Studies on novel BiyXz-TiO2/SrTiO3 composites: Surface properties and visible light-driven photoactivity
Abstrakt
A series of novel BiyXz-TiO2/SrTiO3 composites were prepared by multistep synthesis route. The asprepared photocatalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy (DRS), Fourier transform infrared (FT-IR), Raman spectra and BET analysis. The photocatalytic activity test was performed in aqueous solution of phenol under the irradiation of visible light range ( ≥ 420 nm). Obtained results revealed that the BiOI TiO2/SrTiO3 sample exhibit the highest photocatalytic activity under visible irradiation (0.6 mol/dm3/min). Thus, it was demonstrated that modification of the TiO2/SrTiO3 microspheres by flowers-like structure made of bismuth oxyiodide resulted in enhancement of photocatalytic activity under visible light. The role of active species during the decomposition process of organic compound was investigated using different types of active species scavengers as well as electron paramagnetic resonance analysis (EPR). The study showed that in the BiOI TiO2/SrTiO3/Vis system the holes (h+) plays relevant role in phenol decomposition. Furthermore, the stability and recyclable properties of obtained BiOI TiO2/SrTiO3 sample were confirmed during three consecutive processes.
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Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuł w czasopiśmie wyróżnionym w JCR
- Opublikowano w:
-
APPLIED SURFACE SCIENCE
nr 435,
strony 1174 - 1186,
ISSN: 0169-4332 - Język:
- angielski
- Rok wydania:
- 2018
- Opis bibliograficzny:
- Marchelek M., Grabowska E., Klimczuk T., Lisowski W., Giamello E., Zaleska-Medynska A.: Studies on novel BiyXz-TiO2/SrTiO3 composites: Surface properties and visible light-driven photoactivity// APPLIED SURFACE SCIENCE. -Vol. 435, (2018), s.1174-1186
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.apsusc.2017.11.139
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 167 razy
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