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• Structural, magnetic and spectral properties of tetrahedral cobalt(II) silanethiolates: a variety of structures and manifestation of field-induced slow magnetic relaxation

  Publikacja

  • D. Kowalkowska-Zedler
  • A. Dołęga
  • N. Nedelko
  • R. Łyszczek
  • P. Aleshkevych
  • I. Demchenko
  • J. Łuczak
  • A. Ślawska-waniewska
  • A. Pladzyk

  - DALTON TRANSACTIONS - Rok 2020

  Blue crystals of five heteroleptic cobalt(II) silanethiolates 1–5 have been obtained by the reaction of [Co{SSi (tBuO)3}2(NH3)]2 with aminopyridines and aminomethylpyridines at an appropriate molar ratio and their structural, spectral, thermal and magnetic properties have been established and described. All complexes 1–5 contain Co(II) ions in a tetrahedral CoN2S2 environment formed by (tBuO)3SiS− residues and pyridines and present...

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