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Structural and catalytic properties of ceria layers doped with transition metals for SOFCs fueled by biogas
PublikacjaThe aim of this paper was to investigate an influence of the nanocrystalline Ce0.8A0.2O2-δ (A = Mn, Fe, Co, Ni, Cu) materials on the direct internal reforming of biogas in SOFC. Structural analysis of fabricated compounds has been done. An in-situ analysis of a composition of outlet gases from operating SOFC was performed using FTIR spectroscopy with simultaneous electrical tests. It was found out, that type of dopant strongly...
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Copper and cobalt co-doped ceria as an anode catalyst for DIR-SOFCs fueled by biogas
PublikacjaThe nanocrystalline compounds of Co and Cu co-doped ceria (with up to 20 mol.% of dopants) were fabricated by the reverse microemulsion synthesis method. They were deposited in a form of layers on the surface of SOFC anode in an aim to act as electrochemically active materials for biogas reforming process. Fourier Transformed Infrared Spectroscopy was used to analyze a composition of outlet gases simultaneously with the tests of...
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Investigation of praseodymium and samarium co-doped ceria as an anode catalyst for DIR-SOFC fueled by biogas
PublikacjaThe Pr and Sm co-doped ceria (with up to 20 mol.% of dopants) compounds were examined as catalytic layers on the surface of SOFC anode directly fed by biogas to increase a lifetime and the efficiency of commercially available DIR-SOFC without the usage of an external reformer. The XRD, SEM and EDX methods were used to investigate the structural properties and the composition of fabricated materials. Furthermore, the electrical...
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Investigation of functional layers of solid oxide fuel cell anodes for synthetic biogas reforming
PublikacjaSolid oxide fuel cells (SOFCs) are one of the most promising energy conversion devices due to their high efficiency, low pollution and fuel flexibility. Unfortunately, when hydrocarbons are used as a fuel, for example in the form of a biogas, solid carbon can deposit on the anode surface. This process leads to the degradation of the fuel cell performance. A possible solution to this problem is to apply an additional catalytic material,...
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Piotr Jasiński prof. dr hab. inż.
OsobyPiotr Jasinski obtained MSc in electronics in 1992 from the Gdansk University of Technology (GUT), Poland. Working at GUT, he received PhD in 2000 and DSc in 2009. Between 2001 and 2004 Post Doctoral Fellow at Missouri University of Science and Technology, while between 2008 and 2010 an Assistant Research Professor. Currently is an Associate Professor at Gdansk University of Technology working in the field of electronics, biomedical...
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CeCu2O4 as a functional layer on solid oxide fuel cells for synthetic biogas reforming
PublikacjaSolid Oxide Fuel Cells (SOFC) are one of the most promising electrochemical devices, which can convert chemical energy to the electrical energy these days. Their ability to work with different kind of fuel makes them noteworthy. SOFC can work with biogas. The problem arises when solid carbon starts to be deposited in anode. That leads to degradation of fuel cell. Simple solution is to apply catalytic functional layer, which is...
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Catalytic activity of Ni-MgAl2O4 modified with transition metal (Ti, Mo, W) carbides as potential catalysts for resource recovery via dry reforming of waste plastics
PublikacjaThe growing amounts of plastic waste and CO2 emissions are two environmental threats that require urgent attention. Pyrolysis combined with dry reforming (PCDR) is a technology that allows both CO2 utilization and resource recovery from waste plastic. New catalysts for PCDR are crucial for developing efficient and stable processes that can be widely implemented in the industry. In this study, Ni/MgAl2O4 catalysts modified using different...
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Natalia Anna Wójcik dr hab. inż.
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Reaction quotients of reforming reactions for SOFC and SOFC with LSCNT layer fueled by biogas mixture at 750 C - longterm
Dane BadawczeThe dataset contains the calculated reaction quotients of reforming reactions for the SOFC and SOFC with LSCNT layer (La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-s) fueled by synthetic biogas mixture (60:40 CH4:CO2). The outlet concentration of the gases from SOFC were measured using novel FTIR-based unit.
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Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
PublikacjaDry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view,...
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Nanostructure of the laser-modified transition metal nanocomposites for water splitting
PublikacjaAlthough hydrogen is considered by many to be the green fuel of the future, nowadays it is primarily produced through steam reforming, which is a process far from ecological. Therefore, emphasis is being put on the development of electrodes capable of the efficient production of hydrogen and oxygen from water. To make the green alternative possible, the solution should be cost-efficient and well processable, generating less waste...
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Calixthioamides as ionophores for transition and heavy-metal cations
PublikacjaThere is an increasing interest in applying p-tert-butylcalix[4]arenes as sensing materials in ion-selective electrodes(ISEs). Considerable efforts were made to design calixarenes that are selective for some heavy- or transitionmetal ions to be used in ISEs for controlling and monitoring the level of such pollutants in the environment. It has been reported that introduction of softer sulfur atoms instead of oxygen atoms in calix[4]arene...
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Change of reaction quotients for SOFC fueled by biogas mixture at 750 C
Dane BadawczeThe dataset contains the Change of reaction quotients for SOFC fueled by biogas mixture at 750 C (60:40 CH4:CO2). The outlet concentration of the gases from SOFC were measured using novel FTIR-based unit.
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FTIR spectra of gas mixtures from the process of biogas dry reforming using CLO catalyst
Dane BadawczeThe dataset contains the FTIR spectra collected during the catalytic measurements of dry reforming of biogas (60/40 CH4-CO2) using Ce0.8La0.2O2 nanocatalyst. The specatra were collected every 1 minute.
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Euilibrium composition of CH4-CO2-CO-H2-H2O-C system under biogas reforming conditions
Dane BadawczeThe equilibrium compositions of CH4, CO2, CO, H2, H2O and C under the biogas mixture reforming were supplied with this dataset
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Calix[4]arene-Thioamides as Ionophores for Transition and Heavy Metal cations
PublikacjaCalix[4]arene derivatives play an important role as sensing materials in Ion Selective Electrodes(ISEs). Nowadays a high impact is put to control in natural waters the level of toxic heavy metals, like Pb ,Cd, Hg or Cu which may cause the great risk to human health. Our goal was to design and to synthesize ligands possessing ability to bind transition and heavy metal cations. The synthesis, crystal structures,extractive and ionophoric...
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FTIR spectra of gas mixtures from the process of biogas dry reforming using alumina catalyst - blank
Dane BadawczeThe dataset contains the FTIR spectra collected during the catalytic measurements of blank sample Al2O3 for dry reforming of biogas (60/40 CH4-CO2). The specatra were collected every 1 minute.
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Transition Metal Oxides influence on phosphate and borate glasses structure
PublikacjaBorate and phosphate glasses possess many potential luminescence and optical applications. With their low melting point, they are one of the most often studied amorphous materials. In recent years these glasses, doped with transition metal oxides (TMO), gained much attention due to their tunable structural and thermal properties. Review of systems containing TMOs was presented. Additionally synthesis of binary MnO-P2O5 and MnO-B2O3...
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FTIR spectra of gas mixtures from the process of biogas dry reforming using CLO/Cu catalyst
Dane BadawczeThe dataset contains the FTIR spectra collected during the catalytic measurements of dry reforming of biogas (60/40 CH4-CO2) using Ce0.8La0.2O2+10wt.%Cu nanocatalyst. The specatra were collected every 1 minute.
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FTIR spectra of gas mixtures from the process of biogas dry reforming using CeO2/Cu catalyst
Dane BadawczeThe dataset contains the FTIR spectra collected during the catalytic measurements of dry reforming of biogas (60/40 CH4-CO2) using CeO2+10wt.%Cu nanocatalyst. The specatra were collected every 1 minute.
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FTIR spectra of gas mixtures from the process of biogas dry reforming using Al2O3/5%Cu catalyst
Dane BadawczeThe dataset contains the FTIR spectra collected during the catalytic measurements of dry reforming of biogas (60/40 CH4-CO2) using AlOOH/1%Cu nanocatalyst. The specatra were collected every 1 minute from 800C to 500C. Reagent flow was set to 20ml/min.
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FTIR spectra of gas mixtures from the process of biogas dry reforming using CeO2/5%Cu catalyst
Dane BadawczeThe dataset contains the FTIR spectra collected during the catalytic measurements of dry reforming of biogas (60/40 CH4-CO2) using CeO2/5%Cu nanocatalyst. The specatra were collected every 1 minute from 800C to 500C. Reagent flow was set to 20ml/min.
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FTIR spectra of gas mixtures from the process of biogas dry reforming using Al2O3/5%Cu catalyst
Dane BadawczeThe dataset contains the FTIR spectra collected during the catalytic measurements of dry reforming of biogas (60/40 CH4-CO2) using Al2O3 (TMDAR)/5%Cu nanocatalyst. The specatra were collected every 1 minute from 800C to 500C. Reagent flow was set to 20ml/min.
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Insulator to correlated metal transition in V1−xMoxO2
PublikacjaDyskutowane jest przejście typu izolatro - metal w domieszkowanym atomami Molibdenu związku V1-xMoxO2. Prezentowany jest diagram fazowy.
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Insulator to correlated metal transition inV1−xMoxO2
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublikacjaWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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Syntheses and Structures of Transition Metal Complexes with Phosphanylphosphinidene Chalcogenide Ligands
PublikacjaThe reactivity of the phosphanylphosphinidene complex [(DippN)2W(Cl)(η2-P-PtBu2)]− (1) toward chalcogens (Ch = Se, S) was studied. Reactions of stoichiometric amounts of 1 with chalcogens in DME yielded monomeric tungsten complexes with phosphanylphosphinidene chalcogenide ligands of the formula tBu2P−P−Ch (Ch = Se (in 2) and S (in 5)), which can be regarded as products of the addition of a chalcogen atom to a P=W bond in starting...
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Preparation of methanation catalysts for high temperature SOEC by β-cyclodextrin-assisted impregnation of nano-CeO2 with transition metal oxides
PublikacjaThe aim of this work was to prepare and examine the catalytic activity of nanometric CeO2 decorated with transition metal oxides – Ni, Co, Cu, Fe and Mn – towards a high-temperature methanation process under SOEC CO2/H2O simulated co-electrolysis conditions. Samples were prepared using the wet impregnation method via the conventional process and with the addition of native cyclodextrin. The influence of β-cyclodextrin (βCD) onto...
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Thermodynamic Properties of Inorganic Salts in Nonaqueous Solvents. VI. Apparent Molar Volumes, Expansibilities, and Compressibilities of Divalent Transition Metal Ions in Methanol and Dimethylsulfoxide
PublikacjaThe temperature dependence of the density of divalent transition metal perchlorates in dimethylsulfoxide as well as cobalt(II), nickel(II) perchlorates, and copper(II) trifluoromethanesulfonate in methanol was determined. Moreover, sound velocities for solutions of cobalt(II), nickel(II) perchlorates, and copper(II) trifluoromethanesulfonate in methanol have been measured at 298.15 K. From these data, the partial molar volumes,...
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Study of ZrS3-based field-effect transistors toward the understanding of the mechanisms of light-enhanced gas sensing by transition metal trichalcogenides
PublikacjaExtending knowledge of the properties of low-dimensional van der Waals materials, including their reactivity to the ambiance, is important for developing innovative electronic and optoelectronic devices. Transition metal trichalcogenides with tunable optical band gaps and anisotropic conductivity are an emerging class among low- dimensional structures with the possibility of gate tunability and photoreactivity. These properties...
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Calix[4]arene-Thioamides as Ionophores for Transition and Heavy Metal Cations.
PublikacjaPochodne kaliks[4]arenów odgrywają ważną rolę jako materiał aktywny w membranowych elektrodach jonoselektywnych. Obecnie duży nacisk kładzie się na kontrolę stężeń kationów metali ciężkich, takich jak Pb, Cd, Hg, Cu w wodach naturalnych. Naszym zadaniem było zaprojektować i zsyntezować ligandy, które wykazują zdolność do wiązania kationów metali ciężkich i przejściowych. Synteza, struktury krystaliczne, ekstrakcja i właściwości...
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Application of Coordination Compounds with Transition Metal Ions in the Chemical Industry—A Review
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Identification of multisite behavior in a broadly emitting transition-metal system using pressure
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Transition-Metal-Promoted Oxidative Cyclization To Give 1,2,4-Trisubstituted Carbazole Scaffolds
PublikacjaHerein, we describe the synthesis of a 1,2,4-trisubstituted carbazole core from 5-(1H-indol-3-yl)-3-oxopentanoic acid esters or amides. For oxidative cyclization, we tested two different approaches. First, we used manganese triacetate as a conventional moderate oxidizer to ensure the radical course of the reaction. Second, we examined the use of a more complex oxidizing agent I2/Me(OTf)3. In both cases, formation of a fused-ring...
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Apparent molar volumes of divalent transition metal bromides in dimethyl sulfoxide solutions
PublikacjaWyznaczono pozorne i cząstkowe molowe objętości bromków dwuwartościowych metali przejściowych szeregu Mn(II)-Zn(II)w roztworach w dimetylosulfotlenku. Przedyskutowano korelacje między objętościami molowymi a stanami koordynacyjnymi i sposobem jonizacji soli.
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Group-9 Transition-Metal Suboxides Adopting the Filled-Ti2Ni Structure: A Class of Superconductors Exhibiting Exceptionally High Upper Critical Fields
PublikacjaTi2Ni and the related η-carbide structure are known to exhibit various intriguing physical properties. The Ti2Ni structure with the cubic space group Fd3̅m is surprisingly complex, consisting of a unit cell with 96 metal atoms. The related η-carbide compounds correspond to a filled version of the Ti2Ni structure. Here, we report on the structure and superconductivity in the η-carbide-type suboxides Ti4M2O with M = Co, Rh, and Ir....
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Functionalization of the transition metal oxides FeO, CoO, and NiO with alkali metal atoms decreases their ionization potentials by 3–5 eV
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Adiabatic Compressibilities of Divalent Transition-Metal Perchlorates and Chlorides in N,N-Dimethylacetamide and Dimethylsulfoxide
PublikacjaZmierzono prędkości rozchodzenia się dźwięku roztworów nadchloranów i chlorków manganu(II), kobaltu(II), niklu(II), miedzi(II) i cynku(II) w N,N-dimetyloacetamidzie i dimetylosulfotlenku w temperaturze 298.15 K. Obliczono ściśliwości adiabatyczne i pozorne ściśliwości adiabatyczne badanych roztworów. Przedyskutowano wpływ anionu i rodzaju rozpuszczalnika na uzyskane graniczne wartości pozornych ściśliwości adiabatycznych soli.
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Apparent molar volumes of divalent transition metal chlorides and perchlorates in dimethyl sulfoxide solutions.
PublikacjaZmierzono gęstości roztworów nadchloranów i chlorków dwuwartościowych metali szeregu Mn(II)-Zn(II) w dimetylosulfotenku. Wyznaczone na drodze ekstrapolacji cząstkowe objętości molowe nadchloranów rozdzielono na udziały jonowe. Przeanalizowano wpływ pola ligandów na cząstkowe objętości molowe kationów. Przedstawiono związek między wartościami pozornych objętości molowych a stanami koordynacyjnymi soli w DMSO.
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Apparent molar volumes of divalent transition metal perchlorates and chlorides in N,N-dimethylacetamide.
PublikacjaZmierzono gęstości roztworów nadchloranów i chlorków manganu(II), kobaltu(II), niklu(II), miedzi(II) i cynku(II) w temperaturach 10, 20,25, 30, 40, 50 i 60(o)C. Obliczono pozorne objętości molowe. Wyznaczono graniczne wartości cząstkowych molowych objętości tych soli oraz odpowiednie rozszerzalności. Przeanalizowano i wyjaśniono różnice we właściwościach wolumetrycznych roztworów nadchloranów i chlorków.
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Chemical-vapor generation of transition metals through the reaction with tetrahydroborate in recent achievements in analytical atomic spectrometry
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Mixed electronic-ionic conductivity in transition metal oxide glasses con-taining alkaline ions
PublikacjaOpisano właściwości elektryczne szkieł z tlenkami metali przejściowych zawierających jony metali alkalicznych. Szczególną uwagę zwrócono na typowe zmiany przewodnictwa występujące przy domieszkowaniu tego typu szkieł jonami metali alkalicznych. Porównano przewodnictwo elektryczne szkieł fosforanowo-żelazowych zawierających jony sodu z przewodnictwem szkieł bizmutowo-miedziowych.
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Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems
PublikacjaThis report provides an overview of the use of phosphaalkenes (C=P) in syntheses of various complexes. Going through successive complexes containing the d-block metals, we sought how this area of chemistry was formed over the years. Additionally, this work contains information on the possible coordination types and means of constructing the complexes. In addition, this review reveals the reactivities of phosphaalkene complexes...
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Solvation and partial molar volumes of some transition metal cations in N,N-dimethylacetamide, triethylphosphate and acetonitrile.
PublikacjaW oparciu o precyzyjne pomiary gęstości roztworów nadchloranów metali przejściowych szeregu Mn(II)-Zn(II) w DMA, TEP i AN wyznaczono pozorne molowe oraz graniczne wartości cząstkowych molowych objętości sole w temperaturach 293, 298 i 303,15 K. Wyznaczone wartości rozdzielono na udziały jonowe. Przeanalizowano czynniki decydujące o wielkości cząstkowych molowych objętości solwatowanych kationów.
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TRANSITION METAL CHEMISTRY
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O-substituted tetrahydroxamate derivatives of p-tert-butylcalix[4]arene as receptors for transition and heavy metal cations
PublikacjaTetrasubstituted O-hydroxamate derivatives of p-tert-butylcalix[4]arene were applied as active materials in ion-selective membrane electrodes and were tested towards Pb-selectivity. The electrodes gave near-Nernstian characteristics for Pb2+ cations. The selectivity coefficients were determined. The influence of plasticizer on the electrode behaviour was studied. The dependence of the chemical structure on selectivity coefficients...
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Interaction of Ionomers and Polyelectrolytes with Divalent Transition Metal Cations (Cu2+ and VO2+): A Study by Electron Spin Resonance (ESR) Spectroscopy and Viscosimetry
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Achiral and Chiral Transition Metal Complexes with Modularly Designed Tridentate PNP Pincer-Type Ligands Based on N-Heterocyclic Diamines
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Thermodynamic properties of inorganic salts in nonaqueous solvents. II. Apparent molar volumes and compressibilities of divalent transition-metal perchlorates in acetonitrile
PublikacjaW oparciu w wyniki pomiarów gęstości wykonanych w temperaturze 15,20,25,30,35,40 i 50 stopni Celsjusza oraz pomiaru szybkości dżwięku w temperaturze 25 stopni Celsjusza, wyznaczono pozorne objętości molowe oraz ściśliwości adiabatyczne roztworów nadchloranów manganu(II), kobaltu(II), niklu(II) i cynku(II). Obliczono odpowiednie wartości standardowe oraz rozszerzalności izobaryczne. Przeanalizowano związki między strukurą elektronową...
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Thermodynamic properties of inorganic salt in nonaqeous solvents. IV. Apparent molar volumes and compressibilities of divalent transition-metal bromides and chlorides in acetonitrile
PublikacjaWykonano pomiary gęstości roztworów chlorków i bromków w acetonitrylu w temperaturze 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 K oraz pomiar szybkości rozchodzenia się dźwięku w badanych roztworach w temperaturze 298.15 K. Uzyskane wartości pozwoliły wyznaczyć pozorne objętości molowe oraz pozorne adiabatyczne ściśliwości, których wartości oraz zmiany ze stężeniem tłumaczone są obecnością złożonych układów komplesów w roztworze.