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The reactions of dialkyl phosphites and phosphine oxides with iodosylbenzene

Abstrakt

The reaction of iodosylbenzene with >P(O)H type of acids (dialkyl phosphites, secondary phosphine oxides) was studied. The acids of >P(O)H type add to iodosylbenzene to yield intermediate 6 which in the aprotic solvents yields oxidation products, it means >P(O)OH acids and/or anhydride of >P(O)OP(O)< type. On the other hand if the reaction is performed in alcohol as a solvent in the presence of sodium alcoholate >P(O)OR ester is the major product.

Sławomir Makowiec, Janusz Rachoń. (2002). The reactions of dialkyl phosphites and phosphine oxides with iodosylbenzene. Phosphorus Sulfur And Silicon And The Related Elements, 177(4), 941-955. Retrieved from

Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie z listy filadelfijskiej
Opublikowano w:
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS nr 177, wydanie 4, strony 941 - 955,
ISSN: 1042-6507
Język:
angielski
Rok wydania:
2002
Opis bibliograficzny:
Makowiec S., Rachoń J.: The reactions of dialkyl phosphites and phosphine oxides with iodosylbenzene// PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. -Vol. 177., iss. 4 (2002), s.941-955

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