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Abstract
The title compound, C19H28O5Si, was obtained in the reaction of 1,3-dihydro-4-[(tert-butyldimethylsilyl)oxy]-6-methoxy-7-methyl-3-oxo-5-(prop-2-enyl)isobenzofuran with meta-chloroperbenzoic acid. This reaction is one of the stages of the total synthesis of mycophenolic acid, which we attempted to modify. The title compound forms crystals with only weak intermolecular interactions. The strongest stacking interaction is found between the benzene and furan rings of inversion-related molecules with a distance of 3.8773 (13) Å between the ring centroids.
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Authors (4)
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Magdalena Małachowska-Ugarte
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- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1107/s1600536811049026
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
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ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
no. 67,
ISSN: 1600-5368 - Language:
- English
- Publication year:
- 2011
- Bibliographic description:
- Małachowska-Ugarte M., Cholewiński G., Chojnacki J., Dzierzbicka K.: 4-[(tert-Butyldimethylsilyl)oxy]-6-methoxy-7-methyl-5-(oxiran-2-ylmethyl)-2-benzofuran-3(1H)-one// ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. -Vol. 67, nr. part 12 (2011),
- DOI:
- Digital Object Identifier (open in new tab) 10.1107/s1600536811049026
- Verified by:
- Gdańsk University of Technology
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