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Abstract
We introduce highly antifouling Polymer-Nanoparticle-Nanoparticle/Polymer (PNNP) hybrid membranes as multi-functional materials for versatile purification of wastewater. Nitrogen-rich polyethylenimine (PEI)-functionalized halloysite nanotube (HNT-SiO2-PEI) nanoparticles were developed and embedded in polyvinyl chloride (PVC) membranes for protein and dye filtration. Bulk and surface characteristics of the resulting HNT-SiO2-PEI nanocomposites were determined using Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and thermogravimetric analysis (TGA). Moreover, microstructure and physicochemical properties of HNT-SiO2-PEI/PVC membranes were investigated by scanning electron microscopy (SEM), atomic force microscopy (AFM), and attenuated total reflectance (ATR)-FTIR. Results of these analyses indicated that the overall porosity and mean pore size of nanocomposite membranes were enhanced, but the surface roughness was reduced. Additionally, surface hydrophilicity and flexibility of the original PVC membranes were significantly improved by incorporating HNT-SiO2-PEI nanoparticles. Based on pure water permeability and bovine serum albumin (BSA)/dye rejection tests, the highest nanoparticle-embedded membrane performance was observed at 2 weight percent (wt%) of HNT-SiO2-PEI. The nanocomposite incorporation in the PVC membranes further improved its antifouling performance and flux recovery ratio (96.8%). Notably, dye separation performance increased up to 99.97%. Overall, hydrophobic PVC membranes were successfully modified by incorporating HNT-SiO2-PEI nanomaterial and better-quality wastewater treatment performance was obtained.
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Authors (17)
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Vahid Vatanpour
- Kharazmi University, Department of Applied Chemistry, Faculty of Chemistry
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Maryam Jouyandeh
- University of Tehran, Center of Excellence in Electrochemistry, School of Chemistry
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Seyed Soroush Mousavi Khadem
- University of Tehran, Center of Excellence in Electrochemistry, School of Chemistry
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Shadi Paziresh
- Kharazmi University, Department of Applied Chemistry, Faculty of Chemistry
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Ahmad Dehghan
- Kharazmi University, Department of Applied Chemistry, Faculty of Chemistry
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Mohammad Ganjali
- University of Tehran, Center of Excellence in Electrochemistry, School of Chemistry
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Hiresh Moradi
- Research and Development Unit, Ghaffari Chemical Industries Corporation, Tehran, Iran
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Somayeh Mirsadeghi
- Tehran University of Medical Science, Endocrinology and Metabolism Center, Endocrinology and Metabolism Clinical Medical Institute,
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Alireza Badiei
- University of Tehran, School of Chemistry
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Muhammad Tajammal Munir
- American University of the Middle East, Egaila, Kuwait, College of Engineering and Technology
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Ahmad Mohaddespour
- American University of the Middle East, Egaila, Kuwait, College of Engineering and Technology
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Navid Rabiee
- Sharif University of Technology, Department of Physics
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Sajjad Habibzadeh
- Amirkabir University of Technology (Tehran Polytechnic), Department of Chemical Engineering
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Amin Hamed Mashhadzadeh
- Nazarbayev University, , Kazakhstan, School of Engineering and Digital Sciences, Department of Mechanical and Aerospace Engineering
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Sasan Nouranian
- University of Mississippi, Department of Chemical Engineering,
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Mohammad Saeb
- Université de Lorraine, CentraleSupélec, LMOPS, F-57000, Metz, France
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Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
SCIENCE OF THE TOTAL ENVIRONMENT
no. 810,
ISSN: 0048-9697 - Language:
- English
- Publication year:
- 2022
- Bibliographic description:
- Vatanpour V., Jouyandeh M., Mousavi Khadem S. S., Paziresh S., Dehghan A., Ganjali M., Moradi H., Mirsadeghi S., Badiei A., Munir M. T., Mohaddespour A., Rabiee N., Habibzadeh S., Mashhadzadeh A. H., Nouranian S., Formela K., Saeb M.: Highly antifouling polymer-nanoparticle-nanoparticle/polymer hybrid membranes// SCIENCE OF THE TOTAL ENVIRONMENT -Vol. 810, (2022), s.152228-
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.scitotenv.2021.152228
- Sources of funding:
-
- Free publication
- Verified by:
- Gdańsk University of Technology
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