Wyszukiwarka
New nanoadsorbent based on magnetic iron oxide containing 1,4,7,10-tetraazacyclododecane in outer chain (Fe3O4@SiO2-cyclen) for adsorption and removal of selected heavy metal ions Cd2+, Pb2+, Cu2+
Abstrakt
Magnetic Fe3O4@SiO2-cyclen nanoparticles were prepared and used as adsorbent for Cd2+, Pb2+ and Cu2+ from aqueous solution removal process controlled with differential pulse anodic stripping voltammetry (DPASV) and hanging mercury drop electrode (HDME). Nanomaterial was synthesised in three-step process co-precipitation of Fe3O4 core, coating with silane and N-(3-(triethoxysilyl)propyl)-1,4,7,10-tetraazacyclododecane-1-carboxamide silane functionalisation. The effectiveness of each step of the synthesis was confirmed using scanning electron microscopy (SEM), high-resolution X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (pXRD) and fourier-transform infrared spectroscopy (FT-IR) techniques. The Fe3O4@SiO2-cyclen nanoparticles were employed for Cd2+, Pb2+ and Cu2+ ions elimination from individual and mixed solutions by carrying out titration with a suspension of nanocomposites. The binding level for all ions both in the individual solutions and in the mixture was very similar at high levels. For Cd2+ and Cu2+ ions sorption efficiency level was from 83% to 89%, while for Pb2+ ions it was slightly lower at the level over 73%. In all cases, the equilibrium adsorption capacity parameter was over 1 mg/g and reached definitely higher values for individual ions solutions. The research results revealed that Fe3O4@SiO2- cyclen nanoparticles can be a promising adsorbent for magnetic heavy metal ions water treatment agents.
Cytowania
-
1 5
CrossRef
-
0
Web of Science
-
2 0
Scopus
Autorzy (4)
-
Amanda Kulpa-Koterwa
-
Paweł Niedziałkowski Dr
Cytuj jako
Pełna treść
- Wersja publikacji
- Accepted albo Published Version
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.molliq.2022.120710
- Licencja
-
otwiera się w nowej karcie
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuły w czasopismach
- Opublikowano w:
-
JOURNAL OF MOLECULAR LIQUIDS
nr 368,
ISSN: 0167-7322 - Język:
- angielski
- Rok wydania:
- 2022
- Opis bibliograficzny:
- Kulpa-Koterwa A., Ryl J., Górnicka K., Niedziałkowski P.: New nanoadsorbent based on magnetic iron oxide containing 1,4,7,10-tetraazacyclododecane in outer chain (Fe3O4@SiO2-cyclen) for adsorption and removal of selected heavy metal ions Cd2+, Pb2+, Cu2+// JOURNAL OF MOLECULAR LIQUIDS -Vol. 368,iss. Part B (2022), s.120710-
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.molliq.2022.120710
- Źródła finansowania:
-
- Publikacja bezkosztowa
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 101 razy
Publikacje, które mogą cię zainteresować
Simultaneous voltammetric determination of Cd2+, Pb2+, and Cu2+ ions captured by Fe3O4@SiO2 core-shell nanostructures of various outer amino chain length
- A. Kulpa,
- J. Ryl,
- G. Schroeder
- + 4 autorów
Comparison of Cadmium Cd2+ and Lead Pb2+ Binding by Fe2O3@SiO2‐EDTA Nanoparticles – Binding Stability and Kinetic Studies
- A. Kulpa,
- J. Ryl,
- G. Skowierzak
- + 4 autorów
Cu( II ) ions removal from wastewater using starch nanoparticles ( SNPs ): An Eco‐sustainable approach
- V. S. Hakke,
- V. K. Landge,
- S. H. Sonawane
- + 3 autorów