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Morphology control through the synthesis of metal-organic frameworks

Abstrakt

Designable morphology and predictable properties are the most challenging goals in material engineering. Features such as shape, size, porosity, agglomeration ratio significantly affect the final properties of metal- organic frameworks (MOFs) and can be regulated throughout synthesis parameters but require a deep under- standing of the mechanisms of MOFs formation. Herein, we systematically summarize the effects of the indi- vidual synthesis factors, such as pH of reaction mixture, including acidic or basic character of modulators, temperature, solvents types, surfactants type and content and ionic liquids on the morphology of growing MOFs. We identified main mechanisms of MOFs’ growth leading to different morphology of final particles and next systematically discuss the effect of miscellaneous parameters on MOFs morphology based on the main mecha- nisms related to the nucleation, growth and formation of final MOFs structure, including coordination modu- lation, protonation/deprotonation acting and modulation by surfactants or capping agents. The effect of microwaves and ultrasound employment during synthesis is also considered due to their affecting especially nucleation and particles growing steps during MOFs formation

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Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuły w czasopismach
Opublikowano w:
ADVANCES IN COLLOID AND INTERFACE SCIENCE nr 314,
ISSN: 0001-8686
Język:
angielski
Rok wydania:
2023
Opis bibliograficzny:
Łuczak J., Kroczewska M., Baluk M., Sowik J., Mazierski P., Zaleska-Medynska A.: Morphology control through the synthesis of metal-organic frameworks// ADVANCES IN COLLOID AND INTERFACE SCIENCE -Vol. 314, (2023), s.102864-
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.cis.2023.102864
Źródła finansowania:
Weryfikacja:
Politechnika Gdańska

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