Wyniki wyszukiwania dla: gas chromatography
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Sulfur compounds: Gas chromatography
PublikacjaSulfur compounds, due to their properties, are responsible for the damage of our environment. For this reason sulfur containing compounds are of constant concern in many fields. Gas chromatography (GC), due to combination of separation capability and sensitive detection is a prime technique for the analysis of thes compounds in various matrices. The chapter rewies general problems of the determination of these compounds by GC and...
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Developments in Miniaturization of Gas Chromatography
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Gas chromatography-olfactometry of alcoholic beverages
PublikacjaW rozdziale 5 książki przedstawiono zastosowanie techniki chromatografia gazowa-olfaktometria (GC-O)w ustalaniu zależności między zapachem a składem chemicznym lotnej frakcji napojów alkoholowych. W pierwszej części przedstawiono zasadę techniki GC-O, procedury przygotowania próbek do analizy, metody zbierania danych oraz warunki analizy. Następnie omówiono zastosowanie techniki GC-O w analizie i ocenie jakości różnych napojów...
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Determination of β-blockers and β-agonists using gas chromatography and gas chromatography–mass spectrometry – A comparative study of the derivatization step
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Comparison of an Electronic Nose Based on Ultrafast Gas Chromatography, Comprehensive Two-Dimensional Gas Chromatography, and Sensory Evaluation for an Analysis of Type of Whisky
PublikacjaWhisky is one of the most popular alcoholic beverages. There are many types of whisky, for example, Scotch, Irish, and American whisky (called bourbon). The whisky market is highly diversified, and, because of this, it is important to have a method which would enable rapid quality evaluation and authentication of the type of whisky. The aim of this work was to compare 3 methods: an electronic nose based on the technology of ultrafast...
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APPLICATION OF ULTRAFAST GAS CHROMATOGRAPHY TO RECOGNIZE ODOR NUISANCE
PublikacjaPotentialities of ultrafast gas chromatography applied to periodical monitoring of odor nuisance originating from a municipal landfill have been examined. The results of investigation on classification of the atmospheric air samples collected in a vicinity of the landfill during winter and summer season have been presented. The investigation was performed using ultrafast gas chromatography of Fast/Flash GC type HERACLES II by Alpha...
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Novel stationary phases based on asphaltenes for gas chromatography
PublikacjaWe present the results of investigations on the possibility of the application of the asphaltene fraction isolated from the oxidized residue from vacuum distillation of crude oil as a stationary phase for gas chromatography. The results of the investigation revealed that the asphaltene stationary phases can find use for the separation of a wide range of volatile organic compounds. The experimental values of Rohrschneider/McReynolds...
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Application of gas chromatography to evaluate the quality of rapeseed oil
PublikacjaTwo-dimensional gas chromatography is an analytical technique, which is increasingly being used in food research. Through the analysis of volatile fraction, it is possible to determine the quality of food products. One of the reasons for the deterioration of food is thermal degradation. Products that are often subject to degradation reactions due to temperatures are edible oils. In the thesis, the results of edible oils with different...
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Application of gas chromatography to the analysis of spirit-based alcoholic beverages
PublikacjaSpirit-based beverages are alcoholic drinks, which production processes are dependent on the type and origin of raw materials. The composition of this complex matrix is difficult to analyze and scientists commonly choose a gas chromatography techniques for this reason. With a wide selection of extraction methods and detectors it is possible to provide qualitative and quantitative analysis for many chemical compounds with a various...
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Two-dimensional gas chromatography – principles and application in fruits analysis
PublikacjaTwo-dimensional gas chromatography is a rapidly developing analytical technique. One of the major uses of this technique is its use for food analysis. The paper presents the principle of operation and history of this analytical technique. The specification of the two-dimensional gas chromatography technique has been discussed. The principles of separation of ingredients and application of the method, particularly in the analysis...
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Meat freshness classification using ultra-fast gas chromatography
PublikacjaMeat constitutes an important component of human diet. In order to ensure that it is safe to consume, it is important to be able to determine whether a particular sample is fresh. To this end, an analysis of the headspace of pork, beef, and poultrywas performed over a period of seven days using ultra-fast gas chromatography. Compounds that may possibly be used as indicators of spoilage were identified. Based on the obtained results...
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Classification of Polish wines by application of ultra-fast gas chromatography
PublikacjaThe potential of ultra-fast gas chromatography (GC) combined with chemometric analysis for classification of wine originating from Poland according to the variety of grape used for production was investigated. A total of 44 Polish wine samples differing in the type of grape (and grape growth region) used for the production as well as parameters of the fermentation process, alcohol content, sweetness, and others which characterize...
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Chiral gas chromatography as a tool for investigation into illicitly manufactured methamphetamine
PublikacjaW pracy przedstawiono zastosowanie gazowej chromatografii chiralnej do rozdzielania związków ubocznych powstających w trakcie syntezy metylamfetaminy. Opisano rozdzielanie enancjomerów efedryny, pseudoefedryny, chlorowanych związków posrednich i metylamfetaminy stosując do derywatyzacji bezwodniki fluorowanych kwasów. Jako fazę chiralną zastosowano CHIRALDEX B-DM. Do rozdzielenia enancjomerów pseudoefedryny oraz chlorowanych produktów...
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Chemometric analysis for optimizing derivatization in gas chromatography-based procedures
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Sorption properties of asphaltene stationary phases for gas chromatography separations
PublikacjaW pracy przedstawiono wyniki badań nad możliwością wykorzystania faz stacjonarnych na bazie frakcji asfaltenowych do rozdzielania mieszanin związków chemicznych z wykorzystaniem chromatografii gazowej oraz porównano selektywność faz przygotowanych z frakcji asfaltenowych wyizolowanych z różnych surowców. Na podstawie uzyskanych wyników obliczono wartości liniowych indeksów retencji oraz stałych Rohrschneidera McReynoldsa, za pomocą...
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Two-Dimensional Gas Chromatography Coupled With Mass Spectrometry in Food Analysis
PublikacjaThe development of instrumental analytical techniques provided the opportunity for in-depth characterization of many food matrices. In particular, the use of gas chromatography coupled with mass spectrometry gives impressive results in terms of quality and authenticity testing, conducting food freshness evaluations and contamination assessments. A new variant of gas chromatography, namely two-dimensional gas chromatography (GC...
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Detection of apple in orange juice using ultra-fast gas chromatography
PublikacjaThe determination of authenticity is an increasingly important issue for food quality and safety. The use of an electronic nose based on ultra-fast gas chromatography technique ensures rapid analysis of the volatile compounds from food products. Due to the fact that this technique enables chemical profiling of agricultural products, it can be an effective tool for authentication when combined with chemometrics. In this article...
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Procedure of determination of volatile trihalomethanes in human urine with perwaporation and gas chromatography
PublikacjaPraca przedstawia wyznaczanie podstawowych parametrów walidacyjnych nowej procedury oznaczania lotnych związków chlorowcoorganicznych z grupy trihalometanów w próbkach moczu ludzkiego, opartej na zastosowaniu:- techniki perwaporacji na etapie izolacji i wzbogacania analitów;- bezpośredniego dozowania próbek ekstraktów (permeatu) do kolumny chromatograficznej;- chromatograficznego rozdzielanie mieszaniny na poszczególne składniki;-wykorzystaniu...
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Modern techniques of sample preparation for determination of organic analytes by gas chromatography
PublikacjaW pracy dokonano przeglądu szerokiego spektrum technik przygotowania próbki, ze szczególnym uwzględnieniem technik o charakterze prośrodowiskowym. Opisu technik dokonano pod kątem wykorzystywanych mechanizmów izolacji analitów oraz stosowanych rozwiązań aparaturowych. Przegląd rozwiązań aparaturowych uzupełniono o podstawy teoretyczne izolacji bazującej na zjawisku podziału analitów.
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A procedure for the determination of dichloromethane and tetrachloroethene in water using pervaporation and gas chromatography
PublikacjaIn the present study, pervaporation was applied to the determination of tetrachloroethene (PCE) and dichloromethane (DCM) in liquid samples. PCE is the most commonly used solvent in dry-cleaning processes. PCE belongs to group 2A of carcinogens (probably carcinogenic to humans) according to the classification of the International Agency for Research on Cancer (IARC). DCM is also widely used as an industrial solvent for the purification...
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Procedure of determination of volatile trihalomethanes in human urine with pervaporation and gas chromatography
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Enantioselective comprehensive two-dimensional gas chromatography of lavender essential oil
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Simultaneous analysis of non-steroidal anti-inflammatory drugs and estrogenic hormones in water and wastewater samples using gas chromatography–mass spectrometry and gas chromatography with electron capture detection
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Application of normal-phase high-performance liquid chromatography followed by gas chromatography for analytics of diesel fuel additives
PublikacjaThe paper presents the results of investigations on new procedures of determination of selected cleaning additives in diesel fuel. Two procedures: one-step analysis using gas chromatography with flame ionization detection (GC-FID) or mass spectrometry (GC-MS) and a two-step procedure in which normal-phase high-performance liquid chromatography (NP-HPLC) was used for preliminary separation of the additives, were compared. The additive...
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Application of normal-phase high-performance liquid chromatography followed by gas chromatography for analytics of diesel fuel additives
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Funcionality assessment of Citrus Hysteria peel as a protective barrier using gas chromatography
PublikacjaThe aim of this study was to analyse the volatile fractions of fruit peel and pulp using two-dimensional gas chromatography technique coupled with mass spectrometry. The isolation of the compounds was achieved by microextraction to the stationary phase from the headspace of the sample (HS-SPME). Mass spectrometry with time-of-flight analyser (TOF-MS) was used to identify the chemical compounds. There are no reports in the literature...
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Determination of MDPBP in postmortem blood samples by gas chromatography coupled with mass spectrometry
PublikacjaMDPBP (1-(3,4-methylenedioxyphenyl)-2-(1-pyrrolidinyl)-1-butanone) is a new psychoactive substance sold on the black market. It has been a controlled drug of abuse in Poland and China since 2015 as some toxic and fatal cases connected with use of synthetic cathinone derivatives were observed. The fatal case outlined here concerns a 19 year-old man, who was found dead with an envelope containing white powder lying nearby the cadaver....
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Identification of aromatic compounds in odours mixture by gas chromatography and field olfactometry techniques
PublikacjaThis paper shows the results of investigation on identification aromatic compounds present in odorous mixture in atmospheric air samples collected in a vicinity of the oil refinery LOTOS S.A., located in Gdansk, during March and April period have be presented. The studies were conducted by the use of comprehensive two-dimensional gas chromatograph equipped with a cryogenic modulator and coupled with a time-of-flight mass spectrometer,...
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Combined gas chromatography—mass spectrometry for the analysis of central and peripheral biogenic amines
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Chemometric optimization of derivatization reactions prior to gas chromatography–mass spectrometry analysis
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Multidimensional Gas Chromatography in Essential Oil Analysis. Part 1: Technical Developments
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Headspace liquid phase microextraction for quantitation of hexanal in potato crisps by gas chromatography
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Determination of aliphatic amines in water by gas chromatography using headspace solvent microextraction
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Qualitative characteristics and comparison of volatile fraction of vodkas made from different botanical materials by comprehensive two-dimensional gas chromatography and the electronic nose based on the technology of ultra-fast gas chromatography
PublikacjaBACKGROUND Vodka is a spirit-based beverage made from ethyl alcohol of agricultural origin. At present, increasingly more vodka brands have labels that specify the botanical origin of the product. Until now, the techniques for distinguishing between vodkas of different botanical origin have been costly, time-consuming and insufficient for making a distinction between vodka produced from similar raw materials. Therefore, it is...
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Methods of assaying volatile oxygenated organic compounds in effluent samples by gas chromatography—A review
PublikacjaThe paper is a review of the procedures for the determination of volatile and semivolatile oxygenated organic compounds (O-VOCs) in effluent samples by gas chromatography. Current trends and outlook for individual steps of the procedure for the determination of O-VOCs in effluents are discussed. The available sample preparation techniques and their limitations are described along with GC capillary columns used for O-VOCs separation...
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Comprehensive two-dimensional gas chromatography - promising technique for analysis of complex food matrices
PublikacjaThe present paper is focused on brief description of operational principle of comprehensive two-dimensional gas chromatography (GC×GC) technique, instrumentation and data processing. Furthermore, the examples of application in the field of food analysis, performed also in the author's laboratory, are given. The detailed discussion of GC×GC characterization and comparison of the volatile composition of berries of different blue...
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Application of static headspace gas chromatography for routine analysis of VFAs in cattle farm wastewater
PublikacjaOznaczanie lotnych kwasów tłuszczowych w próbkach środowiskowych jest tematem coraz powszechniej analizowanym z uwagi na ich uciążliwość w środowisku. Celem pracy było wykorzystanie techniki statycznej analizy headspace (HS) w połączeniu z analizą chromatograficzną do oznaczania lotnych kwasów monokarboksylowych w wodnych próbkach środowiskowych pochodzących z hodowli bydła.
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Determination of volatile organic compounds using solventless sample preparation techniques and gas chromatography
PublikacjaIn this paper the latest advances in the determination of volatile organic compounds using solvent-free extraction techniques in the sample preparation step are presented. A paper is focus mainly on one of the most popular sample preparation technique: solid-phase microextraction technique (SPME) combined with different detection systems and its applications to sampling of VOCs from the samples with different matrices. This paper...
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Comprehensive two-dimensional gas chromatography for determination of the terpenes profile of blue honeysuckle berries
PublikacjaTerpenes are the main group of secondary metabolites, which play essential role in human. The establishment of the terpenes profile of berries of different blue honeysuckle cultivars was achieved by headspace solid-phase microextraction coupled with comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry (HS-SPME/GCGC-TOFMS). The berries were found to contain 44 terpenes identified by GCGC-TOFMS....
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Evaluation of the usefulness and optimization of the separation conditions in Empty Column Gas Chromatography (EC-GC)
PublikacjaDotychczasowe badania wykazały, że możliwe jest rozdzielanie wysokowrzących mieszanin techniką chromatografii gazowej z zastosowaniem pustej rurki kapilarnej z topionej krzemionki, zamiast kolumn zawierających fazę stacjonarną. Operacja rozdzielania chromatograficznego ma miejsce jedynie na zasadzie różnicy temperatur wrzenia rozdzielanych substancji. Wysoki stopień podobieństwa warunków rozdzielania, osiąganych w ten sposób, z...
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Multidimensional Gas Chromatography in Essential Oil Analysis. Part 2: Application to Characterisation and Identification
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Comprehensive two-dimensional gas chromatography-mass spectrometry: Recent evolution and current trends
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Essential-Oil Analysis of Irradiated Spices by Using Comprehensive Two-Dimensional Gas Chromatography
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Analysis of essential oils through comprehensive two-dimensional gas chromatography: General utility
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Headspace Liquid-Phase Microextraction of Chlorobenzenes in Soil with Gas Chromatography-Electron Capture Detection
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Determination of solvents residues in vegetable oils and pharmaceuticals by headspace analysis and capillary gas chromatography.
PublikacjaPrzedstawiono wyniki zastosowania techniki analizy fazy nadpowierzchniowej w połączeniu z kapilarną chromatografią gazową do oznaczania wybranych rozpuszczalników organicznych w próbkach olejów jadalnych i produktów farmaceutycznych. Oznaczane rozpuszczalniki to: benzen, toluen, heksan oraz chlorowcopochodne węglowodorów alifatycznych. Opracowaną procedurę poddano walidacji. Wyznaczono granicę wytrzymalności, oznaczalności, liniowość...
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Development and evaluation of headspace gas chromatography method for the analysis of carbonyl compounds in spirits and vodkas
PublikacjaPrzedstawiono wyniki oznaczania związków karbonylowych (po przeprowadzeniu w pochodne przy użyciu odczynnika derywatyzującego - o-PFBHA) przy wykorzystaniu techniki analizy fazy nadpowierzchniowej w połączeniu z chromatografią gazową i detektorem wychwytu elektronów(ECD). Przedstawiono optymalizację metodyki oraz wyniki uzyskane podczas próbek rzeczywistych wybranych wyrobów spirytusowych.
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A headspace solid-phase microextraction method development and itsapplication in the determination of volatiles in honeys by gas chromatography
PublikacjaThe first part of the paper presents the detailed optimisation of all steps of the determination procedureof volatiles from Polish honeys by headspace solid-phase microextraction (HS-SPME) as the sample preparationmethod and gas chromatography/mass spectrometry (GC-MS) as the method of final determination.The methodology of semi-quantative analysis allowed the isolation and identification of volatile fractioncompounds from popular...
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Novel analytical method for detection of orange juice adulteration based on ultra-fast gas chromatography
PublikacjaThe food authenticity assessment is an increasingly important issue in food quality and safety. The application of an electronic nose based on ultra-fast gas chromatography technique enables rapid analysis of the volatile compounds from food samples. Due to the fact that this technique provides chemical profiling of natural products, it can be a powerful tool for authentication in combination with chemometrics. In this article,...
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Poultry meat freshness evaluation using electronic nose technology and ultra-fast gas chromatography
PublikacjaTo ensure that chicken meat products are safe to consume, it is important to be able to reliably determine its shelf-life. To assess the applicability of ultra-fast gas chromatography and electronic nose technology in evaluation of poultry, an analysis of the headspace of ground chicken meat samples refrigerated over a period of 7 days was performed. Chemometric techniques were used to mine additional information from a multiparametric...
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Authenticity Assessment of the "Onisiówka" Nalewka Liqueurs Using Two-Dimensional Gas Chromatography and Sensory Evaluation
PublikacjaThe “Onisiówka” nalewka liqueur is a regional Polish alcoholic beverage, which is inscribed on the list of regional and traditional products of the Ministry of Agriculture and Rural Development in Poland. It is produced from multiflower honey, black elderberry flower syrup, and spirit. Due to fact that the “Onisiówka” nalewka liqueur has never been investigated, these studies are the foundation for further work on this regional...
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Application of gas chromatography–tandem mass spectrometry for the determination of amphetamine-type stimulants in blood and urine
PublikacjaAmphetamine, methamphetamine, phentermine, 3,4-methylenedioxyamphetamine (MDA), 3,4-methylenedioxymethamphetamine (MDMA), and 3,4-methylenedioxy-N-ethylamphetamine (MDEA) are the most popular amphetamine-type stimulants. The use of these substances is a serious societal problem worldwide. In this study, a method based on gas chromatography-tandem mass spectrometry (GC-MS/MS) with simple and rapid liquid-liquid extraction (LLE)...
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A comparison of three solvent-free techniques coupled with gas chromatography for determining trihalomethanes in urine samples
PublikacjaDążenie do oznaczania lotnych analitów organicznych w próbkach płynów biologicznych charakteryzujących się złożonym, a często zmiennym składem matrycy, stanowi siłę napędową do działań analityków w zakresie poszukiwania nowych rozwiązań metodycznych i aparaturowych. Publikacja ta przedstawia porównanie trzech technik zastosowanych do tych celów: technikę analizy fazy nadpowierzchniowej z generacją strumienia ciekłego sorbentu...
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Application of gas chromatography-olfactometry (GC-O) in analysis and quality assessment of alcoholic beverages - a review
PublikacjaW ostatnich latach prowadzone są intensywne badania nad aktywnością sensoryczną poszczególnych składników zapachów napojów alkoholowych i nad zależnościami pomiędzy zapachem, a składem chemicznym lotnej frakcji tych produktów z wykorzystaniem techniki chromatografii gazowej z detekcją olfaktometryczną (GC-O). GC-O jest techniką wykorzystującą możliwość oceny sensorycznej eluatu z kolumny chromatograficznej, przy czym dla każdego...
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Continuous Monitoring of Thermooxidative Degradation Products of Polystyrene by Membrane Extraction with Sorbent Interface and Gas Chromatography
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Determination of carbon monoxide, methane and carbon dioxide in refinery hydrogen gases and air by gas chromatography
PublikacjaW pracy przedstawiono metodę oznaczania śladowych zawartości tlenku węgla, metanu oraz dwutlenku węgla w rafineryjnych gazach wodorowych oraz powietrzu; granica oznaczalności metody wynosi odpowiednio 0,15, 0,15 oraz 0,20 mikro-gram/litr. Zaprezentowano w pracy prostą modyfikację chromatografu gazowego wyposażonego w detektor płomieniowo-jonizacyjny (FID). Zastosowano kolumnę typu PorapakQ, dodatkowo połączono szeregowo z krótką...
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Rapid assessment of the authenticity of limequat fruit using the electronic nose and gas chromatography coupled with mass spectrometry
PublikacjaCitrus fruits are very popular food products. There are many species and varieties of them. There are also documented cases of some citrus fruits causing a severe allergic reaction. Some species of the citrus fruits, especially hybrid ones show a reduced allergenic effect due to the lack of seeds. There is a need for rapid methods for evaluation of citrus’ botanical origin. During research, the headspace of three citrus fruits...
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A natural deep eutectic solvent - protonated L-proline-xylitol - based stationary phase for gas chromatography
PublikacjaThe paper presents a new kind of stationary phase for gas chromatography based on deep eutectic solvents (DES) in the form of a mixture of L-proline (protonated with hydrochloric acid) as a hydrogen bond acceptor (HBA) and xylitol as a hydrogen bond donor (HBD) in a molar ratio of HBA:HBD 5:1. DES immobilized on a silanized chromatographic support was tested by gas chromatography (GC) in order to determine its resolving power for...
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Research on the separation properties of empty-column gas chromatography (EC-GC) and conditions for simulated distillation (SIMDIS)
PublikacjaThe paper presents the results of investigations on new procedures of determination of selected cleaning additives in diesel fuel. Two procedures: one-step analysis using gas chromatography with flame ionization detection (GC-FID) or mass spectrometry (GC-MS) and a two-step procedure in which normal-phase high-performance liquid chromatography (NP-HPLC) was used for preliminary separation of the additives, were compared. The additive...
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The comparison of vodka, whisky and moonshine by using the electronic nose based on the technology of ultra-fast gas chromatography
PublikacjaVodka andwhisky are produced fromgrain distillates. Formerly these alcohols were very often counterfeited, by the made in home conditions spirit drink called moonshine, which is obtained by distilling a mash from the alcoholic fermentation. This study presents research aimed at checking the usefulness of the electronic nose using ultra-fast gas chromatography for the differentiation of whisky, vodka and moonshine. 12 samples of...
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The comparison of vodka, whisky and moonshine by using the electronic nose based on the technology of ultra-fast gas chromatography
PublikacjaVodka andwhisky are produced fromgrain distillates. Formerly these alcohols were very often counterfeited, by the made in home conditions spirit drink called moonshine, which is obtained by distilling a mash from the alcoholic fermentation. This study presents research aimed at checking the usefulness of the electronic nose using ultra-fast gas chromatography for the differentiation of whisky, vodka and moonshine. 12 samples of...
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Thermal degradation assessment of canola and olive oil using ultra-fast gas chromatography coupled with chemometrics
PublikacjaOil blending is often used to enhance the properties of vegetable oils. The admixture of a more thermally stable oil makes the resulting blend more suitable for use in frying. A new method of quality assessment of vegetable oils used in frying is presented in this paper. In this method, ultra-fast gas chromatography coupled with flame ionization detector and chemometrics is employed. Principal component analysis was used for data...
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Direct solid phase microextraction combined with gas chromatography – Mass spectrometry for the determination of biogenic amines in wine
PublikacjaA direct method based on immersion solid phase microextraction (DI-SPME) gas chromatography mass-spectrometry (GC-MS) was optimized and validated for the determination of 16 biogenic amines in Polish wines. In the analysis two internal standards were used: 1,7-diaminoheptane and bis-3-aminopropylamine. The method allows for simultaneous extraction and derivatization, providing a simple and fast mode of extraction and enrichment....
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Evaluation of flavour profiles in e-cigarette refill solutions using gas chromatography–tandem mass spectrometry
PublikacjaMany flavour compounds that are present in e-liquids for e-cigarettes are responsible for specific tastes and smoking sensations for users. Data concerning content and specific types of flavours is often limited and unknown to users. The aim of the research was to define and compare flavour profiles of e-liquids with the same group taste from different manufacturers. Gas chromatography coupled with tandem mass spectrometry (GC–MS/MS)...
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Application of single drop extraxtion (SDE) gas chromatography method for the determination of carbonyl compounds in spirits and vodkas
PublikacjaW pracy przedstawiono metodę oznaczania związków karbonylowych w spirytusach i wódkach, wykorzystującą do izolacji i wzbogacania technikę mikroekstrakcji do pojedynczej kropli (SDE)po derywatyzacji analitów O-(2,3,4,5,6-pentafluorobenzylo)hydroksylaminą. Określono optymalne parametry izolacji i wzbogacania aldehydów z roztworów alkoholowych (objętość próbki, objętość kropli, zawartość alkoholu, temperaturę i czas ekstrakcji)....
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Environmental aspects of using gas chromatography for determination of pharmaceutical residues in samples characterized by different composition of the matrix
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Determination of volatile fatty acid ethyl esters in raw spiritsusing solid phase microextraction and gas chromatography
PublikacjaPrzedstawiono opracowanie i opymalizację metody analitycznej oznaczania estrów etylowych kwasów tłuszczowych w destylatach rolniczych różnej jakości lub wyprodukowanych z różnych surowców. W badaniach wykorzystywano technikę mikroekstrakcji do fazy stacjonarnej (HS-SPME) oraz kapilarnej chromatografii gazowej (CGC) z detektorem płomieniowo-jonizacyjnym (FID). Ekstrakcja związków lotnych prowadzona była według opracowanej procedury,...
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Development of gas chromatography - tandem mass spectrometry procedure for development of pesticide residues in honey and honeybee samples
PublikacjaA new analytical procedure of determination of multiresidue of pesticides based on application of the modified QuEChERS approach at the step of sample preparation and technique GC-MS/MS has been developed and applied for studies the real honey and honeybee samples. Samples were collected from northern Poland (Pomerania). The proposed procedure enables for the determination of 34 and 30 pesticides residues respectively on honey...
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Identification of organic acids as potential biomarkers in the urine of autistic children using gas chromatography/mass spectrometry
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Direct Screening ofWater Samples for Benzene Hydrocarbon Compounds by Headspace Liquid-Phase Microextraction--Gas Chromatography
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Direct screening of ground water samples for fuel oxygenates by headspace liquid phase microextraction–gas chromatography
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Headspace solid-phase microextraction and gas chromatography-olfactometry analysis of raw spirits of different organoleptic quality
PublikacjaCelem pracy było określenie, ktore związki wnoszą wkład w aromat destylatów rolniczych i wskazać te z nich które mogą powodować obniżenie ich właściwości organoleptycznych. W badaniach zastosowano ekstrakcję lotnych analitów z fazy nadpowierzchniowej techniką mikroekstrakcji do fazy nadpowierzchniowej w połączeniu z chromatografia gazową z detekcja olfaktometryczną . Znaleziono 40 zsubstancji, które mogą być markerami jakości organoleptycznej
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Separation of Volatile Oxygen-containing Organic Compounds by Gas Chromatography - selectivity comparison of different polarity stationary phases
PublikacjaThis paper present a results of the separation of 36 reference compounds belonging to the group of Volatile Oxygen-Containing Organic Compounds (OVOCs) using capillary gas chromatography with flame ionization detector (GC-FID) and three stationary phases of different polarity. A selectivity has been studied regarding to OVOCs and n -alkanes. The most useful for the separation of the group OVOCs is a polar ionic liquid stationary...
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Identification of pollutants at the adjacent areas to the landfill site using two dimensional gas chromatography with mass spectrometry technique
PublikacjaMunicipal landfills are considered one of the main sources of air pollutants. In this article is presented the use of a modern analytical technique: a two dimensional gas chromatography to identify the substances in the atmospheric air near a waste processing plant located in Gdansk. In order to determine the types of substances occurring in different atmospheric conditions, the study was conducted from February to April 2016....
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Characteristic of Morpholinium Ionic Liquids as Gas Chromatography Stationary Phases with McReynolds Constants and Activity Coefficients at Infinite Dilution
PublikacjaIn this work, four ionic liquids based on N-alkyl-N-methylmorpholinium cation ([Mor1,R] where R= 2, 4, 8, 10) and bis(trifluoromethanesulfonyl)imide anion [TFSI] were synthesized. Using gas-liquid chromatography a number of parameters describing the sorption properties of the investigated ionic liquids were determined. The values of Kovats indices, McReynolds constants, and activity coefficients at infinite dilution were the basis...
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Determination of antifreeze substances in the airport runoff waters by solid-phase microextraction and gas chromatography–mass spectrometry method
PublikacjaA new method has been developed for the determination of antifreeze agents such as ethylene glycol (EG), propylene glycol (PG), and diethylene glycol (DEG) in the samples of airport runoff water. The method is based on headspace solid–phase microextraction (HS–SPME) of target analytes, which is coupled with gas chromatography–mass spectrometry (GC–MS). Until now, there was a lack of appropriate methodology for collecting reliable...
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A new silylation reagent dimethyl(3,3,3-trifluoropropyl)silyldiethylamine for the analysis of estrogenic compounds by gas chromatography–mass spectrometry
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Determination of twenty pharmaceutical contaminants in soil using ultrasound-assisted extraction with gas chromatography-mass spectrometric detection
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Comprehensive two-dimensional gas chromatography and three-dimensional fluorometry for detection of volatile and bioactive substances in some berries
PublikacjaThe volatilefractionsofCapegooseberryandblueberryweredeterminedbyheadspacesolid-phase microextractioncoupledwithcomprehensivetwo-dimensionalgaschromatographywithtime-of-flight mass spectrometry(HS-SPME/GCGC-TOFMS).Thehighestamountofalcohol(51.8%),ester(32.8%)and carboxylicacid(6.9%)wasinblueberryincomparisonwithgooseberryandoppositelyketones(14.7%), aldehydes(9.9%)andterpenes(8%)werefoundingooseberry.Thebioactivecompoundsandantioxidant capacities...
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Salt saturated single-drop microextraction of malondialdehyde from human plasma before its determination by gas chromatography
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Enantioselective comprehensive two-dimensional gas chromatography. A route to elucidate the authenticity and origin ofRosa damascena Milleressential oils
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Extraction of mass spectra free of background and neighboring component contributions from gas chromatography/mass spectrometry data
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Rapid and sensitive determination of fluoride in toothpaste and water samples using headspace single drop microextraction-gas chromatography
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The research on properties of asphaltene stationary phase to separate mixtures of optically active compounds with the use of gas chromatography technique
PublikacjaW pracy przedstawiono wyniki badań nad możliwością zastosowania asfaltenów jako chiralnej fazy stacjonarnej do chromatografii gazowej. Wyniki uzyskane dla fazy asfaltenowej porównano z wynikami uzyskanymi poprzez zastosowanie komercyjnie dostępnej chiralnej fazy stacjonarnej. Badania wykazały, że frakcja asfaltenowa posiada właściwości umożliwiające uzyskanie rozdzielenia mieszanin związków optycznie czynnych.
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Application of dispersive liquid-liquid microextraction for the determination of selected organochlorine pesticides in honey by gas chromatography - mass spectrometry
PublikacjaDispersive liquid-liquid microextraction (DLLME) is a rapid and easy technique that consumes minute amounts of organic solvents. In this work, we present chemometric study on optimization of DLLME parameters for the extraction of aldrin, endrin, lindane, alfa-endosulfan, 4,4'-DDT and its metabolites from honey matrix. Method quantification limits (MQLs) vary between 0.3 ng/g for 2,4'-DDE and 4,4'-DDE to 13.2 ng/g for alfa-endosulfan...
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Some aspects of the analysis of environmental pollutants in sediments using pressurized liquid extraction and gas chromatography-mass spectrometry
PublikacjaOpisano wyniki badań nowej procedury oznaczania analitów z grupy wielopierścieniowych węglowodorów aromatycznych oraz polichlorowanych bifenyli w próbkach osadów dennych. Szczególnie dużo uwagi poświęcono zbadaniu możliwości wykorzystania techniki przyspieszonej ekstrakcji analitów za pomocą rozpuszczalnika na etapie izolacji wzbogacania. Ustalono również warunki oznaczeń końcowych z wykorzystaniem techniki GC-MS.
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Thin layer headspace gas chromatography for biological monitoring of persons exposed to volatile organohalogen compounds from water
PublikacjaCelem pracy było zbadanie możliwości wykorzystania analizy fazy nadpowierzchniowej nad cienką warstwą cieczy z samoczynną generacją ciekłego sorbentu (TLHS)do izolacji i wzbogacania THM w próbkach moczu i krwi ludzkiej. Umożliwiło to następnie wykorzystanie prostej techniki bezpośredniego nastrzyku próbki do kolumny chromatografu gazowego, wyposażonego w detektor wychwytu elektronów (DAI-GC-ECD).Przy pomocy tak opracowanej metody...
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Development of headspace solid-phase microextraction-gas chromatography method for the determination of solvent residues in edible oils and pharmaceuticals
PublikacjaW pracy przedstawiono wyniki opracowania procedury oznaczania pozostałości rozpuszczalników organicznych w olejach jadalnych z wykorzystaniem techniki HS-SPME na etapie izolacji i wzbogacania analitów. Przedstawiono proces optymalizacji etapu izolacji i rozdzielenia związków. Dla każdego z analitów wyznaczono parametry walidacyjne charakteryzujące procedurę tj. granice wykrywalności, granicę oznaczalności, liniowość, zakres pomiarowy,...
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Monolithic capsule phase microextraction prior to gas chromatography-mass spectrometry for the determination of organochlorine pesticides in environmental water samples
PublikacjaIn this study, a capsule phase microextraction (CPME) protocol followed by gas chromatography-mass spectrometry is proposed for the accurate and sensitive monitoring of organochlorine pesticides (OCPs) in environmental water samples. Different monolithic sol–gel encapsulated sorbents were compared and monolithic sol–gel poly(ethylene glycol)-based sorbent incorporated into porous microextraction capsules resulted in the highest...
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Determination of fuel combustion product in airport runoff water samples using liquid–liquid extraction with gas chromatography–spectrometry
PublikacjaDetermination of xenobiotics in samples of airport runoff water is both a complex and indispensable task due to an increasing threat resulting from the activities of numerous airports. The aim of this study was to develop, optimize, and validate a procedure based on liquid–liquid extraction (LLE) coupled with gas chromatography–mass spectrometry (GC–MS) for the determination of polycyclic aromatic hydrocarbons (PAHs). So far, no...
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The quantification of bisphenols and their analogues in wastewaters and surface water by an improved solid-phase extraction gas chromatography/mass spectrometry method
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Membrane extraction with sorbent interface-gas chromatography as an effective and fast means for continuous monitoring of thermal degradation products of polyacrylonitrile
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Development and Validation of a Gas Chromatography Method for the Trace Level Determination of Allylamine in Sevelamer Hydrochloride and Sevelamer Carbonate Drug Substances
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Evaluation of Gas Chromatography Stationary Phases Based on Morpholinium Ionic Liquids by McReynolds Constants and Activity Coefficients at Infinite Dilution
PublikacjaIn this work, four ionic liquids (ILs) based on the N-alkyl-N-methylmorpholinium cation ([Mor1,R], in which R = 2, 4, 8, or 10) and bis (trifluoromethanesulfonyl)imide anion were synthesized. Using GLC, a number of parameters describing the sorption properties of the investigated ILs were determined. The values of Kovats indices, McReynolds constants, and activity coefficients at infinite dilution were the basis for the evaluation...
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Determination of volatile aliphatic amines in air by solid phase microex traction coupled with gas chromatography with flame ionization detection.
PublikacjaOpisano nową metodę oznaczania lotnych amin alifatycznych w powietrzu. Metodyka oparta jest na zastosowaniu techniki mikroekstrakcji do fazy stacjonarnej na etapie pobierania próbek oraz zestawu GC-FID do rozdzielania i oznaczania poszczególnych analitów.Badaniom poddano nowe typy faz stacjonarnych.Zbadano wpływ wilgotności powietrza na proces pobierania próbek analitów z powietrza.
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Analysis of pesticide residues in fruits and vegetables using QuEChERS sample preparation method and gas chromatography with electron capture detection
PublikacjaPesticides are a numerous and diverse group of chemical compounds. They are some of the most toxic substances contaminating the environment, which are used to eliminate pests in agriculture and the household. Despite considerable progress in the development of methods for preparing samples for analysis and for the final determination of analytes, the analysis of pesticides in biological samples continues to present challenges to...
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First deep eutectic solvent-based (DES) stationary phase for gas chromatography and future perspectives for DES application in separation techniques
PublikacjaThe paper presents the first application of deep eutectic solvents (DES) as stationary phases for gas chromatography. DES obtained by mixing tetrabutylammonium chloride (TBAC) as a hydrogen bond acceptor (HBA) with heptadecanoic acid being a hydrogen bond donor (HBD) in a mole ratio of HBA:HBD equal to 1:2 was characterized by its ability to separate volatile organic compounds (VOCs). The Rohrschneider – McReynolds constants determined...
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Comprehensive two dimensional gas chromatography coupled with mass spectrometry as tool for characterization of the main pollutants present in atmospheric air in Gdansk
PublikacjaNowadays, the technique that is commonly used to identify and quantify the chemical compounds in gas sample is gas chromatography. The separation resolution in gas chromatography can be improved by applying the modulation technique. In this paper present is the most important information regarding the pollutants present in atmospheric air. The areas in which the tests were carried out are one of the largest industrial zones in...
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Comprehensive determination of flavouring additives and nicotine in e-cigarette refill solutions. Part II: Gas-chromatography–mass spectrometry analysis
PublikacjaFlavouring compounds are an essential part of e-liquid products for cigarettes. In general, they are regarded as safe for ingestion, but they may have unrecognized risks when they are inhaled. In some cases, manufactures do not currently abide by the Tobacco Products Directive (2014/40/EU) and do not declare the detailed contents of e-liquids on their labels. To help evaluate the health impact of flavouring substances, there is...
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Process Control and Investigation of Oxidation Kinetics of Postoxidative Effluents Using Gas Chromatography with Pulsed Flame Photometric Detection (GC-PFPD)
PublikacjaThis article presents the results of investigations on the use of headspace analysis and gas chromatography with pulsed flame photometric detection (HSA-GC-PFPD) to evaluate the effectiveness of oxidation of postoxidative effluents from the production of bitumens. Samples of effluents from the bitumen oxidation unit were used in the experiments. In addition, the kinetics of effluent oxidation was also investigated. The content...