Design and characterization of apatite La9.8Si5.7Mg0.3O26±δ-based micro-tubular solid oxide fuel cells - Publikacja - MOST Wiedzy

Twoje konto

zaloguj

Wyszukiwarka

Design and characterization of apatite La9.8Si5.7Mg0.3O26±δ-based micro-tubular solid oxide fuel cells

Abstrakt

In this study, electrolyte-supported (Cell A) and anode-supported (Cell B) micro-tubular solid oxide fuel cells (SOFCs) based on the La9.8Si5.7Mg0.3O26±δ (LSMO) electrolyte is built through an extrusion and dip-coating processes. The formulations and process conditions for these cells are established and optimized. Both cell configurations show no visible delamination or cracking, and reaction zones and inter-diffusion of any species are absent at the interfaces of the multilayer structures. The micro-tubes LSMO and LSMO-NiO have a high flexural strength of ~70 MPa. Cell B with a 3.33 mm outer diameter, a 12 μm LSMO electrolyte layer, a ~300 μm LSMO-NiO functional anode layer, a 9 μm NiO current-collector layer, and a 44 μm La0.6Sr0.4Co0.2Fe0.8O3-δ cathode layer has superior electrochemical performances than does Cell A. The polarization resistance (Rp) value for Cell B accounts for 67.6% and 50.5% of the total resistance (Rt) value at 700 °C and 895 °C, respectively, suggesting that Rp dominates at low temperatures and ohmic resistance (Ro) and Rp values are equally important at high temperatures. Cell B's open-circuit voltages (OCVs) are slightly below the theoretical value due to poor sealing of cells. The maximum power densities (MPDs) of Cell B, increase with increasing operating temperature and are 0.12, 0.24, and 0.27 W cm−2 at 750 °C, 850 °C, and 895 °C, respectively. Compared to Cell A, Cell B displays lower OCV values but higher MPD (0.27 W cm−2 vs. 0.06 W cm−2 at 895 °C) due to its significantly lower Ro value, mainly due to the thin layer of LSMO electrolytes.

Cytowania

  • 1 1

    CrossRef

  • 0

    Web of Science

  • 1 3

    Scopus

Autorzy (5)

Cytuj jako

Pełna treść

pełna treść publikacji nie jest dostępna w portalu

Słowa kluczowe

Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuły w czasopismach
Opublikowano w:
JOURNAL OF POWER SOURCES nr 460,
ISSN: 0378-7753
Język:
angielski
Rok wydania:
2020
Opis bibliograficzny:
Wang S., Hsu Y., Hsia P., Hung W., Jasiński P.: Design and characterization of apatite La9.8Si5.7Mg0.3O26±δ-based micro-tubular solid oxide fuel cells// JOURNAL OF POWER SOURCES -Vol. 460, (2020), s.228072-
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.jpowsour.2020.228072
Weryfikacja:
Politechnika Gdańska

wyświetlono 141 razy

Publikacje, które mogą cię zainteresować

Characteristics of La0.8Sr0.2Ga0.8Mg0.2O3-delta -supported micro-tubular solid oxide fuel cells with bi-layer and tri-layer electrolytes

  • Y. Liu,
  • S. Wang,
  • Y. Hsu
  • + 1 autorów
2017

High-performance anode-supported solid oxide fuel cells with co-fired Sm0.2Ce0.8O2-δ/La0.8Sr0.2Ga0.8Mg0.2O3−δ/Sm0.2Ce0.8O2-δ sandwiched electrolyte

  • S. Wang,
  • H. Lu,
  • Y. Hsu
  • + 1 autorów
2022

Effects of Ni-NCAL and Ni–Ag electrodes on the cell performances of low-temperature solid oxide fuel cells with Sm0.2Ce0·8O2-δ electrolyte at various temperatures

  • S. Wang,
  • Y. Liao,
  • Y. Hsu
  • + 1 autorów
2022

Effects of La0.8Sr0.2MnO3 and Ag electrodes on bismuth-oxide-based low-temperature solid electrolyte oxygen generators

  • J. Tsai,
  • S. Wang,
  • Y. Hsu
  • + 1 autorów
2022
Meta Tagi