A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties
Abstract
Mononuclear and polymeric complexes of zinc(II) and copper(II) have been synthesized using two isomers of the hemi-salen ligand with a different mutual orientation of donor atoms. The heterometallic Cu/Zn metallocycle features a catalytic niche filled with the molecule of water and molecules of methanol. This unusual compound exhibits both pronounced catalytic activity in the reaction of oxidation of a secondary alcohol to ketone and field induced slow magnetic relaxation, which is a very rare phenomenon among Cu(II) complexes.
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- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
DALTON TRANSACTIONS
ISSN: 1477-9226 - Language:
- English
- Publication year:
- 2019
- Bibliographic description:
- Mielcarek A., Bieńko A., Saramak P., Jezierska J., Dołęga A.: A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties// DALTON TRANSACTIONS -,iss. 48 (2019),
- DOI:
- Digital Object Identifier (open in new tab) 10.1039/c9dt03304a
- Verified by:
- Gdańsk University of Technology
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