Activation of N2O and SO2 by the P–B Bond System. Reversible Binding of SO2 by the P–O–B Geminal Frustrated Lewis Pair - Publication - Bridge of Knowledge

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Activation of N2O and SO2 by the P–B Bond System. Reversible Binding of SO2 by the P–O–B Geminal Frustrated Lewis Pair

Abstract

Herein, we present the first transformation of borylphosphine into borylphosphinite using nitrous oxide. Borylphosphine reacts with N2O via insertion of a single oxygen atom into the P−B bond and formation of a P−O−B bond system. Borylphosphine and borylphosphinite capture SO2 and activate it in an irreversible and reversible manner, respectively.

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
INORGANIC CHEMISTRY no. 59, pages 6332 - 6337,
ISSN: 0020-1669
Language:
English
Publication year:
2020
Bibliographic description:
Szynkiewicz N., Chojnacki J., Grubba R.: Activation of N2O and SO2 by the P–B Bond System. Reversible Binding of SO2 by the P–O–B Geminal Frustrated Lewis Pair// INORGANIC CHEMISTRY -Vol. 59,iss. 9 (2020), s.6332-6337
DOI:
Digital Object Identifier (open in new tab) 10.1021/acs.inorgchem.0c00435
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