Search results for: diselenidy elektrofilowe

• Efficient Selenenylation of Malonates Using Bis(phosphorothioyl) Diselenide

  Publication

  • A. Majewski
  • W. Przychodzeń
  • J. Rachoń

  - PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS - Year 2011

  Bis(O,O-diisopropoxyphosphinothioyl) diselenide reacts readily and quickly with the sodium salt of malonates to give quantitatively stable sodium 2-(O,O-diisopropyl phosphorothioselenenyl)propanedioates. No traces of the corresponding C,C-diselenenylation products were detected. A standard aqueous workup procedure affords the products, albeit in poor yield (about 45%). It was proved that the reaction is reversible due to the presence...

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