Effect of alkyl sulfate on the phase behavior of microemulsions stabilized with monoacylglycerols - Publikacja - MOST Wiedzy

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Effect of alkyl sulfate on the phase behavior of microemulsions stabilized with monoacylglycerols

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In this study the effect of an anionic surfactant (sodium dodecyl sulfate SDS) and oils (hydrocarbons: C12-C16) on the formation and phase behavior of the systems of oil/monoacylglycerols (MAG):SDS/propylene glycol/water has been investigated. The effects of the surfactant mixture on the phase behavior and the concentrationof water or oil in the systems were studied at three temperatures (50, 55, 60 C). Electrical conductivity measurement, FT-IR spectroscopy and differential scanning calorimetry methods were applied to determine the structure and type of the microemulsions formed. The dimension of microemulsion droplets was characterizedby dynamic light scattering. It has been stated that the concentration of SDS has a strong influence on the shape and extent of the microemulsion areas. Addition of an ionic surfactant to the mixture with MAG promotes an increase in the area of microemulsion formation in the phase diagrams, and these areas of the isotropic region change with the temperature. It was shown that the presence in the systems of a surfactant more hydrophilic than MAG caused an increase in water content in the microemulsions. It was found that, depending on temperature and concentration of the surfactant mixture, it was possible to obtain a W/O type microemulsion with a dispersed particles size distribution ranging from 20 to 50 nm and containing about 17-38% water in the system. Among different alkanes (from C12 toC16), hexadecane embedded microemulsions showed a maximum water solubilization capacity.

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Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
JOURNAL OF SURFACTANTS AND DETERGENTS nr 14, strony 245 - 255,
ISSN: 1097-3958
Język:
angielski
Rok wydania:
2011
Opis bibliograficzny:
Szeląg H., Szumała P.: Effect of alkyl sulfate on the phase behavior of microemulsions stabilized with monoacylglycerols// JOURNAL OF SURFACTANTS AND DETERGENTS. -Vol. 14, nr. No. 2 (2011), s.245-255
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1007/s11743-010-1220-9
Weryfikacja:
Politechnika Gdańska

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