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Improved performance of LaNi0.6Fe0.4O3 solid oxide fuel cell cathode by application of a thin interface cathode functional layer
PublikacjaIn this work, novel functional layers were prepared by a low temperature spray pyrolysis method on the oxygen side of the solid oxide cells. Thin layers of Ce0.8Gd0.2O2 and LaNi0.6Fe0.4O3 are prepared between the electrolyte and the porous oxygen electrode. Additionally the influence of the sprayed ceria barrier layer on the zirconia based electrolyte with the new layers is evaluated. Impedance spectroscopy results show improvement...
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Low temperature processed MnCo2O4 and MnCo1.8Fe0.2O4 as effective protective coatings for solid oxide fuel cell interconnects at 750 °C
PublikacjaIn this study two materials, MnCo2O4 and MnCo1.8Fe0.2O4 are studied as potential protective coatings for Solid Oxide Fuel Cell interconnects working at 750 °C. First powder fabrication by a modified Pechini method is described followed by a description of the coating procedure. The protective action of the coating applied on Crofer 22 APU is evaluated by following the area specific resistance (ASR) of the scale/coating for 5500...
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An integral-differential method for impedance determination of the hydrogen oxidation process in the presence of carbon monoxide in the proton exchange membrane fuel cell
PublikacjaThe impedance of a proton exchange membrane fuel cell powered by hydrogen contaminated with carbon monoxide, ranging from 150 to 300 ppb, is measured and discussed. The tested range of CO concentration complied with the fuel standard specified in the ISO standards. Studies of influence of CO contamination on operation of PEMFC are crucial for further development and commercialization of fuel cells for automotive applications. Based...
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In situ study of a composition of outlet gases from biogas fuelled Solid Oxide Fuel Cell performed by the Fourier Transform Infrared Spectroscopy
PublikacjaThe purpose of this study was to develop a method and software based on the Fourier Transform Infrared Spectroscopy for the in-situ, quantitative analysis of the composition of outlet gases from Solid Oxide Fuel Cell (SOFC). The calibration procedure performed at the beginning of the experiment indicated a polynomial dependence between the concentration of a calibrating gas (CO, CO2, CH4) and the corresponding integrated absorbance in...
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Evolution of the nanostructure of Pt and Pt–Co polymer electrolyte membrane fuel cell electrocatalysts at successive degradation stages probed by X-ray photoemission
PublikacjaWe present a set of XPS (X-ray photoemission spectroscopy) measurements and detailed data-analysis of electrodes for polymer electrolyte membrane fuel cell (PEMFC) based on carbon supported catalysts (Pt and Pt–Co) subjected to a step-like potential cycling (accelerated degradation test). The results of the measurements complete and corroborate parallel TEM (transmission electron microscopy), XRD (X-ray diffraction) and XAS (X-ray...
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Effects of Ni-NCAL and Ni–Ag electrodes on the cell performances of low-temperature solid oxide fuel cells with Sm0.2Ce0·8O2-δ electrolyte at various temperatures
PublikacjaThree low-temperature solid oxide fuel cells are built using Sm0.2Ce0·8O2-δ (SDC) as the electrolyte. Cell A is symmetrical and features Ni–LiNi0.8Co0·15Al0·05O2 (Ni–NCAL) electrodes, Cell B comprises a Ni–NCAL anode and a Ni–Ag cathode, and Cell C is fabricated using a Ni–NCAL cathode and a Ni–Ag anode. The ohmic resistance and polarization resistance (Rp) of Cells B and C are significantly higher than those of Cell A. The reduction...
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Design and Thermodynamic Analysis of an SOFC System for Naval Surface Ship Application
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High performance LaNi1-xCoxO3-δ (x = 0.4 to 0.7) infiltrated oxygen electrodes for reversible solid oxide cells
PublikacjaOxygen electrodes prepared by infiltration of yttria stabilized zirconia backbone with Ce0.8Gd0.2O1.95 barrier layer and LaNi1-xCoxO3-δ (x=0.4 to 0.7) catalyst for application in reversible solid oxide cells have been studied. The effect of temperature and Ni:Co ratio on their phase composition, microstructure and electrochemical properties are discussed. It was shown that oxygen electrodes infiltrated with LaNi0.5Co0.5O3-δ had...
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Structural and electrical transport properties of Pr-doped SrTi0.93Co0.07O3-δ a novel SOEC fuel electrode materials
PublikacjaSolid Oxide Electrolyzer Cells (SOECs) are very promising electrochemical devices for the production of syngas (H2/CO) by H2O and CO2 co-electrolysis. The structure, microstructure and electrical properties of the fuel electrode material play a crucial role in the performance of the whole cell and efficiency of electrocatalytic reduction of steam into hydrogen. In the present work, a novel Co and Pr co-doped SrTiO3-δ material attracted...
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Processing of Ce0.8Gd0.2O2-δ barrier layers for solid oxide cells: The effect of preparation method and thickness on the interdiffusion and electrochemical performance
PublikacjaCe0.8Gd0.2O1.9 (CGO) barrier layers are required to mitigate the chemical reactions between Sr-containing oxygen electrode materials and Zr-based oxygen ion conductors in high-temperature solid oxide cells. Barrier layers produced by different methods were studied in this work. As a reference, a cell with no barrier layer was measured. The application of the powder-processed barrier layers, considerably increases the performance....
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Bioreactors and biophoton-driven biohydrogen production strategies
PublikacjaGiven the current issues with global warming and rising greenhouse gas emissions, biohydrogen is a viable alternative fuel option. Technologies to produce biohydrogen include photo fermentation, dark fermentation, direct and indirect bio-photolysis, and two-stage fermentation. Biological hydrogen generation is a green and promising technique with mild reaction conditions and low energy consumption compared to thermochemical and...
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Nowa metoda optymalizacji pracy ogniw paliwowych.
PublikacjaPrzedstawiono dynamiczną technikę impedancją jako doskonałe narzędzie służące do określenia optymalnych warunków pracy ogniw paliwowych. Możliwości tej techniki zostały przedstawione na przykładzie ustalenia optymalnej temperatury pracy. Otrzymane wyniki zostały skonfrontowane z charakterystykami prądowo napięciowymi ogniwa.
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Napęd z silnikiem indukcyjnym i 4-gałęziowym falownikiem SiC do turbosprężarek powietrza ogniw paliwowych dużej mocy
PublikacjaWysoka cena ogniw paliwowych utrudnia ich szerokie zastosowanie w transporcie i przemyśle. Należy szukać możliwości obniżenia ich kosztu również poprzez obniżenie kosztu i zwiększenie wydajności urządzeń pomocniczych ogniwa paliwowego (Balance of the Plant). Autorzy proponują aby w napędzie sprężarki powietrza, zastosować wysokoobrotowy silnik indukcyjny, który jest tańszy od stosowanych obecnie silników PMSM. W referacie zaproponowano...
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Wodór jako paliwo cz. 1
PublikacjaW artykule przedstawiono wodór jako nowoczesny nośnik energii oraz jego zastosowanie techniczne w ujęciu konwersji energii. Przybliżono jego odkrycie, właściwości oraz jego wykorzystanie od odkrycia do współczesności. Dokonano opisu budowy i zasady działania ogniw paliwowych. Omówiono ich podział przedstawiając zalety i wady każdego rozwiązania oraz ich zastosowanie techniczne w zależności od typu ogniwa.
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Ceria Based Protective Coatings for Steel Interconnects Prepared by Spray Pyrolysis
PublikacjaStainless steels can be used in solid oxide fuel/electrolysis stacks as interconnects. For successful long term operation they require protective coatings, that lower the corrosion rate and block chemical reactions between the interconnect and adjacent layers of the oxygen or the hydrogen electrode. One of the promising coating materials for the hydrogen side is ceria. Using standard sintering techniques, ceria sinters at around...
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Corrosion Study of Ceria Protective Layer Deposited by Spray Pyrolysis on Steel Interconnects
PublikacjaSingle fuel cells and electrolysis cells are assembled into stacks using interconnects in order to increase power and gas production capacity. The most common choice for the interconnect material is stainless steel. It has good electrical and mechanical properties and is also cost effective. One of the problems when using steel is the formation of a thermally grown oxide scale during use which has a lower electrical conductivity...
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Hydrogen production from ethanol In nitrogen microwave plasma At atmospheric pressure
PublikacjaHydrogen seems to be one of the most promising alternative energy sources. It is a renewable fuel as it could be produced from e.g. waste or bio-ethanol. Furthermore hydrogen is compatible with fuel cells and is environmentally clean. In contrast to conventional methods of hydrogen production such as water electrolysis or coal gasification we propose a method based on atmospheric pressure microwave plasma. In this paper we present...
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Water uptake kinetics and electrical transport in BaCe0.6Zr0.2Y0.1M0.1O3−δ (M = Tb, Pr, Fe) protonic conductors
PublikacjaBaCe0.6Zr0.2Y0.1M0.1O3−d (M = Fe, Pr, Tb) is a mixed conducting oxide in which three mobile charge carriers – oxygen ion, electron/hole, and protonic defects – are present. These types of materials have gained much interest as electrode materials for protonic ceramic fuel cells (PCFCs) and protonic ceramic electrolysis cells (PCECs). In this study, the water uptake and oxygen transport properties of different BaCe0.6Zr0.2Y0.1M0.1O3−d...
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Badania stabilności chemicznej kompozytowego elektrolitu 3-YSZ-Al2O3 w stosunku do materiałów elektrodowych do zastosowania w średniotemperaturowych ogniwach paliwowych
PublikacjaJednym z podstawowych wymogów stawianych mate- riałom na elektrolity do średniotemperaturowych ogniw paliwowych IT-SOFC (ang. intermediate-temperature solid oxide fuel cells) jest ich kompatybilność chemiczna z elektrodami w temperaturach zarówno eksploatacji, jak i wytwarzania ogniw. W celu sprawdzenia, czy badany w pracy kompozytowy elektrolit o osnowie z częściowo stabilizowanego ditlenku cyrkonu i z wtrąceniami tlenku glinu...
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Reaktory elektrochemiczne w przemyśle - konstrukcja i zastosowania
PublikacjaZ biegiem lat reakcje elektrochemiczne przestały być postrzegane jedynie jako eksperymenty laboratoryjne lub proste baterie. Chociaż mechanizm reakcji i budowa prostych reaktorów znana jest ludzkości już od ponad 100 lat w ostatnich latach można zauważyć największy wzrost zainteresowania tą dziedziną. Nowy stale opracowywane są lepsze projekty budowy reaktorów. Modyfikacje to nie tylko rodzaje i formy materiałów, z których wykonane...
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublikacjaWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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Fault Diagnostics in PEMFC Stacks by Evaluation of Local Performance and Cell Impedance Analysis
PublikacjaStarvation, flooding, and dry‐out phenomena occur in polymer electrolyte membrane fuel cells (PEMFCs), due to heterogeneous local conditions, material inhomogeneity, and uneven flow distribution across the single cell active area and in between the individual cells. The impact of the load level and air feed conditions on the performance was identified for individual single cells within a 10‐cell stack. Analysis of the current density...
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High-temperature Co-electrolysis of CO2/H2O and direct methanation over Co-impregnated SOEC. Bimetallic synergy between Co and Ni
PublikacjaTo study the synergy between the transition metals for enhancing the electrochemical and chemical activity, a series of SOECs were modified with a small amount of Co ions, namely 1.8, 3.6, and 5.4 wt% in the reduced state. The addition of βCD into the precursor solution allowed for extremely fine dispersion of Co species across the Ni-YSZ cermet structure. The sample containing 3.6 wt% Co reached an outstanding over 2.5-times-higher...
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The role of electrolysis and enzymatic hydrolysis treatment in the enhancement of the electrochemical properties of 3D-printed carbon black/poly(lactic acid) structures
PublikacjaAdditive manufacturing, also known as 3D printing, is beginning to play an unprecedented role in developing many applications for industrial or personalized products. The conductive composite structures require additional treatment to achieve an electroactive surface useful for electrochemical devices. In this paper, the surfaces of carbon black/poly(lactic acid) CB-PLA printouts were activated by electrolysis or enzymatic digestion...
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Ceramic composites for single-layer fuel cells
PublikacjaComposite materials consisting of acceptor doped lanthanum orthoniobate electrolyte phase (La0.98Ca0.02NbO4) and Li2O:NiO:ZnO semiconducting phase were synthesized. The precursor powder of La0.98Ca0.02NbO4 was prepared in nanocrystalline (mechanosynthesis) and microcrystalline (solid-state synthesis) form. The composite can be applied in a single-layer fuel cell, because of the presence of two phases acting as an anode and a cathode...
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Solid Oxide Fuel Cells with Ni infiltrated perovskite anode
PublikacjaNiobium-doped strontium titanate was used as the anode for a solid oxide fuel cell. Electrolyte-supported cells were prepared with pure perovskite and composite perovskite–yttria–stabilized-zirconia (YSZ) anodes. Fuel cell tests demonstrated significant improvement in power density after infiltration with a small amount of Ni. The obtained values of power densities are comparable with conventional Ni/YSZ cermet anode. In addition,...
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Performance and Stability in H2S of SrFe0.75Mo0.25O3-δ as Electrode in Proton Ceramic Fuel Cells
PublikacjaThe H2S-tolerance of SrFe0.75Mo0.25O3-δ (SFM) electrodes has been investigated in symmetric proton ceramic fuel cells (PCFC) with BaZr0.8Ce0.1Y0.1O3-δ (BZCY81) electrolyte. The ionic conductivity of the electrolyte under wet reducing conditions was found to be insignificantly affected in the presence of up to 5000 ppm H2S. The fuel cell exhibited an OCV of about 0.9 V at 700 °C, which dropped to about 0.6 V and 0.4 V upon exposure...
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Investigation of catalytic layers on anode for solid oxide fuel cells operating with synthetic biogas
PublikacjaIn this paper solid oxide fuel cells operating with dry synthetic biogas have been examined. In order to increase their stability the layers of CuO-CeO2, Cu1.3Mn1.7O4 and Y0.08Sr0.92Ti0.8Fe0.2O3 -δ have been deposited on the Ni-YSZ anode site. These layers should catalyze the internal biogas reforming and prevent the carbon deposition on the anode site. It has been found that CuO-CeO2 and Cu1.3Mn1.7O4 catalysts led to an increase...
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Protonic Ceramic Fuel Cells as novel electrochemical devices
PublikacjaProton ceramic conductors are novel materials which are interesting from the application point of view. For example, Protonic Ceramic Fuel Cells (PCFCs) is a type of a solid oxide fuel cell, which uses proton ceramic conductors as an electrolyte. Scientists are looking for the most efficient materials for these devices. In recent years main focus has been put on the search for new proton and mixed proton-electron conductors which...
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The Application of Electrolysis Method to Disinfect Water Contaminated by Salmonella and Shigella
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Understanding Fuel Saving and Clean Fuel Strategies Towards Green Maritime
PublikacjaDue to recent emission-associated regulations imposed on marine fuel, ship owners have been forced to seek alternate fuels, in order to meet the new limits. The aim of achieving low-carbon shipping by the year 2050, has meant that alternative marine fuels, as well as various technological and operational initiatives, need to be taken into account. This article evaluates and examines recent clean fuels and novel clean technologies...
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CeCu2O4 as a functional layer on solid oxide fuel cells for synthetic biogas reforming
PublikacjaSolid Oxide Fuel Cells (SOFC) are one of the most promising electrochemical devices, which can convert chemical energy to the electrical energy these days. Their ability to work with different kind of fuel makes them noteworthy. SOFC can work with biogas. The problem arises when solid carbon starts to be deposited in anode. That leads to degradation of fuel cell. Simple solution is to apply catalytic functional layer, which is...
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Desirability-based optimization of dual-fuel diesel engine using acetylene as an alternative fuel
Publikacjahe study examined the dual-fuel engine performance employing acetylene gas as primary fuel and diesel as pilot fuel. The engine's operational parameters were adjusted using the Box-Behnken design, and the results were recorded. The best operating settings were yielded as 81.25 % engine load, 4.48 lpm acetylene gas flow rate and the compression ratio were 18. At this optimized setting the BTE was 27.1 % and the engine emitted 360...
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The influence of dynamic load changes on temporary impedance in hydrogen fuel cells, selection and validation of the electrical equivalent circuit
PublikacjaTo achieve optimal performance of a fuel cell, a reliable monitoring and diagnostic method is required. The currently utilized methods give limited information or they are impossible to use under dynamic working conditions. To obtain comprehensive information about the fuel cell operation we utilized novel dynamic electrochemical impedance spectroscopy. Impedance measurements in dynamic mode were performed on a hydrogen fuel cell,...
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EXPERIMENTAL RESEARCH ON INFLUENCE OF THE FUEL NOZZLE GEOMETRY ON THE FUEL CONSUMPTION OF THE MARINE 4-STROKE DIESEL ENGINE
PublikacjaThe article presents experimental research that has been carried out on a marine, 4-stroke, 3-cylinder, turbocharged engine. During testing, the engine operated at a constant rotational speed of 750 rpm and a load from 0 kW to 280 kW. The engine was fuelled by diesel oil of known specification and loaded by electric generator with water resistance. The fuel consumption was measured during the engine operation with fuel nozzles...
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Experimental investigation of the PEM fuel cells performance for automotive and stationary applications
PublikacjaThe aim of the study was to provide dynamic characteristics of the PEM fuel cell system consisted of Nexa modules, provide steady-state characteristics of the for different values of air excess ratio and steady-state characteristics for different stack temperatures and given load.
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A XAS study of a highly diluted Pt electrocatalyst operating in PEM fuel cells
PublikacjaWe present an X-ray absorption spectroscopy (XAS) study of a low Pt content catalyst layer(Pt loading 0.1 mg c2) operating at the cathode of a proton exchange membrane fuel cell(PEMFC). This catalyst is based on the use of a mesoporous inorganic matrix as a support forthe catalyst Pt nanoparticles. Due to the high Pt dilution, in situ measurements of itsstructural properties by XAS are challenging and suitable experimental strategies...
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Optimization of the Relative Humidity of Reactant Gases in Hydrogen Fuel Cells Using Dynamic Impedance Measurements
PublikacjaWater management is a key factor affecting the efficiency of proton exchange membrane fuel cells (PEMFCs). The currently used monitoring methods of PEMFCs provide limited information about which processes or components that humidity has a significant impact upon. Herein, we propose the use of a novel approach of impedance measurements using a multi-sinusoidal perturbation signal, which enables impedance measurements under dynamic...
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A mechanistically approached review upon assorted cell lines stimulated by athermal electromagnetic irradiation
PublikacjaThe probable influence of electromagnetic irradiation on cancer treatment has been deduced from the interaction of artificial electromagnetic emissions with biological organisms. Nonetheless, the suspected health effects induced by electromagnetic-based technology imply that such a treatment may contaminate the adjacent healthy cells. Thus, gaining mechanistic insights into the problem is required to avoid athermal health hazards....
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Fuel systems of high power stationary engine
PublikacjaThe use of alternative fuels and, in the future, synthetic fuels has forced changes in the design of fuel supply systems in internal combustion engines. When operating a stationary engine at constant load, the possibility of using lean fuel mixtures appears. The selection of a precise operating mixture ignition system requires changes in traditional fuel systems. The article presents the current designs of fuel supply systems and...
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Spray pyrolysis of doped-ceria barrier layers for solid oxide fuel cells
PublikacjaGadolinium doped ceria (Ce0.8Gd0.2O2 − x-CGO) layer fabricated by spray pyrolysis is investigated as the diffusion barrier for solid oxide fuel cell. It is deposited between the La0.6Sr0.4FeO3 − δ cathode and the yttria stabilized zirconia electrolyte to mitigate harmful interdiffusion of elements. The parameters of the fabrication process are linked to the measured area specific resistances of the symmetrical cells and the efficiency...
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Municipal wastewater reclamation: Reclaimed water for hydrogen production by electrolysis – A case study
PublikacjaThis paper presents an analysis of a treatment system selection for municipal wastewater stream based on the DuPont Water Solutions WAVE software. The results obtained based on an analysis of 7 different processing cases studies (ultrafiltration and reverse osmosis) confirmed that the application of 2-pass membrane systems enables the reclamation of water from municipal wastewater that fulfills the requirements concerning the...
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Expression of cyclin D1 after treatment with doxorubicin in the HL-60 cell line
PublikacjaIncreased levels of cyclin D1 and amplification of CCND1 gene occur in many types of cancers. We have followed the expression of cyclin D1 after treatment with doxorubicin with reference to cell death and other possible therapeutic implications. The effect of the treatment on the cell cycle, survival, intracellular level (flow cytometry), and intracellular localization of cyclin D1 (fluorescence microscopy) and expression of...
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Heterotrophic Anodic Denitrification in Microbial Fuel Cells
PublikacjaNowadays, pollution caused by energy production systems is a major environmental concern. Therefore, the development of sustainable energy sources is required. Amongst others, the microbial fuel cell (MFC) seems to be a possible solution because it can produce clean energy at the same time that waste is stabilized. Unfortunately, mainly due to industrial discharges, the wastes could contain nitrates, or nitrates precursors such...
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Dimethyl ether (DME) as potential environmental friendly fuel
PublikacjaIn recent years, there has been a growing interest in replacing petroleum fuels with so-called second generation environmental friendly fuels. Compared to traditional petroleum fuels dimethyl ether (DME) could be used as a clean high-efficiency compression ignition fuel with reduced particulate matter (PM), sulfur oxides (SOx), hydrocarbons (HC), carbon monoxide (CO) as well as combustion noise. Compared to some of the other leading...
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Pressure and temperature effect on hypergolic ignition delay of triglyme-based fuel with hydrogen peroxide
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Status report on high temperature fuel cells in Poland – Recent advances and achievements
PublikacjaThe paper presents recent advances in Poland in the field of high temperature fuel cells. The achievements in the materials development, manufacturing of advanced cells, new fabrication techniques, modified electrodes and electrolytes and applications are presented. The work of the Polish teams active in the field of solid oxide fuel cells (SOFC) and molten carbonate fuel cell (MCFC) is presented and discussed. The review is oriented...
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USING ARTIFICIAL NEURAL NETWORKS FOR PREDICTING SHIP FUEL CONSUMPTION
PublikacjaIn marine vessel operations, fuel costs are major operating costs which affect the overall profitability of the maritime transport industry. The effective enhancement of using ship fuel will increase ship operation efficiency. Since ship fuel consumption depends on different factors, such as weather, cruising condition, cargo load, and engine condition, it is difficult to assess the fuel consumption pattern for various types...
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APPLICATION OF THE THEORY OF SEMI-MARKOV PROCESSES TO DETERMINE A LIMITING DISTRIBUTION OF THE PROCESS OF CHANGES OF ABILITY AND INABILITY STATES OF FUEL SUPPLY SYSTEMS IN HEAVY FUEL DIESEL ENGINES
PublikacjaThe paper presents applicability of the theory of semi-Markov processes to determine a limiting distribution of the process of changes of technical states of fuel systems for marine engines running on heavy fuel oils. The proposed study of this process includes the components of such fuel systems like: 1 - injectors, 2 - high pressure hoses, 3 - injection pumps, 4 - low pressure hoses, 5 – fine filters, 6 - coarse filters, 7 – fuel-feed...
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Assessment of Fuel Cells’ State of Health by Low-Frequency Noise Measurements
PublikacjaWe proposed applying low-frequency (flicker) noise in proton-exchange membrane fuel cells under selected loads to assess their state of health. The measurement set-up comprised a precise data acquisition board and was able to record the DC voltage and its random component at the output. The set-up estimated the voltage noise power spectral density at frequencies up to a few hundred mHz. We observed the evolution of the electrical...