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Abstract
We have developed an efficient and convenient regio‐ and stereoselective reduction of the alkynyl sulfides with pinacolborane in the presence of copper(I) chloride to produce (Z)‐alkenyl sulfides in good and very good yields. The functionalized alkynyl sulfides are readily available based on the reaction of lithium acetylides with thiotosylates under mild conditions.
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- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1002/ejoc.201801181
- License
- Copyright (2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
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EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
no. 2018,
pages 6333 - 6337,
ISSN: 1434-193X - Language:
- English
- Publication year:
- 2018
- Bibliographic description:
- Doroszuk J., Musiejuk M., Ponikiewski Ł., Witt D.: Convenient and Efficient Diastereoselective Preparation of Functionalized Z -Alkenyl Sulfides// EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. -Vol. 2018, nr. 45 (2018), s.6333-6337
- DOI:
- Digital Object Identifier (open in new tab) 10.1002/ejoc.201801181
- Verified by:
- Gdańsk University of Technology
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