporocarps and sclerotia. Certified Reference Materials (CRMs) with the assigned values of MeHg and THg as well as the control materials (dried mushrooms) with known content of THg were evaluated for method validation. Recovery of MeHg from reference materials was at the following levels: from tuna fish at 87.0 ± 2.3% (THg at 101.9 ± 1.2%), from fish protein at 99.4 ± 1.3% (THg at 92.70 ± 0.41%), and from dogfish liver at 96.45 ± 0.73%. Recovery of THg from the fungal control material CS-M-5 was at 104.01 ± 0.60% (contribution of MeHg in THg content was at 6.2%), from CS-M-4 at 101.1 ± 2.0% (contribution at 3.2%), from CS-M-3 at 100.55 ± 0.67% (contribution at 0.6%), and from CS-M-2 at 101.5 ± 2.7% (contribution at 3.7%). The content of MeHg in randomly selected wild fungi and their morphological parts was in the range from 0.006 to 0.173 mg kg−1 dry weight (dw). In the case of THg, the concentration values were in the range from 0.0108 to 10.27 mg kg−1 dw. The MeHg content in the control materials with the assigned THg values was determined. Since the control materials play an important role in all elements of the quality assurance system of measurement results, they can be used to analyse MeHg as the first control material for fungi.

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Accepted albo Published Version
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1007/s00253-022-12043-5
Licencja
Copyright (2022 Springer-Verlag GmbH Germany, part of Springer Nature)

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Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuły w czasopismach
Opublikowano w:
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY nr 106, strony 5261 - 5272,
ISSN: 0175-7598
Język:
angielski
Rok wydania:
2022
Opis bibliograficzny:
Rutkowska M., Falandysz J., Saba M., Szefer P., Misztal-Szkudlińska M., Konieczka P.: A method for the analysis of methylmercury and total Hg in fungal matrices// APPLIED MICROBIOLOGY AND BIOTECHNOLOGY -Vol. 106, (2022), s.5261-5272
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1007/s00253-022-12043-5
Źródła finansowania:
  • COST_FREE
Weryfikacja:
Politechnika Gdańska

wyświetlono 362 razy

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