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Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study

Abstract

The reactivities of two selected phosphanylphosphaalkenes, Ph2C=P-PtBu2 (1a) and (p-MeO-Ph)2C=P-PtBu2 (1b), toward CuCl, AgCl and (tht)AuCl (tht = tetrahydrothiophene) were investigated. As a result, new phosphanylphosphaalkene dimeric and monomeric complexes were formed (Cu and Ag dimeric and Au monomeric). All obtained products were air and moisture stable and light insensitive.

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
DALTON TRANSACTIONS no. 52, pages 4658 - 4662,
ISSN: 1477-9226
Language:
English
Publication year:
2023
Bibliographic description:
Ziółkowska A., Szynkiewicz N., Ryl J., Ponikiewski Ł.: Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study// DALTON TRANSACTIONS -Vol. 52,iss. 15 (2023), s.4658-4662
DOI:
Digital Object Identifier (open in new tab) 10.1039/d3dt00626c
Sources of funding:
  • IDUB
Verified by:
Gdańsk University of Technology

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