Search results for: SILANOTIOLANY IMIDAZOLIOWE - Bridge of Knowledge

Search results for: SILANOTIOLANY IMIDAZOLIOWE

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Imidazolium silanethiolates relevant to the active site of cysteineproteases. A cooperative effect in a chain of NH(+)...S(-) hydrogenbonds
Publication
- NEW JOURNAL OF CHEMISTRY - Year 2012
Three imidazolium silanethiolates relevant to the active site of cysteine proteases have been synthesized and investigated by X-ray diffraction, IR spectroscopy and computational methods. As indicated by crystallographic and FT-IR data in the solid state, the transfer of proton from thiol to imidazole takes place and a thiolato-imidazolium ion pair is formed. The FT-IR spectra of crystalline imidazolium silanethiolates exhibit...

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Biomimetic Metal- and Ammonium-Thiolate Systems: The First Crystalline Imidazolium Thiolate and Cadmium Silanethiolate Complexes with Imidazole and Imidazole-Derived Co-ligands
Publication
- K. Kazimierczuk
- N. Piwowarska
- K. Majcher
- A. Herman
- W. Ciesielski
- M. J. Potrzebowski
- A. Dołęga
- CHEMBIOCHEM - Year 2010
Przeprowadzono analizę strukturalną i opisano badania spektroskopowe biomimetycznych tiolanów kadmu oraz tiolanów imidazoliowych.