Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples - Publikacja - MOST Wiedzy

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Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples

Abstrakt

Developed and validated analytical methods for the determination of a wide spectrum of pesticide residues in honey and honeybee samples after the modification of QuEChERS extraction in combination with gas chromatography–tandem quadrupole mass spectrometry (GC-MS/MS) and liquid chromatography–tandem quadrupole mass spectrometry (LC-MS/MS) were discussed and compared. The developed methods were evaluated regarding the utilized equipment and reagents using Eco-Scale and compared in terms of extraction time, accuracy, precision, sensitivity and versatility, with similar procedures. The results proved that the QuEChERS protocol in combination with LC and GC techniques fulfills the requirements of green analytical chemistry, so it can be used as a tool in environmental monitoring. The recovery was 85–116% for honey and 85.5–103.5% for honeybee samples. The developed methods were successfully applied in monitoring real samples collected from three districts of Pomerania in Poland. Analysis of real samples revealed the presence of the following pesticides: bifenthrin, fenpyroximate, methidathione, spinosad, thiamethoxam, triazophos, metconazole and cypermethrin at levels higher than the MRLs established by the EU.

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Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
MOLECULES nr 23, wydanie 10, strony 2582 - 2595,
ISSN: 1420-3049
Język:
angielski
Rok wydania:
2018
Opis bibliograficzny:
Bargańska Ż., Konieczka P., Namieśnik J.: Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples// MOLECULES. -Vol. 23, iss. 10 (2018), s.2582-2595
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3390/molecules23102582
Bibliografia: test
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  45. Sample Availability: Samples of the compounds are not available from the authors. © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). otwiera się w nowej karcie
Weryfikacja:
Politechnika Gdańska

wyświetlono 49 razy

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