Search results for: 13C, 29SI, 113CD NMR

• Similarities and differences in d6 low-spin ruthenium, rhodium and iridium half-sandwich complexes: synthesis, structure, cytotoxicity and interaction with biological targets

  Publication

  • A. Gilewska
  • B. Barszcz
  • J. Masternak
  • K. Kazimierczuk
  • J. Sitkowski
  • J. Wietrzyk
  • E. Turlej

  - JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY - Year 2019

  In this paper, we discussed the similarities and diferences in d6 low-spin half-sandwich ruthenium, rhodium and iridium complexes containing 2,2′-biimidazole (H2biim). Three new complexes, {[RuCl(H2biim)(η6 -p-cymene)]PF6}2·H2O (1), [(η5 - Cp)RhCl(H2biim)]PF6 (2), and [(η5 -Cp)IrCl(H2biim)]PF6 (3), were fully characterized by CHN, X-ray difraction analysis, UV–Vis, FTIR, and 1 H, 13C and 15N NMR spectroscopies. The complexes exhibit...

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