Wyniki wyszukiwania dla: BIMETALLIC MOF-74
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Progressing Pollutant Elution from Snowpack and Evolution of its Physicochemical Properties During Melting Period— a Case Study From the Sudetes, Poland
PublikacjaMain aim of the work assumed recognition of physicochemical changes in snowpack occurring during the melting period. Properties of snow cover had been identified at two sites in Western Sudetes mountains (860 and 1228 m asl) in SW Poland since the end of January, and monitored until the disappearance of snow in late Spring. Snow pit measurements and sample collection at both sites were made followed by chemical analyses with the...
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AlP compound and P-doping for promotion of electrocatalytic activity of N-doped carbon derived from metal-organic framework
PublikacjaWater splitting plays a key role in future fuels, where two processes occur - the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Nitrogen-doped carbon derived from...
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Nanoparticles preparation using microemulsion systems
PublikacjaMetallic nanoparticles become of current interests because they exhibit unique properties compared with those of metal atoms or bulk metal due to the quantum size effect and their large surface area, which make them attractive for applications in optics, electronics, catalysis biology and medicine. TiO2 has been used for environmental remediation purposes such as in the purification of water and air and also solar-to chemical energy...
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New heterometallic Co/Zn, Ag/Co, and Ag/Zn imidazolates: structural characterization and catalytic activity in the oxidation of organic compounds
PublikacjaNanocrystalline powders of monometallic and bimetallic imidazolates of Co, Zn, and Ag were produced by a reaction carried out in water. The powders were characterized by powder X-ray diffraction and the crystal structures of new compounds Ag2ZnIm4 and Ag2CoIm4 (Im = imidazolate) were solved. Heterometallic Co/Zn imidazolates showed the standard ZIF-8 crystal structure while Ag/Zn and Ag/Co systems were isostructural with the copper...
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Zr‐Based Metal‐Organic Framework UiO‐66/Ultem® 1000 Membranes for Effective CO2/H2 Separation
PublikacjaMixed-matrix membranes (MMMs) using UiO-66 nanofillers as dispersing inorganic phase and polyetherimide (PEI) as continuous polymeric matrix were synthesized. Different UiO-66 loadings of 10, 20, and 30 wt % were applied. The morphology and UiO-66 dispersion over the prepared MMMs were examined. Gas separation measurements were performed for H2/CO2 gas mixture to evaluate the influence of UiO-66 on the separation yield of resulting...
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Prel2022 Poprawa właściwości elektrochemicznych katalizatorów jednoatomowych otrzymywanych ze struktur typu MOF
ProjektyProjekt realizowany w Zachodniopomorski Uniwersytet Technologiczny w Szczecinie zgodnie z porozumieniem 2020/37/N/ST5/03170 z dnia 2021-02-01
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Influence of terpenes on indoor air quality
PublikacjaThe aim of this study was to investigate air quality in hairdresser salons, focusing on terpenes determination. Terpenes are known reactive volatile organic compounds that contribute to secondary organic aerosol formation. Those compounds are frequently found in cosmetic products as fragrance agents. Hairdresser salons are special kind of environment, where secondary organic aerosol concentration may be elevated. One hairdresser...
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Binuclear Co(II), Zn(II) and Cd(II) tri-tert-butoxysilanethiolates. Synthesis, crystal structure and spectroscopic studies.
PublikacjaA series of Co(II), Zn(II) and Cd(II) complexes have been synthesized in reaction of respective metal tri-tert-butoxysilanethiolates with pyrazine 1 and 2 and 1,2-bis(2-pyridyl)ethylene 3–5. All compounds have been characterized by single-crystal X-ray structure determination, elemental analysis, FT-IR and thermogravimetry. Obtained complexes are bimetallic with the formula of [M{SSi(OtBu)3}2(μ-L)]2 and metal ions bridged by N,N′-spacer....
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Application of vertical flow constructed wetlands for highly contaminated wastewater treatment: preliminary results
PublikacjaBasing on quantitative and qualitative characteristics of reject waters (RWC) generated during dewatering of digested sewage sludge on centrifuges in conventional WWTP and municipal landfill leachate (LL), the pilot constructed wetlands for treatment of both types wastewater were designed and built. In the paper the conception, design and assumed treatment efficiencies of the pilot plants are presented. The water balance of the...
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Kompleksowa analiza symulacyjna układu napędowego zespołu trakcyjnego
PublikacjaNowoczesne pojazdy sieciowe, a w szczególności elektryczne zespoły trakcyjne (EZT), charakteryzują się wzrostem pobieranej mocy z sieci trakcyjnej oraz wysoką złożonością energoelektronicznego napędu. Duża liczba urządzeń falownikowego układu napędowego, zaawansowane metody sterowania napędem i całym pojazdem oraz wysokie wymagania jakości regulacji i niezawodności pracy wymuszają szczegółową analizę pracy EZT. Dodatkowo parametry...
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Method for Clustering of Brain Activity Data Derived from EEG Signals
PublikacjaA method for assessing separability of EEG signals associated with three classes of brain activity is proposed. The EEG signals are acquired from 23 subjects, gathered from a headset consisting of 14 electrodes. Data are processed by applying Discrete Wavelet Transform (DWT) for the signal analysis and an autoencoder neural network for the brain activity separation. Processing involves 74 wavelets from 3 DWT families: Coiflets,...
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Ag/Pt-modified TiO2 nanoparticles for toluene photooxidation in the gas phase
PublikacjaAg/Pt-modified TiO2nanocomposites were synthesized using the sol–gel method. The effect of metal typeand amount as well as synthesis route on the photocatalytic activity in reaction of toluene removal, usedas a model volatile organic compound, was investigated. Toluene, at the concentration of about 200 ppm,was irradiated over modified TiO2using light-emitting diodes (LEDs, max= 415 nm). The results showedthat toluene could be...
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abiotic degradation of chlorinated ethanes and ethenes in water
PublikacjaIntroduction Chlorinated ethanes and ethenes are among themost frequently detected organic pollutants of water. Theirphysicochemical properties are such that they can contaminateaquifers for decades. In favourable conditions, they canundergo degradation. In anaerobic conditions, chlorinatedsolvents can undergo reductive dechlorination.Degradation pathways Abiotic dechlorination is usuallyslower than microbial but abiotic dechlorination...
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Exposure of a small Arctic seabird, the little auk (Alle alle) breeding in Svalbard, to selected elements throughout the course of a year
PublikacjaThe Arctic marine ecosystem can be altered by processes of natural and anthropogenic origin. Spatio-temporal variation in species exposure to contamination is still poorly understood. Here, we studied elemental concentrations in the non-lethally collected samples from the most numerous seabird in European Arctic, the little auk (Alle alle) nesting in one breeding colony in Svalbard. This seabird spent the breeding season in the...
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Energy neutrality versus carbon footprint minimization in municipal wastewater treatment plants
PublikacjaThis work aimed to compare the carbon footprint (CF) of six full-scale wastewater treatment plants (WWTPs). The CF was estimated in the range of 23–100 kg CO2e per population equivalent. In the total CF, the direct emissions held the highest share (62–74%) for the plants with energy recovery from biogas. In the plants depending entirely on the power grid, the indirect emissions due to energy consumption dominated the total CF (69–72%)....
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Methodology of the Morphometry Study on Baltic Herring
PublikacjaAcoustic techniques are used in the estimation of the abundance of Baltic herring. Investigations of the relationship between the Baltic herring individual target strength TS and the total fish length L, significant in the acoustic assessment, demonstrated its de-pendence on the study area location. It motivated the detailed analysis of the relationship between herring from the southern Baltic ICES Subdivisions 24, 25, and 26,...
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IV Pomorska Uczniowska Konferencja Naukowa "Zdolni z Pomorza" 21.11.2020
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Pendant Proton-Relays Systematically Tune the Rate and Selectivity of Electrocatalytic Ammonia Generation in a Fe-Porphyrin Based Metal-Organic Framework
PublikacjaElectrocatalytic nitrite reduction (eNO2RR) is a promising alternative route to produce ammonia (NH3). Until now, several molecular catalysts have shown capability to homogeneously reduce nitrite to NH3, while taking advantage of added secondary-sphere functionalities to direct catalytic performance. Yet, realizing such control over heterogeneous electrocatalytic surfaces remains a challenge. Herein, we demonstrate that heterogenization...
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Chracteristics of anaerobic ammonium oxidation initated by anaerobic granular sludge
PublikacjaTwo different mixed sludge, anaerobic granular sludge(R1) and anaerobic granular sludge with mature anaerobic ammonium oxidation (ANAMMOX) sludge (R2 )were used as the inocula in two up-flow reactors to enrich anaerobic ammonia-oxidizing bacteria (AnAOB),respectively.The total nitrogen removal rate of R1 reached 74% in 99 days, while R2 remained above 70% in only 48 days.The content of extracellular polymeric substance (EPS) in...
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Chitin nanowhiskers from shrimp shell waste as green filler in acrylonitrile-butadiene rubber: Processing and performance properties
PublikacjaIn this work, chitin nanowhiskers with high crystallinity index were obtained from shrimp shells waste using acid hydrolysis method and then comprehensively characterized. Subsequently, the impact of chitin nanowhisker content on processing and performance of acrylonitrile-butadiene rubber based nanocomposites was evaluated. The results showed that the addition of chitin nanowhiskers increased tensile strength and tear strength...
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Interventions reducing car usage: Systematic review and meta-analysis
PublikacjaThis systematic literature review aimed to investigate the extent to which transport-related interventions induced a reduction in car use. Both qualitative synthesis and meta-analysis were employed. The synthesis included 31 original studies, while the meta-analysis included 21. Of the qualitatively synthesised studies, 74 % demonstrated that interventions were effective in reducing car use. The pooled estimates of the effects...
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Novel Polyurethanes as Antifouling Paint Matrices
PublikacjaThe new poly(ester-ether urethane)s (PEEUR) were prepared in two stage synthesis from formerly obtained oligo(alkylene ester-ether)diols (OAEE) and 4,4‘-diphenylmethane diisocyanate (MDI). PEEUR samples were subjected to crosslinking with styrene in the presence of radical polymerization initiators: methyl ethyl ketone peroxide (MEKPO) or cobalt 2-ethyl cyclohexanoate (EtHCo). Crosslinked PEEUR were characterized by their physicochemical...
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Application of ferric chloride for arsenic removal in the integrated process: coagulation/microfiltration
PublikacjaThe study presents results of using iron coagulation integrated with microfiltration to remove arsenic from water. Tested samples of natural groundwater contained approximately 32 μg/L of arsenic, 0.13 mg/L of iron and 0.085 mg/L of manganese. As a coagulant the aqueous solution of ferric chloride was dosed in portions from 1.0 to 10.5 mg/L. In the research microfiltration membranes with 400 kDa MWCO were used. Tests indicated...
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M-BDC (M = Co and/ or Fe) MOFs as effective catalysts for hydrogen generation via hydrolysis of sodium borohydride
PublikacjaMono- (Co-BDC, Fe-BDC) and bimetallic FeCo-BDC Metal-Organic Frameworks are successfully synthesized by the solvothermal method in DMF at 150 °C within 15 h and tested as catalysts for sodium borohydride hydrolysis. The materials are characterized by FTIR, PXRD, TGA, ICP-OES, H2-TPR, BET model, and SEM-EDS. The catalytic activity of these materials is studied for dehydrogenation of sodium borohydride in water at various temperatures...
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π-Stacking attraction vs. electrostatic repulsion: competing supramolecular interactions in a tpphz-bridged Ru(ii)/Au(iii) complex
PublikacjaThe synthesis and characterization of a mixed metal ruthenium(II)/gold(III) complex bridged by tetrapyridophenazine (tpphz) are described. It is isostructural and isoelectronic to the well-known photocatalysts with palladium(II) or platinum(II). Concentration dependent 1H-NMR spectroscopy and XRD studies show that the electrostatic repulsion between the gold(III) moieties exceeds the attractive π-stacking interaction. Theoretical...
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Visible-light-driven lanthanide-organic-frameworks modified TiO2 photocatalysts utilizing up-conversion effect
PublikacjaHighly efficient and quite stable composite with core-shell-like architecture reported herein, responds to the challenge of sunlight-driven photocatalysts. The Ln(ndc)/TiO2 photocatalytic system comprises active lanthanide-carboxylate coordination networks (Nd, Er, Ho, and Tm as metal ions, and 2,6-naphthalene dicar-boxylic acid as the organic linker) and inert titanium dioxide and allow to convert incompatible visible radiation...
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
PublikacjaCu and Ag enhance the photocatalytic activities of metal–organic frameworks (MOFs) toward CO2 conversion because of their CO2 adsorption capacities and effects on the lowest unoccupied molecular orbital (LUMO) overpotentials of MOFs. However, to date, targeted introduction of metals into MOFs to achieve visible (Vis)- light-active photocatalysts for CO2 photoconversion has not been realized. Herein, a series of aminefunctionalized...
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Determination of Odour Interactions in Gaseous Mixtures Using Electronic Nose Methods with Artificial Neural Networks
PublikacjaThis paper presents application of an electronic nose prototype comprised of eight sensors, five TGS-type sensors, two electrochemical sensors and one PID-type sensor, to identify odour interaction phenomenon in two-, three-, four- and five-component odorous mixtures. Typical chemical compounds, such as toluene, acetone, triethylamine, α-pinene and n-butanol, present near municipal landfills and sewage treatment plants were subjected...
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Design of a compact planar transmission line for miniaturized rat-race coupler with harmonics suppression
PublikacjaThis paper presents an elegant yet straightforward design procedure for a compact rat-race coupler (RRC) with an extended harmonic suppression. The coupler’s conventional λ/4 transmission lines (TLs) are replaced by a specialized TL that offers significant size reduction and harmonic elimination capabilities in the proposed approach. The design procedure is verified through the theoretical, circuit, and electromagnetic (EM) analyses,...
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Materiały sorpcyjne wykorzystywane w maskach ochronnych
PublikacjaOd zarania dziejów ludzie starają się chronić przed chorobami zakaźnymi, stosując środki ochrony osobistej, do których należą maski ochronne. Z uwagi na obecnie panującą pandemię wirusa SARS-CoV-2, noszenie masek stało się normą w walce z koronawirusem. Jednak zagrożenia dla górnych dróg oddechowych nie stanowią wyłącznie wirusy, lecz również cząstki stałe zawieszone w powietrzu. Szczególnie w krajach wysoko uprzemysłowionych,...
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Photocatalytic decolourization of Rhodamine-B dye by visible light active ZIF-8/BiFeO3 composite
PublikacjaIn this work, preparation of ZIF-8 supported BiFeO3 photocatalyst by ultrasound cavitation technique was reported. The synthesized materials were characterized using solid UV absorption spectroscopy, Raman Spectroscopy, and SEM. The catalytic function of synthesized photocatalyst under ultraviolet and visible light was examined for the decolourization of Rhodamine-B (Rh-B) dye. To understand the action of the photocatalyst on Rh-B...
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Kompleksowa analiza symulacyjna układu napędowego zespołu trakcyjnego
PublikacjaThe paper describes an approach to comprehensive analysis of traction electric drive. The drivetrain of ED-74 electric unit equipped with four inverter-fed induction motors was modeled in Matlab/Simulink. The model consists of functional blocks as: motors, inverters, drive controllers, filters. Structure and operation of the model was described. Chosen simulation results were presented and discussed. Two methods of modeling the...
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Chemical Composition of Atmospheric Air in Nemoral Scots Pine Forests and Submountainous Beech Forests: The Potential Region for the Introduction of Forest Therapy
PublikacjaStudies show that forests are one of the main recreational destinations. This can be explained by their beneficial effects on the health of their visitors, which can be attributed to compounds from the terpene group. The aim of this research was to determine the chemical composition of air in the interiors of Nemoral Scots pine forests and submountainous beech forests, with the determination of compounds of the terpene group. Samples...
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An investigation of selected monoaromatic hydrocarbons released from the surface of polystyrene lids used in coffee-to-go cups
PublikacjaA consumer trend towards the fast preparation of beverages has increased the popularity of hot beverages (especially coffee and tea) available in disposable containers called coffee-to-go cups with fitted polystyrene lids. Lids in contact with hot beverages may release low molecular weight organic compounds into the gaseous phase causing direct exposure of consumers to these compounds during drinking. The paper describes in detail...
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Ultrasound-assisted wet-impregnation of Ag–Co nanoparticles on cellulose nanofibers: Enhanced catalytic hydrogenation of 4-nitrophenol
PublikacjaIn this study, a novel nanocomposite of bimetallic Ag–Co nanoparticles supported on cellulose nanofibers (CNFs) was synthesised using the ultrasound-assisted wet-impregnation method for catalytic applications. CNFs were prepared from cellulose acetate using the electrospinning technique. Fourier transform infrared spectroscopy (FTIR) analysis confirmed the successful synthesis of CNFs. Further, scanning electron microscopy (SEM)...
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A novel (Ti/Ce)UiO-X MOFs@TiO2 heterojunction for enhanced photocatalytic performance: Boosting via Ce4+/Ce3+ and Ti4+/Ti3+ redox mediators
PublikacjaTitanium-substituted cerium-oxo-based UiO MOFs with terephthalate linkers modified by various groups (–Br, –NH2, –NO2) or their derivatives (N-heterocyclic or biphenyl groups) were combined with titanium dioxide in a multistep route to obtain a core-shell-like architecture. DFT simulations showed that Ce- and bimetallic Ti/Ce- MOFs exhibited different charge compensation. Extended characterization revealed the formation of heterojunctions between...
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Fabrication of Gold and Silver Nanoparticles Supported on Zinc Imidazolate Metal–Organic Frameworks as Active Catalysts for Hydrogen Release from Ammonia Borane
PublikacjaWell-dispersed Au and Ag nanoparticles (NPs) have been immobilized on a zinc imidazolate metal−organic framework, Zn(mim), using the “one-pot” method and tested as catalysts in ammonia borane hydrolysis. The AuNPs@Zn(mim) and AgNPs@Zn(mim) materials were characterized by FTIR, XRD, ICP-OES, TGA, BET, SEM, and TEM. The AgNPs@Zn(mim) catalyst showed a high yield (98.5%) and high hydrogen generation rate (3352.71 mL min−1 gAg−1) in...
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Nano soil improvement technique using cement
PublikacjaNano soil-improvement is an innovative idea in geotechnical engineering. Nanomaterials are among the newest additives that improve soil properties. Herein, laboratory tests, such as unconfined compressive strength, direct shear test, and initial tests, were conducted to investigate the geotechnical properties of Kelachay clay with micro- and nanosized cement to evaluate its particles in untreated soil and observe changes in the...
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Tyre/road noise measurements on ISO tracks according to the UNECE Regulation 117
PublikacjaWithin the Polish-Norwegian research project ELANORE, a limited Round Robin Test has been performed on 3 ISO tracks in Northern Europe. The basic objective of the project is to improve the EU directive on labelling of tyres for noise and rolling resistance, and this directive is based on the measurement procedures defined in the UN ECE Reg.117. The same test car, test tyres and measurement equipment as well as personnel were used...
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Enhanced photocatalytic, electrochemical and photoelectrochemical properties of TiO2 nanotubes arrays modified with Cu, AgCu and Bi nanoparticles obtained via radiolytic reduction
PublikacjaTiO2 nanotubes arrays (NTs), obtained via electrochemical anodization of Ti foil, were modified with monometallic (Cu, Bi) and bimetallic (AgCu) nanoparticles. Different amounts of metals’ precursors were deposited on the surface of NTs by the spin-coating technique, and the reduction of metals was performed via gamma radiolysis. Surface modification of titania was studied by EDS and XPS analysis. The results show that AgCu nanoparticles...
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Synthesis of green benzamide-decorated UiO-66-NH2 for biomedical applications
PublikacjaMetal-organic frameworks (MOFs) biocompatible systems can host enzymes/bacteria/viruses. Herein we synthesized a series of fatty acid amide hydrolase (FAAH)-decorated UiO-66-NH2 based on Citrus tangerine leaf extract for drug delivery and biosensor applications. Five chemically manipulated FAAH-like benzamides were localized on the UiO-66-NH2 surface with physical interactions. Comprehensive cellular and molecular analyses were...
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Tyre/road noise measurements on ISO tracks using the modified CPX method
PublikacjaTyre rolling noise test method specified in the UNECE Regulation 117 is directly used in the Tyre Labelling Directive. Noise level specified on EU Tyre Label of each new tyre available on the European market was determined based on vehicle coast-by noise measurements performed on the standard reference road surface proscribed in the ISO 10844:2014. Available data from investigations by the vehicle and tyre industry and results...
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Human breast milk concentration of neopterin at various stages of lactation and during a single feeding
PublikacjaThe aim of this work was to determine the physiological level of neopterin in human breast milk, and to study its variability depending on the duration of a single feeding and the lactation stage. Breast milk samples from 74 women were collected between 2 and 4 days after delivery, and at 15, 30, and 90 days after delivery. Additionally, breast milk samples from eight women were collected before and after 7 and 15 min of breastfeeding....
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The effect of nanoparticles size on photocatalytic and antimicrobial properties of Ag-Pt/TiO2 photocatalysts
PublikacjaAg-Pt-modified TiO2 nanocomposites were synthesized using the sol–gel method. Bimetallic modified TiO2 nanoparticles exhibited improved photocatalytic activity under visible-light irradiation, better than monometallic Ag/TiO2 and Pt/TiO2 nanoparticles (NPs). All modified powders showed localized surface plasmon resonance (LSPR) in visible region. The photocatalysts’ characteristics by X-ray diffractometry (XRD), scanning transmission...
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A systematic review on cellular responses of Escherichia coli to nonthermal electromagnetic irradiation
PublikacjaInvestigation of Escherichia coli under electromagnetic fields is of significance in human studies owing to its short doubling time and human‐like DNA mechanisms. The present review aims to systematically evaluate the literature to conclude causality between 0 and 300 GHz electromagnetic fields and biological effects in E. coli. To that end, the OHAT methodology and risk of bias tool were employed. Exponentially growing cells exposed...
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Photochemical and thermal reaction of intermediates in the phenylnitrene rearangment inside a hemicarcerand
PublikacjaBroadband irradiation (λ > 320 nm) of hemicarceplex H1 between −74 °C and −84 °C, produces encapsulated didehydroazepine (2), triplet phenylnitrene (3PN), 2-azabicyclo[3.2.0]hepta-1,3,6-triene (6), and 4-azaspiro[2.4]hepta-1,4,6-triene (7). The highly strained anti-Bredt imine 6 is formed from 2 via a photochemical four-electron electrocyclization. Under the irradiation conditions, 6 rearranges further to azaspirene 7. In addition,...
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Modeling by finite element methods of impact of erosion on frequency of normal modes of L-0 blade
PublikacjaAfter some time of exploitation steam turbine rotors blades in energetic industry they are being eroded and also their frequency of normal modes is changed. Those changes can cause to unwanted shift of blades normal mode frequencies. It is necessary to find quick method of rating changes of frequency in connection of mass loss due erosion. The evaluation of this dependence was made by finite element modeling method using HyperWorks...
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Cross-talk Between the Heart and Arteries in Older 65+ Adults
PublikacjaRegulatory synchronization between the heart and the arterial walls is essential for optimal blood delivery to tissues. We investigated functional coherence between heart rhythm and aortic wall compliance in 30 volunteers aged 65 – 74. ECG and carotid and iliac pulse-wave were recorded and digitized at 2 kHz. Carotid-femoral pulse-wave transit time (cfTT) which reflex aortic compliance was assessed using the intersecting tangent...
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Wire Arc Additive Manufactured Mild Steel and Austenitic Stainless Steel Components: Microstructure, Mechanical Properties and Residual Stresses
PublikacjaWire arc additive manufacturing (WAAM) is an additive manufacturing process based on the arc welding process in which wire is melted by an electric arc and deposited layer by layer. Due to the cost and rate benefits over powder-based additive manufacturing technologies and other alternative heat sources such as laser and electron beams, the process is currently receiving much attention in the industrial production sector. The gas...
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Standard and modified falling mass impact tests on preplaced aggregatefibrous concrete and slurry infiltrated fibrous concrete
PublikacjaAlthough several studies have been conducted to evaluate the impact response of concrete using theAmerican Concrete Institute (ACI) 544-2R falling mass impact test, the variations in test results are themain drawback of this testing method. This study aims to reduce the variations in experimental impacttest results by introducing two simple test setup modifications; (1) using coarse or fine aggregate bed-ding as an alternative...