Search results for: ELECTRONIC DEUSITY - Bridge of Knowledge

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π-Stacking attraction vs. electrostatic repulsion: competing supramolecular interactions in a tpphz-bridged Ru(ii)/Au(iii) complex
Publication
- D. Sorsche
- M. Schaub
- F. Heinemann
- J. Habermehl
- S. Kuhri
- D. Guldi
- J. Guthmuller
- S. Rau
- DALTON TRANSACTIONS - Year 2016
The synthesis and characterization of a mixed metal ruthenium(II)/gold(III) complex bridged by tetrapyridophenazine (tpphz) are described. It is isostructural and isoelectronic to the well-known photocatalysts with palladium(II) or platinum(II). Concentration dependent 1H-NMR spectroscopy and XRD studies show that the electrostatic repulsion between the gold(III) moieties exceeds the attractive π-stacking interaction. Theoretical...

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