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Advanced oxidation treatment of Pentoxifylline in aqueous solution

Abstract

The degradation of pentoxifylline (PTX) using H2O2, UV, H2O2/UV, Fenton and photo- Fenton processes has been examined in aqueous solution. The influence of various amount of oxidation agent on H2O2, H2O2/UV, Fenton and photo-Fenton reactions were investigated. Initial PTX concentration in Fenton and photo-Fenton was considerated. The addition of inorganic ions (Cl-, NO3-, SO42- and CO32-) on the degradation efficiency of PTX were tested for H2O2/UV, Fenton and photo-Fenton rocesses. The results indicate that the photo-Fenton reaction is the most sufficient for PTX removal. The complete pharmaceutics decomposition is achieved after 5 min under optimized concentration of FeSO4·7H2O and H2O2. The degradation of PTX is inhibited in the presence of inorganic matter in H2O2/UV and Fenton reaction. In the photo-Fenton process addition of above compounds does not affect the reaction rate. Structures of nine products of photo-Fenton reaction have been proposed.

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Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
Environment Protection Engineering no. 43, edition 1, pages 31 - 47,
ISSN: 0324-8828
Language:
English
Publication year:
2017
Bibliographic description:
Kamińska B., Skwierawska A., Kozłowska-Tylingo K., Tomczak-Wandzel R., Pazik A., Majewska K.: Advanced oxidation treatment of Pentoxifylline in aqueous solution// Environment Protection Engineering. -Vol. 43, iss. 1 (2017), s.31-47
DOI:
Digital Object Identifier (open in new tab) 10.37190/epe170103
Verified by:
Gdańsk University of Technology

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