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Arylated carbon nanotubes for biobatteries and biofuel cells

Abstract

Singlwalled carbon nanotubes (swcnts)covalently phenylated, napthylated or terphenylated were used for the construction of cathodes in a biobattery and in a biofuel cell. zn is the anode in the biobaterry and single-walled carbon nanotubes are covalently modified with glucose oxidase/catalase (swcnt-gox/cat) and the biofuel cell anode. the cell parameters were determined and the potentials of each of the electrodes under cell working conditions were simultaneously measured vs. ag/agcl reference electrode. this allowed to evaluate the changes of potential under changing loads of the fuel cell or biobaterry. a power density of ca.1mw/cm2 was achieved using the biobateryy with phenylated nanotubes at the cathode and the open circuit potential was 1,5v. the fully enzymatic fuel cell studeid had power density of 40uw/cm2 and at 20kohm loading. the power densities and working potentials are larger for the biobaterry which is especially useful for testing novel cathodes.

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Keywords

Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
ELECTROCHIMICA ACTA no. 79, pages 74 - 81,
ISSN: 0013-4686
Language:
English
Publication year:
2012
Bibliographic description:
Biernat J., Stolarczyk K., Łyp D., Żelechowska K., Rogalski J., Bilwicz R.: Arylated carbon nanotubes for biobatteries and biofuel cells// ELECTROCHIMICA ACTA. -Vol. 79, (2012), s.74-81
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.electacta.2012.06.050
Verified by:
Gdańsk University of Technology

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