Enhanced Mechanical and Electromechanical Properties of Compositionally Complex Zirconia Zr1–x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2−δ Ceramics - Publikacja - MOST Wiedzy

Twoje konto

zaloguj

Wyszukiwarka

Enhanced Mechanical and Electromechanical Properties of Compositionally Complex Zirconia Zr1–x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2−δ Ceramics

Abstrakt

Compositionally complex oxides (CCOs) or high-entropy oxides (HEOs) are new multi-element oxides with unexplored physical and functional properties. In this work, we report fluorite structure derived compositionally complex zirconia with composition Zr1- x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2-δ (x = 0.1 and 0.2) synthesized in solid-state reaction route and sintered via hot pressing at 1350 °C. We explore the evolution of these oxides' structural, microstructural, mechanical, electrical, and electromechanical properties regarding phase separation and sintering mechanisms. Highly dense ceramics are achieved by bimodal mass diffusion, composing nanometric tetragonal and micrometric cubic grains microstructure. The material exhibits an anomalously large electrostriction response exceeding the M33 value of 10−17 m 2 /V2 at room temperatures and viscoelastic properties of primary creep in nanoindentation measurement under fast loading. These findings are strikingly similar to those reported for doped ceria and bismuth oxide derivates, highlighting the presence of a large concentration of point defects linked to structural distortion and anelastic behavior are characteristics of nonclassical ionic electrostrictors.

Cytowania

  • 2

    CrossRef

  • 0

    Web of Science

  • 1

    Scopus

Autorzy (8)

Cytuj jako

Pełna treść

pełna treść publikacji nie jest dostępna w portalu

Słowa kluczowe

Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuły w czasopismach
Opublikowano w:
ACS Applied Materials & Interfaces nr 16, strony 12765 - 12772,
ISSN: 1944-8244
Język:
angielski
Rok wydania:
2024
Opis bibliograficzny:
Kabir A., Lemieszek B., Varenik M., Buratto Tinti V., Molin S., Lubomirsky I., Esposito V., Kern F.: Enhanced Mechanical and Electromechanical Properties of Compositionally Complex Zirconia Zr1–x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2−δ Ceramics// ACS Applied Materials & Interfaces -Vol. 16,iss. 10 (2024), s.12765-12772
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1021/acsami.3c17501
Źródła finansowania:
Weryfikacja:
Politechnika Gdańska

wyświetlono 61 razy

Publikacje, które mogą cię zainteresować

Novel Class of Proton Conducting Materials—High Entropy Oxides

2020

Electronic and ionic relaxations in strontium-borate glass and glass-ceramics containing bismuth and vanadium oxides

2015

Charge Transport in High-Entropy Oxides

2023

What is in a name: Defining “high entropy” oxides

  • M. Brahlek,
  • M. Gazda,
  • V. Keppens
  • + 10 autorów
2022
Meta Tagi