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Abstract
This study was focused on the activation of the C[double bond, length as m-dash]P bond via reactions of Ph2C[double bond, length as m-dash]P-PtBu2 (1) with 1,6-hexanediol and selected dithiols (1,4-butanedithiol, 1,4-benzenedithiol and 1,4-benzenedimethanethiol). These reactions proceed according to a 1,2-addition mechanism, providing new compounds with formulas {(Ph)2(H)C-P-PtBu2}{μ2-(O-(CH2)6-O)}{tBu2P-P-C(H)(Ph)2} (2), {(Ph)2(H)C-P-PtBu2}{μ2-(S-(CH2)4-S)}{tBu2P-P-C(H)(Ph)2} (3a), {(Ph)2(H)C-P-PtBu2}{μ2-(S-C6H4-S)}{tBu2P-P-C(H)(Ph)2} (3b), and {(Ph)2(H)C-P-PtBu2}{μ2-(S-CH2-C6H4-CH2-S)}{tBu2P-P-C(H)(Ph)2} (3c). Next, the reactions of 3a and 3c with metal chlorides led to the growth of desired coordination polymers of copper(I) and silver(I). All the obtained compounds remained stable under atmospheric conditions.
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Authors (5)
-
Tomasz Kruczyński dr inż.
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Michael Gamer Dr
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- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
DALTON TRANSACTIONS
no. 53,
pages 9350 - 9357,
ISSN: 1477-9226 - Language:
- English
- Publication year:
- 2024
- Bibliographic description:
- Ziółkowska A., Prześniak-Welenc M., Kruczyński T., Gamer M., Ponikiewski Ł.: From phosphanylphosphaalkenes to coordination copper and silver polymers containing P–P bonds// DALTON TRANSACTIONS -Vol. 53,iss. 22 (2024), s.9350-9357
- DOI:
- Digital Object Identifier (open in new tab) 10.1039/d4dt00987h
- Sources of funding:
-
- Statutory activity/subsidy
- Verified by:
- Gdańsk University of Technology
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