Highly stable CsFAPbIBr perovskite solar cells with dominant bulk recombination at real operating temperatures

Beatriz Romero; Silvia Delgado; Damian Głowienka; Cheng-Tsung Chang; Gonzalo Del Pozo; Belén Arredondo; Diego Martín-Martín; Pedro Contreras; Yulia Galagan

doi:10.1039/d2se01766k

Highly stable CsFAPbIBr perovskite solar cells with dominant bulk recombination at real operating temperatures

Abstrakt

Mixed-cation mixed-halide perovskite solar cells have been characterized in DC at different temperatures (from −20 °C up to 50 °C) and the time evolution of the device efficiency has been assessed using different degradation protocols (indoors and outdoors). The completely planar p–i–n structure is ITO/CuNiOx/PTAA/CsFAPbIBr/PCBM/PEI/Ag. Pristine current–voltage characteristics barely show hysteresis, at any temperature. Open circuit voltage decreases with temperature at a rate of −1.5 mV °C−1, and the obtained PCE temperature coefficient is lower than −0.001% K−1, which is an outstanding value for this emerging photovoltaic technology. Cells have been degraded under different protocols: indoors using different light/dark cycles and outdoors in a high temperature and high irradiation location. Cells show no significant decrease of the efficiency after more than 350 h of indoor light cycling and the estimated T80 obtained for the sample degraded outdoors under high irradiation and high temperature conditions is ∼15 days.

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Autorzy (9)

Beatriz Romero Prof
Silvia Delgado
Damian Głowienka dr inż.
Cheng-Tsung Chang
Gonzalo Del Pozo
Belén Arredondo
Diego Martín-Martín
Pedro Contreras
Yulia Galagan dr

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Wersja publikacji: Accepted albo Published Version
DOI:: Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.34808/m46x-ym10
Licencja: Copyright (2023 Royal Society of Chemistry)

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Kategoria:

Publikacja w czasopiśmie

Typ:

artykuły w czasopismach

Opublikowano w:

Sustainable Energy & Fuels nr 7, strony 2146 - 2152,
ISSN: 2398-4902

Język:

angielski

Rok wydania:

2023

Opis bibliograficzny:

Romero B., Delgado S., Głowienka D., Chang C., Del Pozo G., Arredondo B., Martín-Martín D., Contreras P., Galagan Y.: Highly stable CsFAPbIBr perovskite solar cells with dominant bulk recombination at real operating temperatures// Sustainable Energy & Fuels -Vol. 7,iss. 9 (2023), s.2146-2152

DOI: