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Nanocrystalline Polymer Impregnated [Fe(pz)Pt(CN)4] Thin Films Prepared by Matrix-Assisted Pulsed Laser Evaporation
Abstract
In this work, the fabrication of [Fe(pz)Pt(CN)4] (pz = pyrazine) thin films by means of matrix-assisted pulsed laser evaporation (MAPLE) was investigated. As starting material, a cryogenically cooled suspension of anocrystalline [Fe(pz)Pt- (CN)4] (0.35wt.-%) in a mixture of 1,1-dichloroethane and polyethylene glycol (PEG) was used. Films of a thickness up to 150–200 nm were deposited on Si substrates by laser ablation at λ = 1064 nm of the cryogenically cooled material. PEG impregnated films exhibit a cooperative first-order hysteretic spin crossover behavior around 155 K as detected by Raman spectroscopy. Most interestingly, deposition of a crystalline material was achieved through MAPLE deposition
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Authors (8)
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Sawczak Mirosław dr hab. inż.
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Dominik Maskowicz mgr inż.
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Garcia Yann dr
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Astha C. Gosh dr
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Gerard Śliwiński prof.
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Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
no. 2019,
pages 3249 - 3255,
ISSN: 1434-1948 - Language:
- English
- Publication year:
- 2019
- Bibliographic description:
- Mirosław S., Jendrzejewski R., Maskowicz D., Yann G., Gosh A., Gazda M., Czechowski J., Śliwiński G.: Nanocrystalline Polymer Impregnated [Fe(pz)Pt(CN)4] Thin Films Prepared by Matrix-Assisted Pulsed Laser Evaporation// EUROPEAN JOURNAL OF INORGANIC CHEMISTRY -Vol. 2019,iss. 27 (2019), s.3249-3255
- DOI:
- Digital Object Identifier (open in new tab) 10.1002/ejic.201900231
- Verified by:
- Gdańsk University of Technology
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