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Interrelated shape memory and Payne effect in polyurethane/graphene oxide nanocomposites

Abstract

We report the fabrication of graphene oxide (GO) based polyurethane (PU) nanocomposites by a simple method of mixing and their shape memory properties at different temperatures. Both the polymer and the filler were synthesized in the laboratory by simple and easy methods – PU by pre-polymer method and GO by improved graphene oxide synthesis method. High molecular level dispersion of GO platelets within the PU matrix and thus good mechanical properties were maintained by the improved PU/GO interfacial interaction. The structure of the polymer composites was investigated by scanning electron microscopy and X-ray diffraction studies revealed a highly dispersed morphology of graphene oxide sheets in PU.

Authors (6)

  • Photo of  Deepalekshmi Ponnamma

    Deepalekshmi Ponnamma

    • School of Chemical Sciences, Mahatma Gandhi University, Kottayam-686560, Kerala, India School of Chemical Sciences, Mahatma Gandhi University, Kottayam-686560, Kerala, India
  • Photo of  Kishor Kumar Sadasivuni

    Kishor Kumar Sadasivuni

    • School of Chemical Sciences, Mahatma Gandhi University, Kottayam-686560, Kerala, India School of Chemical Sciences, Mahatma Gandhi University, Kottayam-686560, Kerala, India
  • Photo of  Paula Moldenaers

    Paula Moldenaers

    • Katholieke Universiteit Leuven, Willem de Croylaan 46, 3001-B Leuven, Belgium Department of Chemical Engineering
  • Photo of  Sabu Thomas

    Sabu Thomas

    • School of Chemical Sciences, Mahatma Gandhi University, Priyadarshini Hills P.O, Kottayam-686 560, Kerala, India. Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Priyadarshini Hills P.O, Kottayam-686 560, Kerala, India
  • Photo of  Yves Grohens

    Yves Grohens

    • School of Chemical Sciences, Mahatma Gandhi University, Kottayam-686560, Kerala, India School of Chemical Sciences, Mahatma Gandhi University, Kottayam-686560, Kerala, India

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
RSC Advances no. 3, pages 68 - 79,
ISSN: 2046-2069
Language:
English
Publication year:
2013
Bibliographic description:
Ponnamma D., Sadasivuni K., Strankowski M., Moldenaers P., Thomas S., Grohens Y.: Interrelated shape memory and Payne effect in polyurethane/graphene oxide nanocomposites// RSC Advances. -Vol. 3, (2013), s.68-79
Verified by:
Gdańsk University of Technology

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