Synthesis, structural characterization, and thermal properties of Ca‐ and La‐doped soda‐lime glasses by laser melting
Abstrakt
Laser melting techniques have been used in the preparation of unconventional glass compositions with high melting temperatures. Thus, we wanted to test the feasibility of using a CO2 laser in the preparation of nitrogen-rich oxynitride glasses and nitride silicate glasses. Melting from oxides and metallic raw materials, we wanted to study first glass formation and possible evaporation losses of the glass components. Two glass series were prepared and studied for their structure and thermal properties, one with Ca2+- and a higher melting La3+-doped soda-lime-silicate (SLS) series. In less than 3minutes of laser melting, spheres of up to 6mm diameter were successfully fabricated. The obtained glass samples were homogeneous and transparent in the visible region. X-ray diffraction and Raman spectroscopic analysis confirmed the amorphous nature of the synthesized samples. Sodium losses increase as calcium is added to the soda-lime-silicate glass. As expected, increasing Ca2+ or La3+ addition lead to increased depolymerization of the silicate network. Moreover, the increases in Tg with the addition of Ca2+ or La3+ ions indicating strengthening of the soda-lime-silicate glass by increasing strength of the M-O bonds of divalent and trivalent ions over monovalent sodium ions, weak Na-O bonds also resulting in significant evaporation loss during the short laser melting times. The thermal stability decreases upon addition of Ca2+ or La3+ ions to the soda-lime-silicate glasses.
Cytowania
-
7
CrossRef
-
0
Web of Science
-
7
Scopus
Autorzy (7)
Cytuj jako
Pełna treść
- Wersja publikacji
- Accepted albo Published Version
- Licencja
- Copyright (2020 The American Ceramic Society and Wiley Periodicals, Inc)
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuły w czasopismach
- Opublikowano w:
-
International Journal of Applied Glass Science
nr 11,
strony 699 - 706,
ISSN: 2041-1286 - Język:
- angielski
- Rok wydania:
- 2020
- Opis bibliograficzny:
- Ali S., Wójcik N., Jonson B., Kamitsos E., Li X., Luo J., Möncke D.: Synthesis, structural characterization, and thermal properties of Ca‐ and La‐doped soda‐lime glasses by laser melting// International Journal of Applied Glass Science -Vol. 11,iss. 4 (2020), s.699-706
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1111/ijag.15477
- Bibliografia: test
-
- Cormier L, Calas G, Beuneu B. Structural changes between soda-lime silicate glass and melt. J Non- Cryst Solids. 2011;357(3):926-31. otwiera się w nowej karcie
- Wondraczek L, Mauro JC, Eckert J, Kuhn U, Horbach J, Deubener J, et al. Towards Ultrastrong Glasses. Advanced Materials. 2011;23(39):4578-86. otwiera się w nowej karcie
- Iftekhar S, Grins J, Edén M. Composition-property relationships of the La2O3-Al2O3-SiO2 glass system. J Non-Cryst Solids. 2010;356(20):1043-8. otwiera się w nowej karcie
- Le J, Song LX, Peng XF, Hu XF. Fracture mechanics analysis of thermally tempered glass plate: fracture induced by an embedded crack. International Journal of Fracture. 2005;132(4):299-309. otwiera się w nowej karcie
- Sebdani MM, Mauro JC, Jensen LR, Smedskjaer MM. Structure-property relations in calcium aluminate glasses containing different divalent cations and SiO2. J Non-Cryst Solids. 2015;427:160-5. otwiera się w nowej karcie
- Sharafat A, Grins J, Esmaeilzadeh S. Glass-forming region in the Ca-Si-O-N system using CaH 2 as Ca source. J Eur Ceram Soc. 2008;28(14):2659-64. otwiera się w nowej karcie
- Sharafat A, Grins J, Esmaeilzadeh S. Hardness and refractive index of Ca-Si-O-N glasses. J Non-Cryst Solids. 2009;355(4-5):301-4. otwiera się w nowej karcie
- Ali S, Paul B, Magnusson R, Broitman E, Jonson B, Eklund P, et al. Synthesis and characterization of the mechanical and optical properties of Ca-Si-O-N thin films deposited by RF magnetron sputtering. Surface and Coatings Technology. 2017;315:88-94. otwiera się w nowej karcie
- Schaller T, Stebbins JF. The Structural Role of Lanthanum and Yttrium in Aluminosilicate Glasses: A 27Al and 17O MAS NMR Study. The Journal of Physical Chemistry B. 1998;102(52):10690-7. otwiera się w nowej karcie
- Schuster K, Litzkendorf D, Grimm S, Kobelke J, Schwuchow A, Ludwig A, et al. Study of lanthanum aluminum silicate glasses for passive and active optical fibers: SPIE; 2013. otwiera się w nowej karcie
- Mahdy EA, Ibrahim S. Influence of Y2O3 on the structure and properties of calcium magnesium aluminosilicate glasses. Journal of Molecular Structure. 2012;1027:81-6. otwiera się w nowej karcie
- Bardez I, Caurant D, Loiseau P, Baffier N, Dussossoy JL, Gervais C, et al. Structural characterisation of rare earth rich glasses for nuclear waste immobilisation. Physics and Chemistry of Glasses. 2005;46(4):320-9. otwiera się w nowej karcie
- Gaddam A, Fernandes HR, Tulyaganov DU, Ferreira JMF. The structural role of lanthanum oxide in silicate glasses. J Non-Cryst Solids. 2019;505:18-27. otwiera się w nowej karcie
- Ellison AJG, Hess PC. Lanthanides in silicate glasses: A vibrational spectroscopic study. Journal of Geophysical Research: Solid Earth. 1990;95(B10):15717-26. otwiera się w nowej karcie
- Park B, Li H, Corrales LR. Molecular dynamics simulation of La2O3-Na2O-SiO2 glasses. I. The structural role of La3+ cations. J Non-Cryst Solids. 2002;297(2):220-38. otwiera się w nowej karcie
- Schaller T, Stebbins JF, Wilding MC. Cation clustering and formation of free oxide ions in sodium and potassium lanthanum silicate glasses: nuclear magnetic resonance and Raman spectroscopic findings. J Non-Cryst Solids. 1999;243(2):146-57. otwiera się w nowej karcie
- Wilding M, Badyal Y, Navrotsky A. The local environment of trivalent lanthanide ions in sodium silicate glasses: A neutron diffraction study using isotopic substitution. J Non-Cryst Solids. 2007;353(52):4792-800. otwiera się w nowej karcie
- Angeli F, Charpentier T, Molières E, Soleilhavoup A, Jollivet P, Gin S. Influence of lanthanum on borosilicate glass structure: A multinuclear MAS and MQMAS NMR investigation. J Non-Cryst Solids. 2013;376:189-98. otwiera się w nowej karcie
- Kamitsos EI, Chryssikos GD. Borate glass structure by Raman and infrared spectroscopies. Journal of Molecular Structure. 1991;247:1-16. otwiera się w nowej karcie
- Wójcik NA, Ali S, Möncke D, Tagiara NS, Kamitsos EI, Segawa H, et al. The influence of Be addition on the structure and thermal properties of alkali-silicate glasses. J Non-Cryst Solids. 2019;521:119532. otwiera się w nowej karcie
- Kamitsos EI, Kapoutsis JA, Jain H, Hsieh CH. Vibrational study of the role of trivalent ions in sodium trisilicate glass. J Non-Cryst Solids. 1994;171(1):31-45. otwiera się w nowej karcie
- Kamitsos EI, Risen WM. Vibrational spectra of single and mixed alkali pentasilicate glasses. J Non- Cryst Solids. 1984;65(2):333-54. otwiera się w nowej karcie
- Furukawa T, Fox KE, White WB. Raman spectroscopic investigation of the structure of silicate glasses. otwiera się w nowej karcie
- III. Raman intensities and structural units in sodium silicate glasses. The Journal of Chemical Physics. 1981;75(7):3226-37. otwiera się w nowej karcie
- Brawer SA, White WB. Raman spectroscopic investigation of the structure of silicate glasses. I. The binary alkali silicates. The Journal of Chemical Physics. 1975;63(6):2421-32. otwiera się w nowej karcie
- Efthimiopoulos I, Palles D, Richter S, Hoppe U, Möncke D, Wondraczek L, et al. Femtosecond laser- induced transformations in ultra-low expansion glass: Microstructure and local density variations by vibrational spectroscopy. Journal of Applied Physics. 2018;123(23):233105. otwiera się w nowej karcie
- Wójcik NA, Jonson B, Möncke D, Kamitsos EI, Segawa H, Karczewski J, et al. The effect of nitrogen on the structure and thermal properties of beryllium-containing Na-(Li)-Si-O-N glasses. J Non-Cryst Solids. 2019;522:119585. otwiera się w nowej karcie
- Grund Bäck L, Ali S, Karlsson S, Möncke D, Kamitsos EI, Jonson B. Mixed alkali/alkaline earth-silicate glasses: Physical properties and structure by vibrational spectroscopy. International Journal of Applied Glass Science. 2019;10(3):349-62.
- Dussauze M, Rodriguez V, Lipovskii A, Petrov M, Smith C, Richardson K, et al. How Does Thermal Poling Affect the Structure of Soda-Lime Glass? The Journal of Physical Chemistry C. 2010;114(29):12754-9. otwiera się w nowej karcie
- M.D. Ingram JED, A.M. Coats, E.I. Kamitsos, J.A. Kapoutsis,. Origins of anomalous mixed-alkali effects in ion-exchanged glasses,. Glass Science and Technology-Glastechnische Berichte. 2000;73(4):89-104.
- Nelson BN, Exarhos GJ. Vibrational spectroscopy of cation-site interactions in phosphate glasses. The Journal of Chemical Physics. 1979;71(7):2739-47. otwiera się w nowej karcie
- Möncke D, Kamitsos EI, Palles D, Limbach R, Winterstein-Beckmann A, Honma T, et al. Transition and post-transition metal ions in borate glasses: Borate ligand speciation, cluster formation, and their effect on glass transition and mechanical properties. The Journal of Chemical Physics. 2016;145(12):124501. otwiera się w nowej karcie
- Iftekhar S, Leonova E, Edén M. Structural characterization of lanthanum aluminosilicate glasses by 29Si solid-state NMR. J Non-Cryst Solids. 2009;355(43):2165-74. otwiera się w nowej karcie
- Takahashi S, Neuville DR, Takebe H. Thermal properties, density and structure of percalcic and peraluminus CaO-Al 2 O 3 -SiO 2 glasses. J Non-Cryst Solids. 2015;411:5-12. otwiera się w nowej karcie
- Stevensson B, Eden M. Structural rationalization of the microhardness trends of rare-earth aluminosilicate glasses: Interplay between the RE3+ field-strength and the aluminum coordinations. J Non-Cryst Solids. 2013;378:163-7. otwiera się w nowej karcie
- Smedskjaer MM, Mauro JC, Kjeldsen J, Yue YZ. Microscopic Origins of Compositional Trends in Aluminosilicate Glass Properties. J Am Ceram Soc. 2013;96(5):1436-43. otwiera się w nowej karcie
- Ali S, Jonson B. Glasses in the Ba-Si-O-N System. J Am Ceram Soc. 2011;94(9):2912-7. otwiera się w nowej karcie
- Sharafat A, Forslund B, Grins J, Esmaeilzadeh S. Formation and properties of nitrogen-rich strontium silicon oxynitride glasses. J Mater Sci. 2009;44(2):664-70. otwiera się w nowej karcie
- Hakeem AS, Grins J, Esmaeilzadeh S. La-Si-O-N glasses -Part I. Extension of the glass forming region. J Eur Ceram Soc. 2007;27(16):4773-81. otwiera się w nowej karcie
- Tagiara NS, Palles D, Simandiras ED, Psycharis V, Kyritsis A, Kamitsos EI. Synthesis, thermal and structural properties of pure TeO 2 glass and zinc-tellurite glasses. J Non-Cryst Solids. 2017;457(Supplement C):116-25. otwiera się w nowej karcie
- Konidakis I, Varsamis CPE, Kamitsos EI. Effect of synthesis method on the structure and properties of AgPO3-based glasses. J Non-Cryst Solids. 2011;357(14):2684-9. otwiera się w nowej karcie
- Palles D, Konidakis I, Varsamis CPE, Kamitsos EI. Vibrational spectroscopic and bond valence study of structure and bonding in Al2O3-containing AgI-AgPO 3 glasses. RSC Advances. 2016;6(20):16697-710. otwiera się w nowej karcie
- Bingham PA, Hand RJ, Hannant OM, Forder SD, Kilcoyne SH. Effects of modifier additions on the thermal properties, chemical durability, oxidation state and structure of iron phosphate glasses. J Non-Cryst Solids. 2009;355(28):1526-38. otwiera się w nowej karcie
- Na7.7Ca10.9Si22.5O58.9 10.4Na2O-29.3CaO-60.3SiO2 5Ca Na7.8Ca20.9Si28.8O43.82 otwiera się w nowej karcie
- Series II samples 1La Na11.6Ca6.9La2.1Si35.0O46.1 otwiera się w nowej karcie
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 90 razy
Publikacje, które mogą cię zainteresować
The influence of Be addition on the structure and thermal properties of alkali-silicate glasses
- N. A. Wójcik,
- S. Ali,
- D. Möncke
- + 5 autorów
Influence of synthesis conditions on glass formation, structure and thermal properties in the Na 2 O-CaO-P 2 O 5 system doped with Si 3 N 4 and Mg
- N. A. Wójcik,
- B. Jonson,
- D. Möncke
- + 6 autorów
Microfluidic devices for photo-and spectroelectrochemical applications
- R. Bogdanowicz,
- M. Jönsson-Niedziolka,
- E. Vereshchagina
- + 8 autorów