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In situ transformation boosts the pseudocapacitance of CuNi-MOF via cooperative orientational and electronic governing
Abstract
The disordered arrangement and thereof inferior conductivity of 2D MOF sheets seriously hinder their practical application. Herein, we propose in situ transformation strategy to architect vertically oriented bimetallic CuNi-MOF as a self-supporting electrode, leading to a decuple high specific capacitance of 1262 C g-1 in comparison with the pristine Ni-MOF powder of 114 C g-1 at 2 A g-1. DFT calculations reveal that introduction of Cu can modulate the electronic structure of metal centers in the Ni-MOF sheets and optimize electrical conductivity. Our strategy is promising to maximize the utilization of MOF superiorities for optimizing their electrochemical performance.
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Authors (7)
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Xianyu Chu
- Jilin University
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Fanling Meng
- Jilin University
-
Wei Zhang
- Jilin University
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Lihua Zhang
- Brookhaven National Laboratory
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Weitao Zheng
- Jilin University
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- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1080/21663831.2023.2181111
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Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
Materials Research Letters
no. 11,
pages 446 - 453,
ISSN: 2166-3831 - Language:
- English
- Publication year:
- 2023
- Bibliographic description:
- Chu X., Meng F., Zhang W., Zhang L., Molin S., Jasiński P., Zheng W.: In situ transformation boosts the pseudocapacitance of CuNi-MOF via cooperative orientational and electronic governing// Materials Research Letters -Vol. 11,iss. 6 (2023), s.446-453
- DOI:
- Digital Object Identifier (open in new tab) 10.1080/21663831.2023.2181111
- Verified by:
- Gdańsk University of Technology
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