Conductive printable electrodes tuned by boron-doped nanodiamond foil additives for nitroexplosive detection - Publication - Bridge of Knowledge

Your account

login

Search

Conductive printable electrodes tuned by boron-doped nanodiamond foil additives for nitroexplosive detection

Abstract

An efficient additive manufacturing-based composite material fabrication for electrochemical applications is reported. The composite is composed of commercially available graphene-doped polylactide acid (G-PLA) 3D printouts and surface- functionalized with nanocrystalline boron-doped diamond foil (NDF) additives. The NDFs were synthesized on a tantalum substrate and transferred to the 3D-printout surface at 200 °C. No other electrode activation treatment was necessary. Different configurations of low- and heavy-boron doping NDFs were evaluated. The electrode kinetics was analyzed using electro- chemical procedures: cyclic voltammetry and electrochemical impedance spectroscopy. The quasi-reversible electrochemical process was reported in each studied case. The studies allowed confirmation of the CV peak-to-peak separation of 63 mV and remarkably high heterogeneous electron transfer rate constant reaching 6.1 × 10 −2 cm s −1 for 10 k ppm [B]/[C] thin NDF fitted topside at the G-PLA electrode. Differential pulse voltammetry was used for effective 2,4,6-trinitrotoluene (TNT) detection at the studied electrodes with a 87 ppb limit of detection, and wide linearity range between peak current density and the analyte concentration (0.064 to 64 ppm of TNT). The reported electrode kinetic differences originate primarily from the boron-dopant concentration in the diamond and the various contents of the non-diamond carbon phase.

Citations

  • 6

    CrossRef

  • 0

    Web of Science

  • 6

    Scopus

Authors (7)

Cite as

Full text

download paper
downloaded 35 times
Publication version
Accepted or Published Version
DOI:
Digital Object Identifier (open in new tab) 10.1007/s00604-022-05371-w
License
Creative Commons: CC-BY open in new tab

Keywords

Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
MICROCHIMICA ACTA no. 189,
ISSN: 0026-3672
Language:
English
Publication year:
2022
Bibliographic description:
Dettlaff A., Rycewicz M., Ficek M., Wieloszyńska A., Szala M., Ryl J., Bogdanowicz R.: Conductive printable electrodes tuned by boron-doped nanodiamond foil additives for nitroexplosive detection// MICROCHIMICA ACTA -Vol. 189,iss. 8 (2022), s.158358-
DOI:
Digital Object Identifier (open in new tab) 10.1007/s00604-022-05371-w
Sources of funding:
Verified by:
Gdańsk University of Technology

Referenced datasets

seen 141 times

Recommended for you

Electrochemical determination of nitroaromatic explosives at boron-doped diamond/graphene nanowall electrodes: 2,4,6-trinitrotoluene and 2,4,6-trinitroanisole in liquid effluents

2020

Electrochemical determination of neurotransmitter serotonin using boron/nitrogen co-doped diamond-graphene nanowall-structured particles

2022

The electrochemical determination of isatin at nanocrystalline boron-doped diamond electrodes: stress monitoring of animals

2020

Enhanced electrochemical kinetics of highly-oriented (111)-textured boron-doped diamond electrodes induced by deuterium plasma chemistry

2021
Meta Tags