Capacitance Enhancement by Incorporation of Functionalised Carbon Nanotubes into Poly(3,4-Ethylenedioxythiophene)/Graphene Oxide Composites - Publikacja - MOST Wiedzy

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Capacitance Enhancement by Incorporation of Functionalised Carbon Nanotubes into Poly(3,4-Ethylenedioxythiophene)/Graphene Oxide Composites

Abstrakt

This paper reports on the role of oxidised carbon nanotubes (oxMWCNTs) present in poly-3,4-ethylenedioxytiophene (PEDOT)/graphene oxide (GOx) composite. The final ternary composites (pEDOT/GOx/oxMWCNTs) are synthesised by an electrodeposition process from the suspension-containing monomer, oxidised carbon nanotubes and graphene oxide. Dissociated functional groups on the surface of graphene oxide play a role of counter-ions for the polymer chains. Detailed physicochemical and electrochemical characterisation of the ternary composites is presented in the paper. The results prove that the presence of oxMWCNTs in the ternary composites doubles the capacitance values compared to the binary ones (450 vs. 270 F cm3 for PEDOT/GOx/oxMWCNTs and PEDOT/GOx, respectively). The amount of carbon nanotubes in the synthesis solution is crucial for physicochemical properties of the composites, their adhesion to the electrode substrate and the electrochemical performance.

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Kategoria:
Publikacja w czasopiśmie
Typ:
artykuły w czasopismach
Opublikowano w:
Materials nr 13, strony 2419 - 2435,
ISSN: 1996-1944
Język:
angielski
Rok wydania:
2020
Opis bibliograficzny:
Cymann A., Sawczak M., Ryl J., Klugmann-Radziemska E., Wilamowska-Zawłocka M.: Capacitance Enhancement by Incorporation of Functionalised Carbon Nanotubes into Poly(3,4-Ethylenedioxythiophene)/Graphene Oxide Composites// Materials -Vol. 13,iss. 10 (2020), s.2419-2435
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3390/ma13102419
Źródła finansowania:
Weryfikacja:
Politechnika Gdańska

wyświetlono 171 razy

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