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iPP/HDPE blends compatibilized by a polyester: An unconventional concept to valuable products

Abstract

Polyolefins are the most widely used plastics accounting for a large fraction of the polymer waste stream. Although reusing polyolefins seems to be a logical choice, their recycling level remains disappointingly low. This is mainly due to the lack of large-scale availability of efficient and inexpensive compatibilizers for mixed polyolefin waste, typically consisting of high-density polyethylene (HDPE) and isotactic polypropylene (iPP) that, despite their similar chemical hydrocarbon structure, are immiscible. Here, we describe an unconventional approach of using polypentadecalactone, a straightforward and simple-to-produce aliphatic polyester, as a compatibilizer for iPP/HDPE blends, especially the brittle iPP-rich ones. The unexpectedly effective compatibilizer transforms brittle iPP/HDPE blends into unexpectedly tough materials that even outperform the reference HDPE and iPP materials. This simple approach creates opportunities for upcycling polymer waste into valuable products.

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Authors (10)

Keywords

Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
Science Advances no. 10, pages 1 - 11,
ISSN: 2375-2548
Language:
English
Publication year:
2024
Bibliographic description:
Jasińska-Walc L., Kruszyński J., Nowicka W., Duchateau R., Bouyahyi M., Yang L., Różański A., Yingxin L., Parisi D., Farhan A.: iPP/HDPE blends compatibilized by a polyester: An unconventional concept to valuable products// Science Advances -,iss. 21 (2024),
DOI:
Digital Object Identifier (open in new tab) 10.1126/sciadv.ado1944
Verified by:
Gdańsk University of Technology

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