Dipodal Tetraamide Derivatives of 1,10-Diaza-18-Crown-6 and Alkylmalonic Acids—Synthesis and Use as Ionophores in Ion Selective Membrane Electrodes - Publication - Bridge of Knowledge

Your account

login

Search

Dipodal Tetraamide Derivatives of 1,10-Diaza-18-Crown-6 and Alkylmalonic Acids—Synthesis and Use as Ionophores in Ion Selective Membrane Electrodes

Abstract

Novel dipodal derivatives of an 18-membered diaza-crown ether with two diamide chains featuring methylmalonic or butylmalonic acid residues were obtained and tested as ionophores in ion-selective plasticized membrane electrodes. The objective of the study was to identify measurement conditions which ensure the most favorable performance for magnesium ion-selective electrodes. The relationship between the molar lipophilic anion salt-to-ionophore ratio and selectivity of electrodes was examined. The best result was obtained for the conventional electrode containing Mg2 ionophore. Calculated selectivity coefficients were as follows: logKMg/Ca = −2.77, logKMg/Na = −3.46 and logKMg.K = −2.24 (SSM, 1M)

Citations

  • 1

    CrossRef

  • 0

    Web of Science

  • 0

    Scopus

Authors (3)

Cite as

Full text

download paper
downloaded 46 times
Publication version
Accepted or Published Version
DOI:
Digital Object Identifier (open in new tab) 10.3390/s21154984
License
Creative Commons: CC-BY open in new tab

Keywords

Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
SENSORS no. 21,
ISSN: 1424-8220
Language:
English
Publication year:
2021
Bibliographic description:
Pomećko R., Luboch E., Jeszke M.: Dipodal Tetraamide Derivatives of 1,10-Diaza-18-Crown-6 and Alkylmalonic Acids—Synthesis and Use as Ionophores in Ion Selective Membrane Electrodes// SENSORS -Vol. 21,iss. 15 (2021), s.4984-
DOI:
Digital Object Identifier (open in new tab) 10.3390/s21154984
Verified by:
Gdańsk University of Technology

seen 158 times

Recommended for you

Solid-Contact Ion-Selective Electrodes with Highly SelectiveThioamide Derivatives of p-tert-Butylcalix[4]arene for theDetermination of Lead(II) in Environmental Samples

2013

O-substituted tetrahydroxamate derivatives of p-tert-butylcalix[4]arene as receptors for transition and heavy metal cations

2010

Potentiometric Solid-Contact Ion-Selective Electrode for Determination of Thiocyanate in Human Saliva

  • M. Urbanowicz,
  • K. Sadowska,
  • D. G. Pijanowska
  • + 2 authors
2020

Functionalized azobenzocrown ethers as sensor materials—The synthesis and ion binding properties

2013
Meta Tags