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Composite Materials Based on Polymer-Derived SiCN Ceramic and Disordered Hard Carbons as Anodes for Lithium-Ion Batteries
Abstract
New composite materials based on polymer-derived SiCN ceramics and hard carbons were studied in view of its application as anodes for lithium-ion batteries. Two kinds of composites were prepared by pyrolysis of the preceramic polysilazane (HTT1800, Clariant) at 1000 °C in Ar atmosphere mixed with hard carbons derived from potato starch (HC_PS) or with a hard carbon precursor, namely potato starch (PS), denoted as HTT/HC_PS and HTT/PS composites, respectively. Thermal gravimetric analysis suggests possible reactions between the preceramic polymer and the carbon precursor. The HTT/PS composites contain higher amount of oxygen and appear to be more homogeneous than that of the HTT/HC_PS composite. Raman analysis confirms the presence of highly disordered carbon in the composites by the appearance of the well-pronounced D band at 1347 cm−1. The materials are amorphous with a significant fraction of single graphene sheets as confirmed by X-ray diffraction. The HTT/PS composite exhibits a high-recovered capacity (434 mAh g−1 when charging with a current of 36 mA g−1) and outstanding cyclability for 400 cycles even at high current rates (90 mAh g−1 when charging with 3600 mA g−1). These properties make the composite a candidate anode material for high power energy devices.
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Authors (3)
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Magdalena Graczyk-Zajac
- Technische Universität Darmstadt Fachbereich Material-und Geowissenschaften
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Ralf Riedel
- Technische Universität Darmstadt Fachbereich Material-und Geowissenschaften
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Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
JOURNAL OF POWER SOURCES
no. 244,
pages 80 - 86,
ISSN: 0378-7753 - Language:
- English
- Publication year:
- 2013
- Bibliographic description:
- Wilamowska-Zawłocka M., Graczyk-Zajac M., Riedel R.: Composite Materials Based on Polymer-Derived SiCN Ceramic and Disordered Hard Carbons as Anodes for Lithium-Ion Batteries// JOURNAL OF POWER SOURCES. -Vol. 244, (2013), s.80-86
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.jpowsour.2013.03.137
- Verified by:
- Gdańsk University of Technology
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