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(CsX)Cu5O2(PO4)2 (X = Cl, Br, I): A Family of Cu2+ S = 1/2 Compounds with Capped-Kagomé Networks Composed of OCu4 Units
Abstrakt
Three new salt inclusion compounds (CsX)Cu5O2(PO4)2 (X = Cl, Br, I), phosphate analogues of the kagomé mineral averievite, are reported. Their crystal structures are composed of trigonal networks of corner-sharing OCu4 anion-centered tetrahedra, forming capped-kagomé planes, which can also be regarded as two-dimensional slices along the [111] direction of a pyrochlore lattice. Magnetization and heat capacity measurements reveal strong geometric frustration of this network and complex magnetic behavior. X-ray and neutron diffraction studies show that all three compounds undergo a trigonal-to-monoclinic phase transition upon cooling, with a first-order phase transition seen in CsBr and CsI analogues. Along with the previously reported (CsCl)Cu5O2(VO4)2, these three new compounds belong to a large family of OCu4-based networks, which are a playground for studying frustrated quantum magnetism.
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Autorzy (4)
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Thao Tran
- Johns Hopkins University Department of Chemistry, Department of Physics and Astronomy, and Institute for Quantum Matter
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Juan Chamorro
- Johns Hopkins University Department of Chemistry, Department of Physics and Astronomy, and Institute for Quantum Matter
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Tyrel McQueen
- Johns Hopkins University Department of Chemistry, Department of Physics and Astronomy, Department of Materials Science and Engineering, and Institute for Quantum Matter
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Pełna treść
- Wersja publikacji
- Accepted albo Published Version
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1021/acs.inorgchem.8b03464
- Licencja
- Copyright (2019 American Chemical Society)
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuł w czasopiśmie wyróżnionym w JCR
- Opublikowano w:
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INORGANIC CHEMISTRY
nr 58,
wydanie 7,
strony 4328 - 4336,
ISSN: 0020-1669 - Język:
- angielski
- Rok wydania:
- 2019
- Opis bibliograficzny:
- Winiarski M., Tran T., Chamorro J., Mcqueen T.: (CsX)Cu5O2(PO4)2 (X = Cl, Br, I): A Family of Cu2+ S = 1/2 Compounds with Capped-Kagomé Networks Composed of OCu4 Units// INORGANIC CHEMISTRY. -Vol. 58, iss. 7 (2019), s.4328-4336
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1021/acs.inorgchem.8b03464
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 99 razy
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