Abstract
A copper-tartrate, [Cu2(Tart)2(H2O)2]·4H2O, was synthesized at room temperature in aqueous media using copper chloride and D-tartaric acid. The compound crystallizes in the monoclinic system P21 space group and was characterized by infrared spectroscopy, thermogravimetry, X-ray powder diffraction and the results are in good agreement with the single crystal structure. Catalytic properties for allylation of aldehydes were investigated at different solvents, and the best conditions obtained were using a mixture of CH2Cl2:H2O. The copper-tartrate obtained showed good performance as catalyst for different substrates and yields were between 62% and 95%
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- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
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JOURNAL OF MOLECULAR STRUCTURE
no. 1155,
pages 530 - 535,
ISSN: 0022-2860 - Language:
- English
- Publication year:
- 2018
- Bibliographic description:
- Da_silva G., Menezes P., Malvestiti I., Falcão E., Junior S., Chojnacki J., Da Silva F.: Copper-based 2D-coordination polymer as catalyst for allylation of aldehydes// JOURNAL OF MOLECULAR STRUCTURE. -Vol. 1155, (2018), s.530-535
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.molstruc.2017.10.096
- Bibliography: test
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- Post-print of: Da_silva G., Menezes P., Malvestiti I., Falcão E., Junior S., Chojnacki J., Da Silva F.: Copper-based 2D- coordination polymer as catalyst for allylation of aldehydes. JOURNAL OF MOLECULAR STRUCTURE. Vol. 1155, (2018), p. 530-535. DOI: 10.1016/j.molstruc.2017.10.096 open in new tab
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