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Luminescent properties of Ln3+ doped tellurite glasses containing AlF3

Abstract

The low-phonon energy tellurite glasses TeO2-BaO-Bi2O3 and TeO2-BaO-Bi2O3-AlF3 triply doped with Eu3+, Tb3+, Tm3+ ions in two different molar ratios were synthesized using melt-quenching technique. Their structure and luminescence properties were widely investigated by X-ray Diffraction (XRD), Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR) and Photoluminescence Spectroscopy (PL). The luminescence spectra of Eu3+, Tb3+, Tm3+ co-doped glasses show apart of the bands corresponding to the 4f-4f transitions of lanthanide ions also band corresponding to glass matrix. AlF3 doping increases emission intensity, although to improve overall emission color further studies on molar composition of samples and the molar ratio of the components should be carried out.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
OPTICAL MATERIALS no. 59, pages 70 - 75,
ISSN: 0925-3467
Language:
English
Publication year:
2016
Bibliographic description:
Walas M., Pastwa A., Lewandowski T., Synak A., Gryczyński I., Sadowski W., Kościelska B.: Luminescent properties of Ln3+ doped tellurite glasses containing AlF3// OPTICAL MATERIALS. -Vol. 59, (2016), s.70-75
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.optmat.2016.01.040
Verified by:
Gdańsk University of Technology

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