Enhanced photoelectrochemical performance of inorganic-organic hybrid consisting of BiVO4 and PEDOT:PSS
Abstrakt
The PEDOT:PSS (poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)) was electrodeposited on a thin layer of bismuth vanadate (BiVO 4 ) prepared using the pulsed laser deposition technique onto FTO. The inorganic-organic junction was characterized by Raman spectroscopy, UV-Vis spectroscopy and sc anning electron microscopy. Chronoamperometry curves, recorded under simulated solar light illumination, were performed to determine generated photocurrent during water and hydroquinone oxidation at the electrode surface. Experiments were performed for three types of electrode materials: i) FTO/BiVO 4 , ii) FTO/PEDOT:PSS and iii) FTO/BiVO 4 /PEDOT:PSS in aqueous electrolyte. Almost 5 times higher photocurrent in electrolyte containing hole scavenger was generated after modification of BiVO 4 photoanode with electrodeposited polymer. It is noteworthy that anodic photocurrent was stable even after 4 h of illumination. Cyclic voltammetry curves of FTO/BiVO 4 /PEDOT:PSS recorded before and after experiments performed under electrode illumination indicated that the organic part in tested junction is photo-corrosion resistant.
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Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuł w czasopiśmie wyróżnionym w JCR
- Opublikowano w:
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APPLIED SURFACE SCIENCE
nr 388,
strony 753 - 761,
ISSN: 0169-4332 - Język:
- angielski
- Rok wydania:
- 2016
- Opis bibliograficzny:
- Trzciński K., Szkoda M., Siuzdak K., Sawczak M., Lisowska-Oleksiak A.: Enhanced photoelectrochemical performance of inorganic-organic hybrid consisting of BiVO4 and PEDOT:PSS// APPLIED SURFACE SCIENCE. -Vol. 388, nr. part B (2016), s.753-761
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.apsusc.2016.02.143
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 185 razy
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